본문 바로가기
KERD
논문KCI 등재

Ti3C2Tx MXene 기반 전극 소재의 자가 치유 적용 기술 개발 동향

Recent Progress of Ti3C2Tx MXene Electrode Based Self-Healing Application

0

조회

0

다운로드

0

인용

0

참고문헌

키워드

주제분류재료공학

초록

수 나노미터의 두께의 단일 또는 여러 층으로 구성된 2차원 소재는 전기전도성, 유연성, 광학적 투명성 등의 고유한 특성으로 많은 연구 분야에서 활용되고 있다. 이 중 Electronic skin (E-Skin)이나 Smart Textile 과 같은 반복적인 기계적 동작이 수반될 수 있다. 또한, 온도, 습도, 압력과 같은 외부적 요인에 노출이 되는 경우가 빈번하다. 이 때, 소자의 내구성과 수명 저하를 유발하기 때문에 자가 치유 특성이 내포된 소자를 제작하기 위한 연구가 많이 이루어지고 있다. 최근다양한 2차원 소재 중 자가 치유 기능을 구현할 수 있는 Ti3C2Tx MXene 기반 전극의 복합 소재의 연구 결과가 학계의 주목을 받고 있다. 본 논문에서는 Ti3C2Tx MXene의 다양한 합성 방법 및 특성에 대해 소개한 후, Ti3C2Tx MXene 전극 기반의 자가 치유 적용 기술 사례에 대해 알아보고자 한다.

Abstract

Single or multi-layered two-dimensional (2D) materials, with thicknesses in the order of a few nanometers, have garnered substantial attention across diverse research domains owing to their distinct properties, including electrical conductivity, flexibility, and optical transparency. These materials are frequently subjected to repetitive mechanical actions in applications like electronic skin (E-Skin) and smart textiles. Moreover, they are often exposed to external factors like temperature, humidity, and pressure, which can lead to a deterioration in component durability and lifespan. Consequently, significant research efforts are directed towards developing self-healing properties in these components. Notably, recent investigations have revealed promising outcomes in the field of self-healing composite materials, with Ti3C2Tx MXene being a prominent component among the myriad of available 2D materials. In this paper, we aim to introduce various synthesis methods and characteristics of Ti3C2Tx MXene, followed by an exploration of self-healing application technologies based on Ti3C2Tx MXene.

참고문헌 (94)

  1. D. L. Wen, "Recent progress in silk fibroin-based flexible electronics", Microsyst. Nanoeng, 35(7), pp.1~ (2021)
  2. 최수빈, "신축성 전극 기술 개발 동향", 마이크로전자 및 패키징학회지, 26(3), pp.23~26 (2019), 한국마이크로전자및패키징학회
  3. Y. Tomoyuki, "Recent Progress of Flexible Image Sensors for Biomedical Applications", Adv. Mater, 33(19), pp.2004416~ (2021)
  4. S. Terrym, "A review on self-healing polymers for soft robotics", Mater. Today, 47, pp.187~ (2021)
  5. M. Qi, "Bioinspired Self-healing Soft Electronics", Adv. Funct. Mater, 33(17), pp.2214479~ (2023)
  6. P. Bertsch, "Self-Healing Injectable Hydrogels for Tissue Regeneration", Chem. Rev, 123(2), pp.834~ (2022)
  7. S. B. Choi, "Revolutionizing Thermal Stability and Self-Healing in Pressure Sensors : A Novel Approach", Adv. Fiber. Mater (2023)
  8. L. Yang, "Self-Healing, Reconfigurable, Thermal-Switching, Transformative Electronics for Health Monitoring", Adv. Mater, 35(15), pp.2207742~ (2023)
  9. S. Chuangchote, "Self-Healing Carbon Fiber–Reinforced Polymers for Aerospace Applications", Aerosp Sci Technol, 85 (2022)
  10. H. Yin, "A selfhealing hydrogel based on oxidized microcrystalline cellulose and carboxymethyl chitosan as wound dressing material", Int. J. Biol. Macromol, 30, pp.1606~ (2022)
  11. C. Liu, "Self-healing concrete with recycled coarse aggregate : The performance of biochemical-chloride ion transport", J. Build. Eng, 57, pp.104925~ (2022)
  12. J. Jiao, "Self-Healing Mechanism of Lithium in Lithium Metal", Adv. Sci, 9(12), pp.2105574~ (2022)
  13. C. Huang, "Self-Healing SeO2Additives Enable Zinc Metal Reversibility in Aqueous ZnSO4Electrolytes", Adv. Funct. Mater, 32(18), pp.2112091~ (2022)
  14. J. Huang, "Synergistic healing mechanism of self-healing ceramics coating", Ceramics International, 48(5), pp.6520~ (2022)
  15. J. Xiang, "Investigating the potential for porous ceramics as bacterial carrier in selfhealing cemented paste backfill", Ceramics International, 49(9), pp.13490~ (2023)
  16. B. Li, "Intrinsically Self-Healing Polymers : From Mechanistic Insight to Current Challenges", Chem. Rev, 123(2), pp.701~ (2023)
  17. Z. Li, "Shape-Memory and Self-Healing Polymers Based on Dynamic Covalent Bonds and Dynamic Noncovalent Interactions : Synthesis, Mechanism, and Application", ACS Appl. Bio Mater, 4(8), pp.5926~ (2021)
  18. S. W. Cho, "Recent progress in self-healing polymers and hydrogels based on reversible dynamic B–O bonds : boronic", boronate esters, borax, and benzoxaborole, 2021, pp.9, 14630~
  19. T. Jing, "Rapid self-healing and tough polyurethane based on the synergy of multi-level hydrogen and disulfide bonds for healing propellant microcracks", Mater. Chem. Front, 6, pp.1161~ (2022)
  20. Y. Cai, "A room temperature self-healing and thermally reprocessable cross-linked elastomer with unprecedented mechanical properties for ablation-resistant applications", Chem. Eng. J, 436, pp.135156~ (2022)
  21. D. Q. Li, "Fabrication of self-healing pectin", chitosan hybrid hydrogel via Diels-Alder reactions for drug delivery with high swelling property, pH-responsiveness, and cytocompatibility, 2021, pp.268, 118244~
  22. D. Yilmaz, "Combination of permanent hydrosilylation and reversible Diels–Alder reactions for self-healing poly(dimethylsiloxane)materials with enhanced ageing properties", Mater. Today Chem, 24, pp.100860~ (2022)
  23. Y. H. Eom, "Mechanoresponsive hydrogen-bonding array of thermoplastic polyurethane elastomer captures both strength and self-healing", Nat. Commun, 12, pp.621~ (2021)
  24. C. Zhang, "Highly adhesive and self-healing γ-PGA", PEDOT : PSS conductive hydrogels enabled by multiple hydrogen bonding for wearable electronics, 2022, pp.95, 106991~
  25. P. Hu, "Fouling resistant silicone coating with self-healing induced by metal coordination", Chem. Eng. J, 406, pp.126870~ (2021)
  26. C. N. Z. Schmitt, "Role of Sacrificial Protein–Metal Bond Exchange in Mussel Byssal Thread Self-Healing", Biomacromolecules, 16(9), pp.2582~ (2015)
  27. M. Zhu, "Long-Lasting Sustainable Self-Healing Ion Gel with Triple-Network by Trigger-Free Dynamic Hydrogen Bonds and Ion Bonds", ACS Sustain. Chem. Eng, 6(12), pp.17087~ (2018)
  28. X. Wang, "Preparation and research of intrinsic self-healing elastomers based on hydrogen and ionic bond", Compos Sci Technol, 193, pp.108127~ (2020)
  29. W. Yu, "Flexible 2D Materials beyond Graphene : Synthesis, Properties, and Applications", Small, 18(14), pp.2105383~ (2022)
  30. Q. Jiang, "2D materials-based nanomedicine : From discovery to applications", Adv. Drug Deliv. Rev, 185, pp.114268~ (2022)
  31. V. Shanmugam, "A Review of the Synthesis, Properties, and Applications of 2D Materials", Part Part Syst Charact, 39(6), pp.2200031~ (2022)
  32. J. An, "Perspectives of 2D Materials for Optoelectronic Integration", Adv. Funct. Mater, 32(14), pp.2110119~ (2021)
  33. M. Marian, "Roadmap for 2D materials in biotribological", biomedical applications – A review, 2022, pp.307, 102747~
  34. K. S. Novoselov, "Electric Field Effect in Atomically Thin Carbon Films", Science, 306(5696), pp.666~ (2004)
  35. J. Wu, "Graphene oxide for photonics, electronics and optoelectronics", Nat. Rev. Chem, 7, pp.162~ (2023)
  36. Y. Xiao, "Structure modulation of two-dimensional transition metal chalcogenides : recent advances in methodology, mechanism and applications", Chem. Soc. Rev, 52, pp.1215~ (2023)
  37. Y. V. Kaneti, "Borophene : Two-dimensional Boron Monolayer : Synthesis, Properties, and Potential Applications", Chem. Rev, 1(122), pp.1000~ (2022)
  38. A. S. Sethlekshmi, "MoS2 based nanomaterials : Advanced antibacterial agents for future", J Control Release, 348, pp.158~ (2022)
  39. A. E. Naclerio, "A Review of Scalable Hexagonal Boron Nitride(h-BN)Synthesis for Present and Future Applications", Adv. Mater, 35(6), pp.2207374~ (2023)
  40. G. Murali, "A Review on MXene Synthesis, Stability, and Photocatalytic Applications", ACS Nano, 16(9), pp.13370~ (2022)
  41. 최수빈, "Ti3C2TX MXene 기반 유연 전극 기술 개발 동향", 마이크로전자 및 패키징학회지, 29(1), pp.17~33 (2022), 한국마이크로전자및패키징학회
  42. H. Zhang, "Structural changes of Ti3SiC2 induced by helium irradiation with different doses", Appl. Surf. Sci, 434, pp.1210~ (2018)
  43. S. Panda, "MXene based emerging materials for supercapacitor applications : Recent advances, challenges, and future perspectives", Coord Chem Rev, 462, pp.214518~ (2022)
  44. M. Khazaei, "Electronic properties and applications of MXenes : a theoretical review", J. Mater. Chem. C, 5, pp.2488~ (2017)
  45. B. Fu, "MXenes : Synthesis, Optical Properties, and Applications in Ultrafast Photonics", Small, 17(11), pp.2006054~ (2021)
  46. Y. Ibrahim, "The Recent Advances in the Mechanical Properties of Self-Standing Two-Dimensional MXene-Based Nanostructures : Deep Insights into the Supercapacitor", Nanomaterials, 10(10), pp.1916~ (2020)
  47. C. Ma, "Flexible MXene-Based Composites for Wearable Devices", Adv. Funct. Mater, 31(22), pp.2009524~ (2021)
  48. K. Gong, "MXene as emerging nanofillers for high-performance polymer composites : A review", Compos. B. Eng, 217, pp.108867~ (2021)
  49. G. Li, "Graphene based selfhealing materials", Carbon, 146, pp.371~ (2019)
  50. W. Feng, "Shear-thinning and self-healing chitosan-graphene oxide hydrogel for hemostasis and wound healing", Carbohydr. Polym, 294, pp.119824~ (2022)
  51. X. Zhu, "Ultrahigh Mechanical Strength and Robust Room-Temperature Self-Healing Properties of a Polyurethane–Graphene Oxide Network Resulting from Multiple Dynamic Bonds", ACS Nano, 16(10), pp.16724~ (2022)
  52. M. Naguib, "Two-Dimensional Nanocrystals Produced by Exfoliation of Ti3AlC2", Adv. Mater, 23(37), pp.4248~ (2011)
  53. Y. B. Shin, "Ultra-robust bonding between MXene nanosheets and stretchable", Adv. Nano Res, 11(5), pp.453~ (2021)
  54. X. Chen, "N-Butyllithium-Treated Ti3C2Tx MXene with Excellent Pseudocapacitor Performance", ACS Nano, 13(8), pp.9449~ (2019)
  55. V. Natu, "2D Ti3C2Tz MXene Synthesized by Water-free Etching of Ti3AlC2 in Polar Organic Solvents", Chem, 6, pp.613~ (2020)
  56. 56. H. W. Wang, "Resolving the Structure of Ti3C2Tx MXenes through Multilevel Structural Modeling of the Atomic Pair Distribution Function", Chem. Mater, 28(1), pp.349~ (2016)
  57. M. A. Hope, "NMR reveals the surface functionalisation of Ti3C2 MXene", Phys. Chem. Chem. Phys, 18, pp.5099~ (2016)
  58. M. Naguib, "Ten Years of Progress in the Synthesis and Development of MXenes", Adv. Mater, 33(39), pp.2103393~ (2021)
  59. J. Luo, "Pillared Structure Design of MXene with Ultralarge Interlayer Spacing for High-Performance Lithium-Ion Capacitors", ACS Nano, 11(3), pp.2459~ (2017)
  60. J. Come, "Controlling the actuation properties of MXene paper electrodes upon cation intercalation", Nano Energy, 17, pp.27~ (2015)
  61. H. S. Lim, "One-Way Continuous Deposition of Monolayer MXene Nanosheets for the Formation of Two Confronting Transparent Electrodes in Flexible Capacitive Photodetector", ACS Appl. Mater, 13(21), pp.25400~ (2021)
  62. J. Lipton, "Scalable, Highly Conductive, and Micropatternable MXene Films for Enhanced Electromagnetic Interference Shielding", Matter, 3, pp.546~ (2020)
  63. M. Saraf, "Free-Standing α-MoO3", Ti3C2 MXene Hybrid Electrode in Water-in-Salt Electrolytes, 2022, pp.6(4), e12516~
  64. O. Mashtalir, "Amine-Assisted Delamination of Nb2C MXene for Li-Ion Energy Storage Devices", Adv. Mater, 27(23), pp.3501~ (2015)
  65. O. Mashtalir, "Intercalation and delamination of layered carbides and carbonitrides", Nat. Commun, 1716 (2013)
  66. 66. D. A. Qian, "Surface Functional Groups and Electrochemical Behavior in Dimethyl Sulfoxide-Delaminated Ti3C2Tx MXene", Chem-SusChem, 11(21), pp.3719~ (2018)
  67. M. Naguib, "Large-scale delamination of multi-layers transition metal carbides and carbonitrides"MXenes"", Dalton Trans, 44(20), pp.9353~ (2015)
  68. D. Bury, "Photocatalytic Activity of the Oxidation Stabilized Ti3C2Tx MXene in Decomposing Methylene Blue, Bromocresol Green and Commercial Textile Dye", Small, 7(8), pp.2201252~ (2023)
  69. H. Wang, "Surface modified MXene Ti3C2 multilayers by aryl diazonium salts leading to large-scale delamination", Appl. Suf. Sci, 384, pp.287~ (2016)
  70. M. Ghidiu, "Conductive two-dimensional titanium carbide ‘clay’ with high volumetric capacitance", Letters, 516, pp.78~ (2014)
  71. T. G. Oh, "Fast and High-Yield Anhydrous Synthesis of Ti3C2Tx MXene with High Electrical Conductivity and Exceptional Mechanical Strength", Small, 18(46), pp.2203767~ (2022)
  72. Z. Huang, "Green and scalable electrochemical routes for cost-effective mass production of MXenes for supercapacitor electrodes", Carbon Energy, early view (2023)
  73. D. Qu, "An Organic Solvent-Assisted Intercalation and Collection(OAIC)for Ti3C2Tx MXene with Controllable Sizes and Improved Yield", Nanomicro Lett, 13(188) (2021)
  74. J. Xu, "Recent advances in 2D MXenes : preparation, intercalation and applications in flexible devices", J. Mater. Chem. A, 9, pp.14147~ (2021)
  75. A. S. Zeraati, "Improved synthesis of Ti3C2Tx MXenes resulting in exceptional electrical conductivity, high synthesis yield, and enhanced capacitance", Nanoscale, 13(6), pp.3572~ (2021)
  76. H. Chen, "Pristine Titanium Carbide MXene Films with Environmentally Stable Conductivity and Superior Mechanical Strength", Adv. Funct. Mater, 30(5), pp.1906996~ (2020)
  77. T. Hu, "Interlayer coupling in two-dimensional titanium carbide MXenes", Phy. Chem. Chem. Phy, 18(30), pp.20256~ (2016)
  78. K. Hantanasiriakul, "Fabrication of Ti3C2Tx MXene Transparent Thin Films with Tunable Optoelectronic Properties", Adv. Elec. Mater, 2(6), pp.1600050~ (2016)
  79. K. Maleski, "Size-Dependent Physical and Electrochemical Properties of TwoDimensional MXene Flakes", ACS Appl. Mater, 10, pp.24491~ (2018)
  80. L. M. Zang, "The Swiss Immigration to Misiones-Argentina(1935-1939) : An Analysis Based on Migration Theories", Migraciones, 11(9) (2020)
  81. C. L. Idimah, "Recent advancements in electromagnetic interference shielding of polymer and mxene nanocomposites", POLYM-PLAST TECH MAT, 62(1), pp.19~ (2023)
  82. A. H. Najafabadi, "Magnetic-MXene-based nanocomposites for water and wastewater treatment : A review", J. Water Process. Eng, 47, pp.102696~ (2022)
  83. X. Li, "Bio-inspired self-healing MXene", polyurethane coating with superior active, Chem. Eng. J, pp.2023, 454[DOI]
  84. S. Gao, "MXene based flexible composite phase change material with shape memory, selfhealing and flame retardant for thermal management", Compos Sci Technol, 234, pp.109945~ (2023)
  85. K. Zhang, "Self-Healing Ti3C2 MXene", PDMS Supramolecular Elastomers Based on Small Biomolecules Modification for Wearable Sensors, 2020, pp.12, 45306~
  86. E. Calo, "Biomedical applications of hydrogels : A review of patents and commercial products", Eur. Polym. J, 65, pp.252~ (2015)
  87. X. Li, "Healable, Degradable, and Conductive MXene Nanocomposite Hydrogel for Multifunctional Epidermal Sensors", ACS Nano, 15, pp.7765~ (2021)
  88. A. Chae, "Highly Oxidation-Resistant and Self-Healable MXene-Based Hydrogels for Wearable Strain Sensor", Adv. Funct. Mater, 33(24), pp.2213382~ (2023)
  89. H. Zhang, "Ultrastretchable, Self-Healing Conductive Hydrogel-Based Triboelectric Nanogenerators for Human-Computer Interaction", ACS Appl. Mater, 15, pp.5128~ (2023)
  90. J. Stergar, "Review of aerogel-based materials in biomedical applications", J. Solgel. Sci. Technol, 77, pp.738~ (2016)
  91. A. Du, "A Special Material or a New State of Matter : A Review and Reconsideration of the Aerogel", Materials, 6(3), pp.941~ (2013)
  92. Y. Yue, "Highly Self-Healable 3D Microsupercapacitor with MXene-Graphene Composite Aerogel", ACS Nano, 12, pp.4224~ (2018)
  93. W. W. Hu, "Light-actuated shape memory and self-healing phase change composites supported by MXene", waterborne polyurethane aerogel for superior solar-thermal energy storage, 2021, pp.28, 100980~
  94. Y. Cheng, "Maximizing Electron Channels Enabled by MXene Aerogel for High-Performance SelfHealable Flexible Electronic Skin", ACS Nano, 17, pp.1393~ (2023)

관련 논문AI추천

이 간행물의 다른 논문 (14건)