Study on the Phase and Bath Electrochemical Properties in Electrodeposition of ZnS Film
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초록
ZnS does nearly not absorb sun light, it is the most suitable buffer layer material in solar cell. For preparing ZnS film withlow cost, the bath electrochemical performance and the effect of deposition potential on the phase of ZnS films prepared byelectrodeposition were studied under different electrodeposition conditions. The phases and morphology of product films wereinvestigated by X-ray diffraction and scanning electron microscope respectively. Experimental results show that, it was moreconducive to achieve co-deposition using the constant potential method. Compared with thiourea, it is easier to achieve codepositionfor ZnS. ZnS phase can be obtained under −1.0 ~ −1.6 V. When the deposition potential increased, the (100) crystalplane of the highest XRD peak of ZnS phase changed as (101) crystal plane. Well crystallized, dense and uniform ZnS filmcan be obtained under conditions of sodium citrate as complexing agent, sodium thiosulfate as sulfur source, ion ratio of Zincand Sulfide 1 : 5 and −1.2 V.
Abstract
ZnS does nearly not absorb sun light, it is the most suitable buffer layer material in solar cell. For preparing ZnS film withlow cost, the bath electrochemical performance and the effect of deposition potential on the phase of ZnS films prepared byelectrodeposition were studied under different electrodeposition conditions. The phases and morphology of product films wereinvestigated by X-ray diffraction and scanning electron microscope respectively. Experimental results show that, it was moreconducive to achieve co-deposition using the constant potential method. Compared with thiourea, it is easier to achieve codepositionfor ZnS. ZnS phase can be obtained under −1.0 ~ −1.6 V. When the deposition potential increased, the (100) crystalplane of the highest XRD peak of ZnS phase changed as (101) crystal plane. Well crystallized, dense and uniform ZnS filmcan be obtained under conditions of sodium citrate as complexing agent, sodium thiosulfate as sulfur source, ion ratio of Zincand Sulfide 1 : 5 and −1.2 V.
참고문헌 (15)
- M. Adelifard, "Synthesis and characterization of nanostructural CuS-ZnS binary compound thin films prepared by spray pyrolysis", Opt. Commun., 285(21-22), pp.4400~4404 (2012)[DOI]
- L. Qi, "Chemical bath-deposited ZnS thin films: preparation and characterization", Appl. Surf. Sci., 254(18), pp.5711~5714 (2008)[DOI]
- Aixiang Wei, "Preparation and characterization of ZnS thin films prepared by chemical bath deposition", Materials Science in Semiconductor Processing, 16(6), pp.1478~1484 (2013)[DOI]
- Dhanya A C, "Effect of deposition time on optical and luminescence properties of ZnS thin films prepared by photo assisted chemical deposition technique", Materials Science in Semiconductor Processing (2013)
- A. Bahloul, "New composite cathode material for Zn", TEX> cells obtained by electrodeposition of polybithiophene on manganese dioxide particles, pp.Solid State Ionics, 2011[DOI]
- Zhang R, "Growth and properties of ZnS thin films by sulfidation of sputter deposited Zn", Vacuum, 86(8), pp.1210~1214 (2012)[DOI]
- F. Ghribi, "Sputtered ZnS thin film from nanoparticles synthesized by hydrothermal route", Optik - International Journal for Light and Electron Optics, 127(7), pp.3688~3692 (2016)[DOI]
- J. Cui, "Tunable blue and orange emissions of ZnS: Mn thin films deposited on GaN substrates by pulsed laser deposition", J. Lumin., 147, pp.310~315 (2014)[DOI]
- V.L. Gayou, "Structural studies of ZnS thin films grown on GaAs by RF magnetron sputtering", Vacuum, 84(10), pp.1191~1194 (2010)[DOI]
- A. Khare, "Effects of copper concentration on electro-optical and structural properties of chemically deposited nanosized (Zn-Cd)S: Cu films", J. Lumin., 130(7), pp.1268~1274 (2010)[DOI]
- Khaoula Ghezali, "Electrochemical deposition of ZnS thin films and their structural, morphological and optical properties", Journal of Electroanalytical Chemistry, 794, pp.212~220 (2017)[DOI]
- A. Goudarzi, "Ammonia-free chemical bath deposition of nanocrystalline ZnS thin film buffer layer for solar cells", Thin Solid Films, 516(15), pp.4953~4957 (2008)[DOI]
- J. Yuvaloshini, "Effect of annealing on optical and structural properties of ZnS", MnS and MnS, International Journal for Light and Electron Optics, pp.2014, 125(6)[DOI]
- L.M. Zhou, "Influence of deposition temperature on ZnS thin film performance with chemical bath deposition", Surf. Coat. Tech., 228, pp.S146~S149 (2013)[DOI]
- F. Fan, "Investigation on the effect of complexing agents and concentrations on electrodeposition of ZnS film", Applied Mechanics and Materials, 457-458, pp.211~214 (2014)