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3C-SiC 광기전 특성 기반 광학식 수소센서의 제작과 그 특성

Fabrication of an Optical Hydrogen Sensor Based on 3C-SiC Photovoltaic Effect and Its Characteristics

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초록

This paper presents the optical hydrogen sensor based on transparent 3C-SiC membrane and photovoltaic effect. Gasochromic materials of Pd and Pd/WO3 were deposited by sputter on 3C-SiC membrane for gas sensing area. Gasochromic materials change to transparency by exposure to hydrogen. The variations of light intensity by hydrogen generate the photovoltaic of P-N junction between N-type 3C-SiC and P-type Si. Single layer of Pd shows higher photovoltaic compared with Pd/WO3. However, phase transition from to is shown at 6 %. Pd/WO3 structure show the more linear response to hydrogen range of 2 % 10 %. Also, almost 2 times fast response and recovery characteristics are shown at Pd/WO3. These fast performances are come from the fact that Pd promoted the chemical reaction between hydrogen and WO3.

Abstract

This paper presents the optical hydrogen sensor based on transparent 3C-SiC membrane and photovoltaic effect. Gasochromic materials of Pd and Pd/WO3 were deposited by sputter on 3C-SiC membrane for gas sensing area. Gasochromic materials change to transparency by exposure to hydrogen. The variations of light intensity by hydrogen generate the photovoltaic of P-N junction between N-type 3C-SiC and P-type Si. Single layer of Pd shows higher photovoltaic compared with Pd/WO3. However, phase transition from to is shown at 6 %. Pd/WO3 structure show the more linear response to hydrogen range of 2 % 10 %. Also, almost 2 times fast response and recovery characteristics are shown at Pd/WO3. These fast performances are come from the fact that Pd promoted the chemical reaction between hydrogen and WO3.

참고문헌 (7)

  1. 한상도, "수소센서 기술의 고찰과 최근동향", 센서학회지, 19(2), pp.67~86 (2010), 한국센서학회
  2. D. K. Benson, "Low-cost, fiber-optic hydrogen gas detector using guided-wave, surface-plasmon resonance in chemochromic thin films", Proc. SPIE-Int. Soc. Opt. Eng (1999)
  3. D. Nau, "Hydrogen sensor based on metallic photonic crystal slabs", Opt. Lett, 35, pp.3150~3152 (2010)
  4. V. Palmisano, "An optical hydrogen sensor based on Pd-capped Mg thin film wedge", Int. Hyd. energy, 35, pp.12574~12578 (2010)
  5. B. S. Richards, "3C-SiC as a future photovoltaic material", 3rd world conf. Photovoltaic energy conversion, pp.2738~2741 (2003)
  6. K. S. Kim, "Effects of illumination on capacitance characteristics of Au", 3C-SiC, Al diode, pp.J. Alloy. Comp, 2011[DOI]
  7. K. Kalli, "Characterization of reflectivity inversion, α-and β-phase transitions and nanostructure formation in hydrogen activated thin Pd films on silicon based substrates", J. Appl. Phys, vol, 91, pp.3829~3840

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