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Effects of Oxygen Plasma Treatment on the Wettability of Polypropylene Fabrics

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초록

The objective of this study is to give PP(polypropylene) fabric a good affinity for water. Oxygen plasma wastreated to PP fabrics in a commercial glow discharge reactor with different RF power, discharge pressure, and reactiontime. The PP fiber surfaces were characterized by the measurement of contact angle and ESCA. A JEOL scanning electronmicroscope was used to observe the surface morphology of fibers. The spontaneous water uptake amount of PP fabricswas determined by the demand wettability test. To determine the effect of aging on the surface properties of O2plasma treated PP, all the above measurements of the samples were carried out after 1, 7, 30, 60, and 150 days. Theresults are as follows. The PP fiber surfaces treated by O2 plasma treatment have a chemical composition that consistedof various oxygen containing polar groups. Consequently, the contact angles of the treated PP fibers decreased, whichimproved the water uptake rate of PP fabrics. Surface roughness of the treated PP affected the fabric wettabiity as well. Wettability of the treated PP decreased and leveled off with aging. The O2 plasma treatment is a simple and effectivemethod to increase the water uptake rate of PP fabrics.

Abstract

The objective of this study is to give PP(polypropylene) fabric a good affinity for water. Oxygen plasma wastreated to PP fabrics in a commercial glow discharge reactor with different RF power, discharge pressure, and reactiontime. The PP fiber surfaces were characterized by the measurement of contact angle and ESCA. A JEOL scanning electronmicroscope was used to observe the surface morphology of fibers. The spontaneous water uptake amount of PP fabricswas determined by the demand wettability test. To determine the effect of aging on the surface properties of O2plasma treated PP, all the above measurements of the samples were carried out after 1, 7, 30, 60, and 150 days. Theresults are as follows. The PP fiber surfaces treated by O2 plasma treatment have a chemical composition that consistedof various oxygen containing polar groups. Consequently, the contact angles of the treated PP fibers decreased, whichimproved the water uptake rate of PP fabrics. Surface roughness of the treated PP affected the fabric wettabiity as well. Wettability of the treated PP decreased and leveled off with aging. The O2 plasma treatment is a simple and effectivemethod to increase the water uptake rate of PP fabrics.

참고문헌 (11)

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  2. Kan, C. W., "Effect of atmospheric pressure plasma treatment on wettability and dryability of synthetic textile fibre", Surface and Coatings Technology, 228, pp.607~610 (2013)
  3. Kosaraju, P. B., "Interfacially polymerized thin film composite membranes on microporous polypropylene supports for solvent-resistant nanofiltration", Journal of Membrane Science, 321(2), pp.155~161 (2008)
  4. Lei, M. K., "Controllable wettability of poly(ethylene terephthlate) film modified by oxygen combined inductively and capacitively coupled radio-frequency plasma", Applied Surface Science, 257(16), pp.7350~7358 (2011)
  5. Liu, Z., "Atmospheric air plasma treated PBO fibers: Wettability, adhesion and aging behaviors", Vacuum, 92, pp.13~19 (2013)
  6. Miller, B., "Spontaneous transplanar uptake of liquids by fabrics", Textile Research Journal, 54, pp.706~712 (1984)
  7. Miller, B., "Methodology for studying the wettability of filament", Textile Research Journal, 45, pp.359~365 (1975)
  8. Sarmadi, A. M., "Surface modification of polypropylene fabrics by acrylonitrile cold plasma", Textile Research Journal, 63(12), pp.697~705 (1993)
  9. Tsai, P. P., "Surface modification of fabric using a one-atmosphere glow discharge plasma to improve fabric wettability", Textile Research Journal, 67(5), pp.359~369 (1997)
  10. 원종일, "폴리프로필렌 복합소재의 아르곤 플라즈마 처리로 표면층 제거와 젖음성 향상", 폴리머, 36(4), pp.461~469 (2012), 한국고분자학회
  11. Yasuda, T., "Effects of glow discharge on fibers and fabrics", Journal of Applied Polymer science : Applied Polymer symposium, 38, pp.201~214 (1984)

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