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전자선에 의해 제조된 나노 clay 함유 에폭시 수지의 특성

Characterization of Epoxy Resin Containing Nano Clay Prepared by Electron Beam

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초록

Epoxy resin is widely used as aerospace, automobile, construction and electronics dueto their good mechanical and electrical properties and environmental advantages. However, theinherent flammability of epoxy resin has limited its application in some field where good flameretardancy is required. Nano clay can enhance the properties of polymers such as flames retardancyand thermal stability. In this study, we have investigated the nanoclay filled epoxy composite,which has good flame retardancy while maintaining high mechanical properties. The curedepoxy resins were obtained using an electron beam curing process. The nano clays were dispersedin epoxy acrylate solution and mechanically stirred. The prepared mixtures were irradiated usingan electron beam accelerator. The composites were characterized by gel content and thermal/mechanical properties. Moreover, the flammability of the composite was evaluated by limitedoxygen index (LOI). The flame retardancy of nano clay filled epoxy composite was evidentlyimproved.

Abstract

Epoxy resin is widely used as aerospace, automobile, construction and electronics dueto their good mechanical and electrical properties and environmental advantages. However, theinherent flammability of epoxy resin has limited its application in some field where good flameretardancy is required. Nano clay can enhance the properties of polymers such as flames retardancyand thermal stability. In this study, we have investigated the nanoclay filled epoxy composite,which has good flame retardancy while maintaining high mechanical properties. The curedepoxy resins were obtained using an electron beam curing process. The nano clays were dispersedin epoxy acrylate solution and mechanically stirred. The prepared mixtures were irradiated usingan electron beam accelerator. The composites were characterized by gel content and thermal/mechanical properties. Moreover, the flammability of the composite was evaluated by limitedoxygen index (LOI). The flame retardancy of nano clay filled epoxy composite was evidentlyimproved.

참고문헌 (20)

  1. Alessia S, "E-beam curing of epoxy-based blends in order to produce high-performance composites", Radiat. Phys. Chem, 76, pp.1308~1311 (2007)
  2. Chen X, "Flammability and Thermal Degradation of Epoxy Acrylate Modified with Phosphorus-Containing Compounds", J. Appl. Polym. Sci, 115, pp.3332~3338 (2010)
  3. Cho MS, "Polymer nanocomposites using nano clay", Prospective Industrial Chem, 9, pp.22~36 (2006)
  4. 최용석, "고분자-점토 나노복합체 이해와 향후 연구 방향", Korean Chemical Engineering Research(HWAHAK KONGHAK), 46(1), pp.23~36 (2008), 한국화학공학회
  5. Chun HA, "The epoxy resin for the semiconductor packaging", Polym. Sci. Technol, 24, pp.10~16 (2013)
  6. Dai G, "Damage evolution in nano-clay-reinforced polymers : A three-dimensional computational study", Compos. Sci. Tecnol, 74, pp.63~77 (2013)
  7. Hemly S, "Tensile fatigue behavior of tapered glass fiber reinforced epoxy composites containing nanoclay", Compos. Sci. Technol, 102, pp.10~19 (2014)
  8. Jang BN, "Research trends of flame retardant and flame retardant resin", Polym. Sci. Technol, 20, pp.8~15 (2009)
  9. Khan SU, "Fatigue damage behaviors of carbon fiber-reinforced epoxy composites containing nanoclays", Compos. Sci. Technol, 70, pp.2077~2085 (2010)
  10. 이재락, "에폭시 수지의 전자선 및 열경화 특성에 관한 연구", 폴리머, 26(1), pp.80~87 (2002), 한국고분자학회
  11. Levchik SV, "Thermal decomposition, combustion and flame-retardancy of epoxy resins-a review of the recent literature", Polym. Int, 53, pp.1901~1929 (2004)
  12. Lopataa VJ, "Electron-beam-curable epoxy resins for the manufacture of high-performance composites", Radiat. Phys. Chem, 56, pp.405~415 (1999)
  13. 박종석, "Effects of a Radiation Crosslinking on a Drawn Microporous HDPE Film with a Nucleating Agent", Macromolecular Research, 17(8), pp.580~584 (2009), 한국고분자학회
  14. 박수진, "양이온 개시제 함량이 2관능성 에폭시 수지의 Electron-beam 경화에 미치는 효과", 대한화학회지, 47(3), pp.250~256 (2003), 대한화학회
  15. 신범식, "HDPE", EPDM, Triphenyl Phosphate 블렌드의 상용화제 첨가에 따른 난연성 및 기계적 물성 연구, pp.폴리머, 2012[DOI]
  16. Shin T, "Electron beam curing of acrylated epoxy resins for anisotropic conductive film application", Thin Solid Films, 547, pp.246~249 (2013)
  17. Wang L, "Preparation, morphology and thermal", mechanical properties of epoxy, Compos. Part A, pp.2006, 37[DOI]
  18. Yen YY, "Synergistic flame retardant effect of metal hydroxide and nanoclay in EVA composites", Polym. Degrad. Stabil, 97, pp.863~869 (2012)
  19. 유혜련, "에폭시 복합체의 난연 특성에 미치는 불소화 일라이트의 영향", 폴리머, 35(1), pp.47~51 (2011), 한국고분자학회
  20. Zhang W, "The influence of the phosphorus-based flame retardant on the flame retardancy of the epoxy resins", Polym. Degrad. Stabil, 109, pp.209~217 (2014)

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