Effect of annealing temperature on amorphous indium zinc oxide thin films prepared by a sol-gel spin-coating method
1
조회
0
다운로드
1
인용
0
참고문헌
키워드
초록
Transparent conductive indium zinc oxide thin films were prepared by spin-coating a sol-gel solution. Zinc acetate dihydrate [Zn(CH3COO)2 · 2H2O] and indium acetate [In(CH3COO)3] were used as starting precursors, and 2-methoxyethanol with 1-propanol as solvents. Upon annealing in a temperature range from 500 to 1000oC, the thin film crystallizes into polycrystalline In2O3(ZnO). The lowest electrical resistivity was obtained at an annealing temperature of 700oC as 2 Ω · cm. Average optical transmittances were higher than 80% at all annealing temperatures. These experimental results confirm that the sol-gel spin-coating can be a good simplified practical method for forming transparent electrodes.
Abstract
Transparent conductive indium zinc oxide thin films were prepared by spin-coating a sol-gel solution. Zinc acetate dihydrate [Zn(CH3COO)2 · 2H2O] and indium acetate [In(CH3COO)3] were used as starting precursors, and 2-methoxyethanol with 1-propanol as solvents. Upon annealing in a temperature range from 500 to 1000oC, the thin film crystallizes into polycrystalline In2O3(ZnO). The lowest electrical resistivity was obtained at an annealing temperature of 700oC as 2 Ω · cm. Average optical transmittances were higher than 80% at all annealing temperatures. These experimental results confirm that the sol-gel spin-coating can be a good simplified practical method for forming transparent electrodes.
참고문헌 (16)
- T. Moriga, "Phase relationships and physical properties of homologous compounds in the zinc oxide-indium oxide system", J. Am. Ceram. Soc, 81(5), pp.1310~ (1998)
- K.Y. Son, "Phase development procedure of In2O3(ZnO)3 ceramics and its sintering behavior", Solid State Ion, 172, pp.425~ (2004)
- L. Dupont, "Structures and textures of transparent conducting pulsed laser deposited In2O3-ZnO thin films revealed by transmission electron microscopy", J. Solid State Chem, 158, pp.119~ (2001)
- T. Moriga, "Effects of introduction of argon on structural and transparent conducting properties of ZnO-In2O3 thin films prepared by pulsed laser deposition", Thin Solid Films, 486, pp.53~ (2005)
- N. Naghavi, "Structural and physical characterization of transparent conducting pulsed laser deposited In2O3-ZnO thin films", J. Mater. Chem, 10, pp.2315~ (2000)
- G. Goncalves, "Crystallization of amorphous indium zinc oxide thin films produced by radio-frequency magnetron sputtering", Thin Solid Films, 516, pp.1374~ (2008)
- Y.R. Park, "Growth of transparent conducting nano-structured In doped ZnO thin films by pulsed DC magnetron sputtering", Applied Surface Science, 254, pp.2250~ (2008)
- K.J. Chen, "Microstructures, optical and electrical properties of In-doped ZnO thin films prepared by sol-gel method", Applied Surface Science, 255, pp.6308~ (2009)
- S.Y. Lee, "Electrical and optical properties of In2O3-ZnO thin films prepared by sol-gel method", Thin Solid Films, 484, pp.184~ (2005)
- J.H. Lee, "Fabrication and characteristics of transparent conducting In2O3-ZnO thin films by ultrasonic spray pyrolysis", Mater. Sci. Eng. B, 127, pp.267~ (2006)
- Z.Q. Xu, "Characteristics of Al-doped c-axis orientation ZnO thin films prepared by the sol-gel method", Mater. Res. Bull, 41, pp.354~ (2006)
- G.S. Wang, "Combined annealing temperature and thickness effects on properties of PbZr0.53Ti0.47O3 films on LaNiO3", Si substrate by sol-gel process, 2006, pp.293, 370~
- G. Machado, "Indium doped zinc oxide thin films obtained by electrodeposition", Thin Solid Films, 490, pp.124~ (2005)
- N. Naghavi, "Systemic study and performance optimization of transparent conducting indium-zinc oxide thin films", Electrochim. Acta, 46, pp.2007~ (2001)
- R. Ghosh, "Effect of thermal annealing treatment on structural, electrical and optical properties of transparent sol-gel ZnO thin films", Mater. Res. Bul, 40, pp.1905~ (2005)
- P.K. Ghosh, "Size-dependent optical and dielectric properties of nanocrystalline ZnS thin films synthesized via rf-magnetron sputtering technique", Mater. Res. Bul, 42, pp.505~ (2006)
