전자빔에 의하여 가교된 EVA/HDPE 복합재료의 제조 및 평가
Preparation and Characterization of EVA/HDPE Composites Crosslinked by Electron Beam Irradiation
2
조회
0
다운로드
4
인용
0
참고문헌
키워드
초록
The preparation and characterization of poly(ethylene-co-vinyl acetate)/high-densitypolyethylene (EVA/HDPE) composites crosslinked by electron beam irradiation were investigated inthis study. Matrix resins (EVA and HDPE) and additives, such as flame retardant, antioxidant, andlubricant, were melt-mixed and then were compression molded in a hot-press molder to obtain thesheet-type samples. The prepared sheets were electron beam-irradiated at various absorbed dosesof 50~200 kGy in air. The gel contents, mechanical and thermal properties, and flame retardancywere evaluated. As a result, the gelation content, flame-retardancy, thermal, and mechanicalproperties were found to be increased by electron beam irradiation. These results indicate thatelectron beam irradiation is a powerful tool to prepare high-performance polymer composites dueto its advantages such as no use of toxic chemicals, simple, controllable, and fast process.
Abstract
The preparation and characterization of poly(ethylene-co-vinyl acetate)/high-densitypolyethylene (EVA/HDPE) composites crosslinked by electron beam irradiation were investigated inthis study. Matrix resins (EVA and HDPE) and additives, such as flame retardant, antioxidant, andlubricant, were melt-mixed and then were compression molded in a hot-press molder to obtain thesheet-type samples. The prepared sheets were electron beam-irradiated at various absorbed dosesof 50~200 kGy in air. The gel contents, mechanical and thermal properties, and flame retardancywere evaluated. As a result, the gelation content, flame-retardancy, thermal, and mechanicalproperties were found to be increased by electron beam irradiation. These results indicate thatelectron beam irradiation is a powerful tool to prepare high-performance polymer composites dueto its advantages such as no use of toxic chemicals, simple, controllable, and fast process.
참고문헌 (27)
- Albano C, "Characterization of gamma irradiated PEs using ESR, FTIR and DSC techniques", Polym. Bull., 51(2), pp.135~142 (2003)
- Bahattab MA, "Cross-linked poly (ethylene vinyl acetate) (EVA)", low density polyethylene (LDPE), Polym. Bull, pp.2010, 64(6)[DOI]
- Bee ST, "Effects of montmorillonite on the electron beam irradiated alumina trihydrate added polyethylene and ethylene vinyl acetate nanocomposite", Polym. Compos, 33(11), pp.1883~1892 (2012)
- copolymer) blends containing alumina trihydrate, "J. Vinyl Addit. Technol", 2014, 91~98
- Bee ST, "Dispersion and roles of montmorillonite on structural, flammability, thermal and mechanical behaviours of electron beam irradiated flame retarded nanocomposite", Compos. B. Eng, 61, pp.41~48 (2014)
- Bee ST, "Effects of electron beam irradiation on the structural properties of polylactic acid", polyethylene blends, 2014, pp.334, 18~27
- Cao R, "Effect of EVA on thermal stability, flammability, mechanical properties of HDPE", EVA, IOP Conf. Ser.: Mater. Sci. Eng, pp.2017, 213(1)[DOI]
- Cárdenas MA, "Mechanical and fire retardant properties of EVA", clay, Polym. Degrad. Stabil, pp.2008, 93(11)[DOI]
- Chowdhury SR, "Tensile, flexural and morphological properties of electron beam-crosslinked LDPE-EPDM blends", Plast. Rubber Compos, 44(10), pp.440~448 (2015)
- blends, "Polym. Int", 2005, 686~691
- Datta SK, "Effect of electron beam radiation on mechanical and electrical properties of poly(ethylene-co-vinyl acetate)", Die Angew. Makromol. Chem, 238(1), pp.105~117 (1996)
- Gheysari D, "The effect of high-energy electron beam on mechanical and thermal properties of LDPE and HDPE", Eur. Polym. J., 37(2), pp.295~302 (2001)
- 임종수, "다양한 전자선 전류 조건에서 조사된 폴리에틸렌 분리막의 특성 연구", 폴리머, 34(1), pp.74~78 (2010), 한국고분자학회
- Ismail H, "The effect of trimethylol propane tetraacrylate (TMPTA)and organoclay loading on the properties of electron beam irradiated ethylene vinyl acetate (EVA)", natural rubber (SMR L), J. Appl. Polym. Sci, pp.2010, 117(2)[DOI]
- Lu H, "Influence of gamma irradiation on high density polyethylene", ethylene-vinyl acetate, Polym. Adv. Technol, pp.2004, 15(10)[DOI]
- Liu H, "The effects of irradiation cross-linking on the thermal degradation and flame-retardant properties of the HDPE", EVA, Radiat. Phys. Chem, pp.2009, 78(11)[DOI]
- Ma Y, "Combustion characteristics and thermal properties of high-density polyethylene", ethylene vinyl-acetate copolymer blends containing magnesium hydroxide, 2017, pp.30(10), 1393~1413
- Murray KA, "The effects of high energy electron beam irradiation on the thermal and structural properties of low density polyethylene", Radiat. Phys. Chem., 81(8), pp.962~966 (2012)
- Oyama HT, "Influence of the polymer", inorganic filler interface on the mechanical, thermal, and flame retardant properties of polypropylene, J. Macromol. Sci. Part B-Phys, pp.2011, 50(3)[DOI]
- Sabet M, "Mechanical, thermal and electrical properties of ethylene vinyl acetate irradiated by an electron-beam", Polym.-Plast. Technol. Eng, 49(6), pp.589~594 (2010)
- Sabet M, "Electron beam irradiation of low density polyethylene", ethylene vinyl acetate filled with metal hydroxides for wire and cable applications, 2012, pp.97(8), 1432~1437
- Sabet M, "Electron-beam irradiation of low density polyethylene", ethylene vinyl acetate blends, 2013, pp.33(2), 149~161
- Sabet M, "Thermal stability and flame-retardant characteristic of irradiated LDPE and composites", Bull. Mat. Sci, 43(1), pp.1~8 (2020)
- Suzanne M, "Flame extinction properties of solids obtained from limiting oxygen index tests", Combust. Flame, 161(1), pp.288~294 (2014)
- Wang B, "Comparative study on the effect of electron beam irradiation on the physical properties of ethylene-vinyl acetate copolymer composites", Radiat. Phys. Chem, 97, pp.284~291 (2014)
- Witkowski A, "The influence of metal hydroxide fire retardants and nanoclay on the thermal decomposition of EVA", Polym. Degrad. Stabil, 97(11), pp.2231~2240 (2012)
- Xu ZS, "Synergistic flame retardant effects between aluminum hydroxide and halogen-free flame retardants in high density polyethylene composites", Procedia Eng, 135, pp.631~636 (2016)
