Phases and morphorlogy of CuFeS2 films prepared by electrodeposition
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This work reports one low-priced ways for production of CuFeS2 films on conductive glass surface. CuFeS2 films wereprepared by electrodeposition and post-sulfurization treatment at 220 oC for 30 h in N2 atmosphere for the first time. CuFeS2films were prepared by electrodeposition with sulfate, ascorbic acid, complexing agent sodium citrate as raw materials. Whenthe deposition potential is -1.0 V and the deposition time is 20 min, CuFeS2 thin films with good phrase formation can beobtained at pH 4 and 0.02M Na2S2O3·H2O. The phase of samples were characterized using X-ray diffraction (XRD). Themorphology of samples were characterized via scanning electron microscopy (SEM). The composition of samples werecharacterized by energy dispersive spectrometer (EDS). The crystallinity of CuFeS2 thin films prepared under these conditionsare relatively good. The microcosmic morphology of the samples is flaky crystal. It is shows that post-sulfurization method ishelpful for the phase formation of CuFeS2 films electrodeposited.
Abstract
This work reports one low-priced ways for production of CuFeS2 films on conductive glass surface. CuFeS2 films wereprepared by electrodeposition and post-sulfurization treatment at 220 oC for 30 h in N2 atmosphere for the first time. CuFeS2films were prepared by electrodeposition with sulfate, ascorbic acid, complexing agent sodium citrate as raw materials. Whenthe deposition potential is -1.0 V and the deposition time is 20 min, CuFeS2 thin films with good phrase formation can beobtained at pH 4 and 0.02M Na2S2O3·H2O. The phase of samples were characterized using X-ray diffraction (XRD). Themorphology of samples were characterized via scanning electron microscopy (SEM). The composition of samples werecharacterized by energy dispersive spectrometer (EDS). The crystallinity of CuFeS2 thin films prepared under these conditionsare relatively good. The microcosmic morphology of the samples is flaky crystal. It is shows that post-sulfurization method ishelpful for the phase formation of CuFeS2 films electrodeposited.
참고문헌 (22)
- N. Wu, , J. Solid State Chem., 271, pp.292~297 (2019)
- E. Bastola, , Randy J Ellingson. MRS Commun, 8(3), pp.970~978 (2018)
- S. Sil, , J. Mater. Eng. Perform., 27(6), pp.2649~2654 (2018)
- B. Korzun, , J. Electron. Mater., 48(5), pp.3351~3354 (2019)
- K. M. Deen, , Electrochim. Acta, 297, pp.1079~1093 (2019)
- Q. Jiang, , Sol. Enrgy, 179, pp.59~66 (2019)
- I. S. Lyubutin, , ACTA Mater, 61(11), pp.3956~3962 (2013)
- K. M. Deen, , Electrochimica. Acta, 212, pp.979~991 (2016)
- K. Liu, , Results. Phys., 11, pp.749~754 (2018)
- L. Barkat, , J. Cryst. Growth, 297(2), pp.426~431 (2006)
- P. Kumar, , Chem. Commun., 49(66), pp.7316~7318 (2013)
- Y. -H. A. Wang, , Solid State Sci., 12(3), pp.387~390 (2010)
- D. Liang, , J. Mater. Sci., 51(11), pp.5412~5420 (2016)
- H. Yu, , J. Mater. Sci.: Mater. Electron., 30(13), pp.12269~12274 (2019)
- Jicheng Zhou, "Preparation and characterization of Cu2FeSnS4 thin films for solar cells via a co-electrodeposition method", Current Applied Physics, 19(2), pp.67~71 (2019), 한국물리학회[DOI]
- N. Poloko, , Procedia Manufacturing, 35, pp.488~493 (2019)
- A. O. Moghaddam, , J. Alloy. Compd., 773, pp.1064~1074 (2019)
- Se Hoon Kim, "Influence of surface roughness on the efficiency of a flexible organic solar cell", Journal of Ceramic Processing Research, 21(1), pp.42~49 (2020), 청정에너지연구소[DOI]
- Guan-Lin Chiu, "Influence of doping iron ions into Cu(In,Ga)Se2 films in the morphology and photovoltaic properties of thin-film solar cells", Journal of Ceramic Processing Research, 18(10), pp.754~759 (2017), 청정에너지연구소[DOI]
- K. Liu, , Results. Phys., 12, pp.766~770 (2019)
- K. Liu, , Cryst. Res. Technol., 53(2), pp.1700203~ (2018)
- Kegao Liu, "Study on the Phase and Bath Electrochemical Properties in Electrodeposition of ZnS Film", Journal of Ceramic Processing Research, 19(2), pp.146~149 (2018), 청정에너지연구소[DOI]