본문 바로가기
KERD
논문KCI 등재

Ti6Al4V 합금에 두 종류의 생체활성화 유리 코팅

Coating of two kinds of bioactive glass on Ti6Al4V alloy

1

조회

0

다운로드

0

인용

0

참고문헌

키워드

주제분류재료공학

초록

에나멜 기법을 활용하여 Ti6Al4V 합금에 두 종류의 생체활성화 유리를 코팅하였다. 재료간의 열팽창계수 차이에 의한 열응력을 줄이기 위해 재료간의 열팽창계수의 차가 2 × 10−6/oC 정도 되도록 생체활성화 유리 조성을 선정하였다. 열팽창계수의 차이에도 불구하고 Ti6Al4V 합금과 코팅 유리간에 확산결합에 의해 양호한 부착이 형성되었음을 FE-SEM과EDS 분석으로 확인하였다. 의사체액에 담근 후 코팅 표면에 일반적인 생체활성화 유리와 같은 hydroxycarbonate apatite가형성됨을 FT-IR로부터 확인하였다.

Abstract

Two kinds of bioactive glass were coated on the Ti6Al4V alloy by the enameling technique. In order to reduce the thermal stress due to the difference in expansion coefficient with the alloy with the secondary coating forming hydroxyapatite, the difference in expansion coefficient between the alloy and the two glasses was adjusted at 2 × 10−6 / o C intervals. FE-SEM and EDS analysis showed that good adhesion was formed between the Ti6Al4V alloy and the primary coating by diffusion bonding. After immersion in SBF solution, it was confirmed from FT-IR that hydroxycarbonate apatite formed in the secondary coating was not different from bulk bioactive glass.

참고문헌 (29)

  1. B.D. Ratner, "Titanium in medicine: material science, surface science, engineering, biological responses and medical applications", pp.1~ (2001), Springer
  2. R. Branemark, "Biomechanical characterization of osseointegration during healing: an experimental in vivo study in the rat", Biomaterials, 18, pp.969~ (1997)[DOI]
  3. A.M. Baool, "Implant dentistry - a rapidly evolving practice", pp.19~ (2011), InTech
  4. W. Suchanek, "Processing and properties of hydroxyapatite-based biomaterials for use as hard tissue replacement implants", J. Mater. Res., 13, pp.94~ (1998)[DOI]
  5. S.W. Ha, "Chemical and morphological changes of vacuumplasma-sprayed hydroxyapatite coatings during immersion in simulated physiological solutions", J. Am. Ceram. Soc., 81(1), pp.81~ (1998)
  6. K.A. Gross, "Thermal analysis of amorphous phases in hydroxyapatite coatings", J. Am. Ceram. Soc., 81(1), pp.106~ (1998)
  7. L.L. Hench, "Bioceramics", J. Am. Ceram. Soc., 81(7), pp.1705~ (1998)
  8. R. Boyer, "Materials Properties Handbook: Titanium Alloys", pp.493~ (1994)
  9. D. Bellucci, "Coefficient of thermal expansion of bioactive glasses: available literature data and analytical equation estimates", Ceram. Int., 37, pp.2963~ (2011)[DOI]
  10. R.G. Hill, "Predicting the bioactivity of glasses using the network connectivity or split network models", J. Non-Cryst. Solids, 357, pp.3884~ (2011)[DOI]
  11. D.R. Bloyer, "Fabrication and characterization of a bioactive glass coating on titanium implant alloys", Acta. Meter., 47(15), pp.4221~ (1999)[DOI]
  12. J.M. Gomez-Vega, "Bioactive glass coating with hydroxyapatite and <TEX>$Bioglass^{(R)}$<", TEX> particles on Ti-based implants. 1. Processing, 2000, pp.21, 105~
  13. S. Lopez-Esteban, "Bioactive glass coatings for orthopedic metallic implants", J. Eur. Ceram. Soc., 23, pp.2921~ (2003)[DOI]
  14. H. Ylanen, "Effect of immersion in SBF on porous bioactive bodies made by sintering bioactive glass microspheres", J. Non-Cryst. Solids, 275, pp.107~ (2000)[DOI]
  15. N. Lotfibakhshaiesh, "Bioactive glass engineered coatings for Ti6Al4V alloys: influence of strontium substitution for calcium on sintering behavior", J. Non-Cryst. Solids, 356, pp.2583~ (2010)[DOI]
  16. M. Brink, "The influence of alkali and alkaline earths on the working range for bioactive glasses", J. Biomed. Mater. Res., 36(1), pp.109~ (1997)[DOI]
  17. T. Kokubo, "How useful is SBF in predicting in vivo bone bioactivity", Biomaterials, 27, pp.2907~ (2006)[DOI]
  18. W.D. Kingery, "Factors Affecting Thermal Stress Resistance of Ceramic Materials", J. Am. Ceram. Soc., 38(1), pp.3~ (1955)[DOI]
  19. A.K. Srivastava, "In vitro bioactivity and physical - mechanical properties of <TEX>$Fe_2O_3$<", TEX> substituted 45S5 bioactive glasses and glass-ceramics, 2012, pp.3(2), 1~
  20. S. Lopez-Esteban, "Bioactive glass coatongs for orthopedic metallic implants", J. Eur. Ceram. Soc., 23, pp.2921~ (2003)[DOI]
  21. H. Liu, "An in vitro evaluation of the Ca", P ratio for the cytocompatibility of nano-to-micron particulate calcium phosphates for bone regeneration, 2008, pp.4, 1472~
  22. S.A. MacDonald, "Dispersion analysis of FTIR reflection measurements in silicate glasses", J. Non-Cystal. Solids, 275, pp.72~ (2000)[DOI]
  23. R.V. Santos, "The carbonate content in high-temperature apatite: An analytical method applied to apatite from the Jacupiranga alkaline complex", Am. Mineral., 80, pp.336~ (1995)[DOI]
  24. I. Rehman, "Characterization of hydroxyapatite and carbonated apatite by photo acoustic FTIR spectroscopy", J. Mat. Sci.: Mater. Med., 8, pp.1~ (1997)
  25. R.M. Wilson, "Rietveld refinements and spectroscopic structural studies of a Nafree carbonate apatite made by hydrolysis of monetite", Biomaterials, 27, pp.4682~ (2006)[DOI]
  26. C. Rey, "The carbonate environment in bone mineral: a resolution-enhanced Fourier transform infrared spectroscopy", Calcif. Tissue Int., 45, pp.157~ (1989)[DOI]
  27. I. Lebecq, "Compositional dependence on the in vitro bioactivity of invert or conventional bioglasses in the Si-Ca-Na-P system", J. Biomed. Mater. Res. A, 83, pp.156~ (2007)
  28. M.D. O'Donnell, "The effect of phosphate content on the bioactivity of soda-lime-phosphosilicate glasses", J. Mater. Sci. Mater. Med., 20, pp.1611~ (2009)[DOI]
  29. J. Serra, "FTIR and XPS studies of bioactive silica based glasses", J. Non-Cryst. Solids, 332, pp.20~ (2003)[DOI]

관련 논문AI추천

이 간행물의 다른 논문 (7건)