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BCl₃/Cl₂/Ar 플라즈마에서의 Na0.5K0.5NbO3 박막의 표면반응

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키워드

주제분류기계공학

초록

The etch of (Na0.5K0.5)NbO3 (NKN) thin film was performed in BCl₃/Cl₂/Ar inductively coupled plasma. It was found that the 1sccm addition BCl₃ (5%) into Cl₂2/Ar plasma caused a non-monotonic behavior of the NKN etch rate. The maximum etch rate of NKN was 95.3 nm/min at BCl₃ (1sccm)/Cl₂ (16 sccm)/Ar (4 sccm), 800 W ICP power, 1 Pa pressure and 400 W bias power. The NKN etch rate shows a monotonic behavior as the bias power increases. The analysis of the narrow scan spectra of XPS for both as-deposited and etched NKN films allowed one to assume ion assisted etch mechanism. The most probable reason for the maximum etch rate can be defined as a concurrence of chemical and physical etch pathways.

Abstract

The etch of (Na0.5K0.5)NbO3 (NKN) thin film was performed in BCl₃/Cl₂/Ar inductively coupled plasma. It was found that the 1sccm addition BCl₃ (5%) into Cl₂2/Ar plasma caused a non-monotonic behavior of the NKN etch rate. The maximum etch rate of NKN was 95.3 nm/min at BCl₃ (1sccm)/Cl₂ (16 sccm)/Ar (4 sccm), 800 W ICP power, 1 Pa pressure and 400 W bias power. The NKN etch rate shows a monotonic behavior as the bias power increases. The analysis of the narrow scan spectra of XPS for both as-deposited and etched NKN films allowed one to assume ion assisted etch mechanism. The most probable reason for the maximum etch rate can be defined as a concurrence of chemical and physical etch pathways.

참고문헌 (11)

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  4. C. R Cho, , Appl. Phy. Lett, 80, pp.3171~ (2002)
  5. C. M. Kang, , Ferroelectrics, 357, pp.179~ (2007)
  6. S. J. Yun, , 82, pp.1198~ (2008)
  7. E. Meeks, , J. Vac. Sci. Technol. A, 16, pp.2227~ (1998)
  8. H. S. Kim, , J. Vac. Sci. Technol. A, 17, pp.2214~ (1999)
  9. M. S. Kim, , Microele. Eng, 84, pp.348~ (2008)
  10. D. R. Lide, "Handbook of Chemistry and Physics", pp.4~74 (1998), CRC Press
  11. J. Chastain, "Handbook of X-ray Photoelectron Spectroscopy" (1992), Perkin Elmer

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