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High Temperature Durability Amorphous ITO:Yb Films Deposited by Magnetron Co-Sputtering

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초록

Yb-doped ITO (ITO:Yb) films were deposited on unheated non-alkali glass substrates by magnetron cosputtering using two cathodes (DC, RF) equipped with the ITO and Yb2O3 target, respectively. The composition of the ITO:Yb films was controlled by adjusting the RF powers from 0 W to 480 W in 120 W steps with the DC power fixed at 70 W. The ITO:Yb films had a higher crystallization temperature (200ºC) than that of the ITO films (170oC), which was attributed to both larger ionic radius of Yb3+ and higher bond enthalpy of Yb2O3, compared to ITO. This amorphous ITO:Yb film post-annealed at 170oC showed a resistivity of 5.52 × 10−4 Ωcm, indicating that a introduction of Yb increased resistivity of the ITO film. However, these amorphous ITO:Yb films showed a high etching rate, fine pattering property, and a very smooth surface morphology above the crystallization temperature of the amorphous ITO films (about 170ºC). The transmittance of all films was >80% in the visible region.

Abstract

Yb-doped ITO (ITO:Yb) films were deposited on unheated non-alkali glass substrates by magnetron cosputtering using two cathodes (DC, RF) equipped with the ITO and Yb2O3 target, respectively. The composition of the ITO:Yb films was controlled by adjusting the RF powers from 0 W to 480 W in 120 W steps with the DC power fixed at 70 W. The ITO:Yb films had a higher crystallization temperature (200ºC) than that of the ITO films (170oC), which was attributed to both larger ionic radius of Yb3+ and higher bond enthalpy of Yb2O3, compared to ITO. This amorphous ITO:Yb film post-annealed at 170oC showed a resistivity of 5.52 × 10−4 Ωcm, indicating that a introduction of Yb increased resistivity of the ITO film. However, these amorphous ITO:Yb films showed a high etching rate, fine pattering property, and a very smooth surface morphology above the crystallization temperature of the amorphous ITO films (about 170ºC). The transmittance of all films was >80% in the visible region.

참고문헌 (13)

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