논문KCI 등재
카본우븐패브릭 기반 2D 구조의 Ti3C2Tx 배터리음극소재
2D Layered Ti3C2Tx Negative Electrode based Activated Carbon Woven Fabric for Structural Lithium Ion Battery
0
조회
0
다운로드
0
인용
0
참고문헌
키워드
주제분류재료공학
초록
2D 전이금속 탄화물(MXenes) 가운데, 타이타늄 기반의 Ti3C2는 뛰어난 전기전도성과 전기화학적 특성 및 표면작용기의 영향으로 이차 전지와 슈퍼캐패시터와 같은 에너지저장장치의 유망한 전극 물질로 각광받고 있다. 전극으로서 Ti3C2의 사용은 이온이 반응할 수 있는 표면적을 넓혀줄 뿐만 아니라, 이온의 확산 거리를 줄여주고, 전하의 운동을 향상시켜준다. 이 연구에서, 효율적으로 MAX phase로부터 Ti3C2를 합성하는 방법을 통해 리튬이온배터리에서 MXene기반의 전극 물질을 위한 새로운 방향을 제시하고자 한다.
Abstract
Two dimensional transition metal carbides and/or nitrides, known as MXenes, are a promising electrode material in energy storage due to their excellent electrical conductivity, outstanding electrochemical performance, and abundant functional groups on the surface. Use of Ti3C2 as electrode material has significantly enhanced electrochemical performance by providing more chemically active interfaces, short ion-diffusion lengths, and improved charge transport kinetics. Here, we reports the efficient method to synthesize Ti3C2 from MAX phase, and opens new avenues for developing MXene based electrode materials for Lithium-Ion batteries.
참고문헌 (29)
- Dunn, B., "Electrical Energy Storage for the Grid: A Battery of Choices", Science, 334(6058), pp.928~935 (2011)
- Salanne, M., "Efficient Storage Mechanisms for Building Better Supercapacitors", Nature Energy, 1(6) (2016)
- Nitta, N., "Li-ion Battery Materials:Present and Future", Materials Today, 18(5), pp.252~264 (2015)
- Zhu, J., "Graphene and Graphene-Based Materials for Energy Storage Applications", Small, 10(17), pp.3480~3498 (2014)
- Sheberla, D., "Conductive MOF Electrodes for Stable Supercapacitors with High Areal Capacitance", Nature Energy, 16(2), pp.220~224 (2016)
- Bonaccorso, F., "Graphene, Related Two-dimensional Crystals, and Hybrid Systems for Energy Conversion and Storage", Science, 347(6217) (2015)
- Anasori, B., "2D Metal Carbides and Nitrides (MXenes) for Energy Storage", Nature Reviews Materials, 2(2) (2017)
- Wang, X., "Pseudocapacitance of MXene Nanosheets for High-power Sodium-ion Hybrid Capacitors", Nature Communications, 6(1) (2015)
- Chen, D., "Graphene-like Layered Metal Dichalcogenide", graphene Composites:Synthesis and Applications in Energy Storage and Conversion, 2014, pp.17(4), 184~193
- Pan, H., "Room-temperature Stationary Sodium-ion Batteries for Large-scale Electric Energy Storage", Energy & Environmental Science, 6(8), pp.2338~ (2013)
- Shein, I.R., "Graphene-like Nanocarbides and Nanonitrides of d Metals (MXenes): Synthesis, Properties and Simulation", Micro & Nano Letters, 8(2), pp.59~62 (2013)
- Ivanovskii, A.L., "Graphene-like Transition-metal Nanocarbides and Nanonitrides", Russian Chemical Reviews, 82(8), pp.735~746 (2013)
- Naguib, M., "Two-Dimensional Nanocrystals Produced by Exfoliation of Ti3AlC2", Advanced Materials, 23(37), pp.4248~4253 (2011)
- Li, R., "MXene Ti3C2 : An Effective 2D Light-to-Heat Conversion Material", ACS Nano, 11(4), pp.3752~3759 (2017)
- Xie, Y., "Role of Surface Structure on Li-Ion Energy Storage Capacity of Two-Dimensional Transition-Metal Carbides", Journal of the American Chemical Society, 136(17), pp.6385~6394 (2014)
- Xie, Y., "Prediction and Characterization of MXene Nanosheet Anodes for Non-Lithium-Ion Batteries", ACS Nano, 8(9), pp.9606~9615 (2014)
- Er, D., "Ti3C2MXene as a High Capacity Electrode Material for Metal (Li, Na, K, Ca) Ion Batteries", ACS Applied Materials & Interfaces, 6(14), pp.11173~11179 (2014)
- Peng, Q., "Unique Lead Adsorption Behavior of Activated Hydroxyl Group in Two-Dimensional Titanium Carbide", Journal of the American Chemical Society, 136(11), pp.4113~4116 (2014)
- Dillon, A.D., "Highly Conductive Optical Quality Solution‐Processed Films of 2D Titanium Carbide", Advanced Functional Materials, 26(23), pp.4162~4168 (2016)
- Ghidiu, M., "Conductive Two-dimensional Titanium Carbide ‘clay’ with High Volumetric Capacitance", Nature, 516, pp.78~ (2015)
- Tang, Q., "Are MXenes Promising Anode Materials for Li Ion Batteries? Computational Studies on Electronic Properties and Li Storage Capability of Ti3C2 and Ti3C2X2 (X=F, OH) Monolayer", Journal of the American Chemical Society, 134(40), pp.16909~16916 (2012)
- Yamada, T., "Full Picture Discovery for Mixed-fluorine Anion Effects on Highvoltage Spinel Lithium Nickel Manganese Oxide Cathodes", Journal Article Published in NPG Asia Materials, 9, pp.398~398 (2017)
- Zuo, T. T., "Graphitized Carbon Fibers as Multifunctional 3D Current Collectors for High Areal Capacity Li Anodes", Advanced Materials, 29, pp.1700389~ (2017)
- Hsu, C. H., "Carbon Fibers as Three-Dimensional Current Collectors for Silicon", Reduced Graphene Oxide Lithium Ion Battery Anode with Improved Rate Performance and Cycle Life, 2018, pp.42, 9058~9064
- Chen, P., "Three-dimensional Carbon Fiber as Current Collector for Lithium", sulfur Batteries, 2014, pp.20(6), 803~808
- Anasori, B., "2D Metal Carbides and Nitrides(MXenes)for Energy Storage", Nature Reviews Materials, 2, pp.16098~ (2017)
- Jin, Q., "Rationally Designing S", Ti3C2Tx as a Cathode Material with an Interlayer for High-rate and Long-cycle Lithium–sulfur Batteries, 2018, pp.10, 16935~
- Mendoza-Sánchez, B., "Synthesis of Two-Dimensional Materials for Capacitive Energy Storage", Advanced Mat, 28(29), pp.6104~6135 (2016)
- Yu, X. Q., "Reversible Lithium Storage in LiF", Ti Nanocomposites, 2009, pp.11, 9497~
관련 논문AI추천
Ti3C2TX MXene 기반 유연 전극 기술 개발 동향김종웅, 최수빈, 미나자간싱한국마이크로전자및패키징학회 · 마이크로전자 및 패키징학회지2022 · 제29권 제1호Ti3C2Tx MXene 기반 전극 소재의 자가 치유 적용 기술 개발 동향김종웅, 정승부, 최준상한국마이크로전자및패키징학회 · 마이크로전자 및 패키징학회지2023 · 제30권 제3호차세대 2차원 소재, MXenes의 연구 동향변종민, 윤예준, 이호준, 장진광한국분말재료학회 · 한국분말재료학회지2021 · 제28권 제2호열처리에 의한 Ti 기반 MXene 소재의 구조 변화와 전자파 간섭 차폐 특성에 관한 연구경지수, 슈에한, 우윤성한국마이크로전자및패키징학회 · 마이크로전자 및 패키징학회지2023 · 제30권 제3호펄스전류활성 소결장치를 이용한 MXene 소재 합성송준혁한국기계기술학회 · 한국기계기술학회지2022 · 제24권 제6호2차원 결정성 탄소 소재의 최근 이차전지 소재 개발 동향: 그래핀(graphene)과 그라파인(graphyne)의 이차전지 개발 최근 동향봉성율, 이혁진한국전기화학회 · 전기화학회지2022 · 제25권 제4호