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국가표준향상과 핵심국제비교를 위한 물의 삼중점 온도 측정

Measurement of triple point of water temperature for improvement of the national standards and key comparison

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초록

The Korea Research Institute of Standards and Science (KRISS), a National Metrology Institute of Korea, participated in the secondround of the international key comparison CCT-K7.2021 of triple point of water (TPW) cells. For the key comparison, three TPW cells, one of which had been used in the old CCT-K7 comparison, were assigned as the national standard of the TPW. The temperature difference (ΔT) between the average of the new and old national standards and ΔT between the new national standard and the transfer standard were measured. The comparison between the new and old national standards indicated a temperature increase of 69.5 µK after both the standards were corrected for the isotopic composition. The uncertainty of the national standard of the TPW temperature was 28 µK, and the uncertainty of ΔT was 14 µK. Three aspects of improvements in the new comparison compared to the old one were noted: (1) inclusion of two quartz cells in the national standard strengthens its long-term stability; (2) the standard deviation associated with the measurement of ΔT was reduced from 21 µK to 9.6 µK; (3) and the measured immersion profile of the TPW cells was much closer to the theoretically predicted dependence.

Abstract

The Korea Research Institute of Standards and Science (KRISS), a National Metrology Institute of Korea, participated in the secondround of the international key comparison CCT-K7.2021 of triple point of water (TPW) cells. For the key comparison, three TPW cells, one of which had been used in the old CCT-K7 comparison, were assigned as the national standard of the TPW. The temperature difference (ΔT) between the average of the new and old national standards and ΔT between the new national standard and the transfer standard were measured. The comparison between the new and old national standards indicated a temperature increase of 69.5 µK after both the standards were corrected for the isotopic composition. The uncertainty of the national standard of the TPW temperature was 28 µK, and the uncertainty of ΔT was 14 µK. Three aspects of improvements in the new comparison compared to the old one were noted: (1) inclusion of two quartz cells in the national standard strengthens its long-term stability; (2) the standard deviation associated with the measurement of ΔT was reduced from 21 µK to 9.6 µK; (3) and the measured immersion profile of the TPW cells was much closer to the theoretically predicted dependence.

참고문헌 (12)

  1. 양인석, "켈빈의 재정의", 한국정밀공학회지, 35(4), pp.399~404 (2018), 한국정밀공학회
  2. H. Preston-Thomas, "international temperature scale of 1990 (ITS-90)", Metrologia, 27(1), pp.3~10 (1990)
  3. M. Stock, "Final report on CCT-K7 : Key Comparison of water triple point cells", Metrologia, 43(1A), pp.03001~ (2006)
  4. 강기훈, "핵심국제비교용 무의 삼중점 셀 제작과 비교 실험 및 불확도 평가", 센서학회지, 13(2), pp.114~120 (2004), 한국센서학회
  5. K. S. Gam, "Isotopic composition of water used in triple-point cells", Int. J. Thermophys, 29(3), pp.808~814 (2008)
  6. S. F. Tsai, "Final report on APMP.T-K7 key comparison of water triple point cells", Metrologia, 53(1A), pp.03004~ (2016)
  7. S. N. Dedyulin, "On the long-term stability of the triple-point-of-water cells", Metrologia, 57(6), pp.065032(1)~065032(11) (2020)
  8. D. R. White, "Measuring the residual air pressure in triplepoint-of-water cells", Meas. Sci. Technol, 15(1), pp.N15~N16 (2003)

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