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Synthesis and Characterization of Transition Metal Complexes with Benzimidazolyl-2-hydrazones of o-anisaldehyde and Furfural

R. K. Mohapatra|U. K. Mishra|S. K. Mishra|A. Mahapatra|D. C. Dash
대한화학회|2011.12|대한화학회지 (Journal of the Korean Chemical Society)|제55권 제6호|pp. 926-931

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참고문헌

키워드

Benzimidazolyl-2-hydrazoneso-anisaldehydeFurfural and Transition metal complexes
주제분류화학

초록

A series of complexes of the type [ML_2Cl_2], where L=2-(o-anisylidene-2’-imino) amino benzimidazole (AIAB)and 2-(furfurylidene imino) amino benzimidazole (FIAB), M=Cu(II), Co(II), Ni(II) and Zn(II), have been synthesized and characterized on the basis of elemental analysis, thermal analysis, molar conductivity, magnetic moment, electronic, infrared,^1H-NMR spectral studies. The results are in consistent with bidentate chelation of ligand with azomethine nitrogen and ring nitrogen donors. All these Schiff bases and their complexes have also been screened for their antibacterial (Bacillus subtilis,Bacillus stearothermophilus, Escherichia coli and Salmonella typhi) and antifungal activities (Aspergillus niger and Aspergillus flavus).

Abstract

A series of complexes of the type [ML_2Cl_2], where L=2-(o-anisylidene-2’-imino) amino benzimidazole (AIAB)and 2-(furfurylidene imino) amino benzimidazole (FIAB), M=Cu(II), Co(II), Ni(II) and Zn(II), have been synthesized and characterized on the basis of elemental analysis, thermal analysis, molar conductivity, magnetic moment, electronic, infrared,^1H-NMR spectral studies. The results are in consistent with bidentate chelation of ligand with azomethine nitrogen and ring nitrogen donors. All these Schiff bases and their complexes have also been screened for their antibacterial (Bacillus subtilis,Bacillus stearothermophilus, Escherichia coli and Salmonella typhi) and antifungal activities (Aspergillus niger and Aspergillus flavus).

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