전자선 조사에 의해 제조된 라돈 차폐용 ethylene vinyl acetate/silicone 에멀젼의 물리적 특성 평가
Evaluation of Physical Properties of Ethylene Vinyl Acetate/Silicone Emulsion for Radon Shielding Prepared by Electron-beam Irradiation
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R adon, a carcinogenic substance generated from soil or building materials, have tobe fundamentally blocked from entering indoors. In this study, ethylene vinyl acetate (EVA)/siliconeemulsions with excellent mechanical and thermal properties and effective blocking of radon gas wereprepared by using radiation technology. As the electron-beam irradiation does increased, a partiallycrosslinked structure was formed in EVA molecular chain, increasing tensile properties and adhesivestrength. The EVA/silicone film showed excellent thermal stability without deformation. In addition, thenon-irradiated EVA/silicone film showed a radon blocking rate of about a 75%, while the EVA/silicone filmirradiated with 3 and 5 kGy showed an excellent radon blocking rate of over 90% due to the formation ofcrosslinked structure in the EVA molecular chain. These results indicated that the radiation technologycan effectively block radon by forming a partially crosslinked structure of EVA/silicone emulsion toimprove tensile property, adhesive strength, and deformation stability.
Abstract
R adon, a carcinogenic substance generated from soil or building materials, have tobe fundamentally blocked from entering indoors. In this study, ethylene vinyl acetate (EVA)/siliconeemulsions with excellent mechanical and thermal properties and effective blocking of radon gas wereprepared by using radiation technology. As the electron-beam irradiation does increased, a partiallycrosslinked structure was formed in EVA molecular chain, increasing tensile properties and adhesivestrength. The EVA/silicone film showed excellent thermal stability without deformation. In addition, thenon-irradiated EVA/silicone film showed a radon blocking rate of about a 75%, while the EVA/silicone filmirradiated with 3 and 5 kGy showed an excellent radon blocking rate of over 90% due to the formation ofcrosslinked structure in the EVA molecular chain. These results indicated that the radiation technologycan effectively block radon by forming a partially crosslinked structure of EVA/silicone emulsion toimprove tensile property, adhesive strength, and deformation stability.
참고문헌 (26)
- 김임순, "환경영향평가 단계에서의 라돈 관리에 대한 연구", 환경영향평가, 27(3), pp.241~250 (2018), 한국환경영향평가학회
- Kulalı F, "Determination of indoor radon levels at campuses of Üsküdar and Okan Universities", Int. J. Environ. Sci. Technol, 16(9), pp.5281~5284 (2019)[DOI]
- Mustafa Al-Zoughool, "Health effects of radon: A review of the literature", International Journal of Radiation Biology, 85(1), pp.57~69 (2009), Informa UK Limited[DOI]
- Hassanvand H, "Indoor radon measurement in dwellings of Khorramabad City", Iranian J. Med. Phys, 15(1), pp.19~27 (2018)[DOI]
- 박훈채, "건축자재로부터 방출되는 라돈의 실내 확산에 대한 수치해석적 연구", 대한환경공학회지, 36(5), pp.325~332 (2014), 대한환경공학회[DOI]
- Hori N, "Effect of the ethylene", vinyl acetate ratio of ethylene-vinyl acetate emulsion on the curing behavior of an emulsion polymer isocyanate adhesive for wood, 2008, pp.54, 294~299
- Poljanšek I, "Emulsion copolymerization of vinyl acetate-ethylene in high pressure reactor-characterization by inline FTIR spectroscopy", Prog. Org. Coat, 76(12), pp.798~1804 (2013)[DOI]
- Azizi S, "Electrical and thermal conductivity of ethylene vinyl acetate composite with graphene and carbon black filler", Polym. Test, 72, pp.24~31 (2018)[DOI]
- Chitra, "Structural composition and thermal stability of extracted EVA from silicon solar modules waste", Sol. Energy, 211(2020), pp.74~81 (2020)[DOI]
- Mészáros L, "The effect of EVA content on the processing parameters and the mechanical properties of LDPE", ground tire rubber blends, 2008, pp.48(5), 868~874
- A.M. Henderson, "Ethylene-vinyl acetate (EVA) copolymers: a general review", IEEE Electrical Insulation Magazine, 9(1), pp.30~38 (1993), Institute of Electrical and Electronics Engineers (IEEE)[DOI]
- Rosdi MRH, "Evaluation of flow ability response in EVA emulsion preparation with different vinyl acetate percentage by intrinsic viscosity measurement", Procedia Chem, 19(2016), pp.455~461 (2016)[DOI]
- Hirschl C, "Determining the degree of crosslinking of ethylene vinyl acetate photovoltaic module encapsulants-A comparative study", Sol. Energy Mater. Sol. Cells, 116(2013), pp.203~218 (2013)[DOI]
- Zeng F, "Non-isothermal crosslinking of ethylene vinyl acetate initiated by crosslinking agents : kinetic modelling", RSC Adv, 12(2022), pp.15623~15630 (2022)[DOI]
- Kaltenegger-Uray A, "Physical Foaming and Crosslinking of Polyethylene with Modified Talcum", Polymers, 11(2019), pp.1472~ (2019)[DOI]
- Mbarek M, "The effect of cross-linking yield of PVK on the vibrational and emissive properties of new copolymer based on vinylcarbazole and phenylene-vinylene units", J. Mol. Struct, 1120(2016), pp.125~131 (2016)[DOI]
- Kazemi-Najafi S, "Effect of Highly Degraded High-Density Polyethylene(HDPE)on Processing and Mechanical Properties of Wood Flour-HDPE Composites", J. Appl. Polym. Sci, 129(6), pp.3404~3410 (2013)[DOI]
- Jeong JO, "Optimization of the Physical Properties of HDPE", PU Blends through Improved Compatibility and Electron Beam Crosslinking, 2022, pp.14(2022), 3607~
- 신재환, "전자빔 조사에 의한 폴리(에틸렌-co-초산비닐)", 고밀도 폴리에틸렌, 방사선산업학회지, pp.2022, 16(3)[DOI]
- Zhang Y, "Thermal Stability and Mechanical Property of Vinyl-Functionalized Polyborosiloxane and Silicone Rubber", J. Phys. : Conf. Ser, 1637(1), pp.012051~ (2020)[DOI]
- Han R, "Research on the preparation and thermal stability of silicone rubber composites : A review", Compos. Pt. C-Open Access, 8(2022), pp.100249~ (2022)[DOI]
- 박종석, "방사선에 의해 제조된 폴리아크릴산", 실리콘 하이드로겔의 첨가제 종류 및 함량에 따른 물리적 특성 평가, 2020, pp.14(4), 327~333[DOI]
- Fuke CA, "Modified ethylene-propylene-diene elastomer(EPDM)-contained silicone rubber", ethylene-propylene-diene elastomer(EPDM)blends : Effect of composition and electron beam crosslinking on mechanical, heat shrinkability, electrical, and morphological properties, 2019, pp.136(29), 47787~
- Fresneda M, "Production of more sustainable emulsions formulated with eco-friendly materials", J. Clean. Prod, 243(2020), pp.118661~ (2020)[DOI]
- 김정일, "오일 극성도에 따른 에멀젼의 점도와 유기개념도에 의한 해석", 한국응용과학기술학회지, 31(4), pp.623~627 (2014), 한국응용과학기술학회
- 김은하, "Comparison of Vinyl Acetate Contents of Poly(Ethylene-co-Vinyl Acetate) Analyzed by IR, NMR, and TGA", 엘라스토머 및 콤포지트, 50(1), pp.18~23 (2015), 한국고무학회
