본문 바로가기
KERD
논문KCI 등재

Synthesis, Characterization and Biological Studies of New Mn(II), Ni(II), Co(II), Cu(II) and Zn(II) of 2-(benzothiazol-2-yl)-N'-(2,5-dihydroxybenzylidene)acetohydrazide

Ahmed N. Al-Hakimi|Mohamad M. E. Shakdofa|Ahmed M. A. El-Seidy|Abdou S. El-Tabl
대한화학회|2011.02|대한화학회지 (Journal of the Korean Chemical Society)|제55권 제1호|pp. 19-27

2

조회

0

다운로드

0

인용

0

참고문헌

키워드

Complexes착물AcetohydrazideESR 분광학BenzothiazolFungicidal activitiesESR spectroscopy살균활성
주제분류화학

초록

New series of Mn(II), Ni(II), Co(II), Cu(II) and Zn(II) of the 2-(benzothiazol-2-yl)-N'-(2,5-dihydroxybenzylidene)acetohydrazide have been synthesized and characterized by elemental analysis, IR, UV-vis, ^1H-NMR, mass and ESR spectra, magnetic susceptibility and molar conductivity measurements. The spectral data and magnetic measurements of the complexes indicate that, the geometries are either square planar or octahedral. The biological activity of the ligand and its complexes against fungi (Aspergillus nigar and Fusarium oxysporium) were investigated. The metal complexes exhibited higher activity than both the parent ligand and the corresponding metal ion.

Abstract

New series of Mn(II), Ni(II), Co(II), Cu(II) and Zn(II) of the 2-(benzothiazol-2-yl)-N'-(2,5-dihydroxybenzylidene)acetohydrazide have been synthesized and characterized by elemental analysis, IR, UV-vis, ^1H-NMR, mass and ESR spectra, magnetic susceptibility and molar conductivity measurements. The spectral data and magnetic measurements of the complexes indicate that, the geometries are either square planar or octahedral. The biological activity of the ligand and its complexes against fungi (Aspergillus nigar and Fusarium oxysporium) were investigated. The metal complexes exhibited higher activity than both the parent ligand and the corresponding metal ion.

참고문헌 (44)

  1. Thompson, K. H., , Coord. Chem. Rev, 219, pp.1053~ (2001)
  2. Sridhar, S. K., , Eur. J. Pharm. Sci, 16, pp.129~ (2002)
  3. Vicini, P., , Eur. J. Med. Chem, 37, pp.553~ (2002)
  4. Kocyigit-Kaymakcioglu, B., , Farmaco, 57, pp.595~ (2002)
  5. Ragavendran, J. V., , Eur. J. Med. Chem, 42, pp.146~ (2007)
  6. Rollas, S., , Farmaco, 57, pp.171~ (2002)
  7. Carcelli, M., , J. Inorg. Biochem, 57, pp.43~ (1995)
  8. Johnson, D. K., , Inorg. Chim. Acta, 67, pp.159~ (1982)
  9. Ranford, J. D., , Inorg. Chem, 37, pp.1226~ (1998)
  10. Buss, J. L., , Curr. Top. Med. Chem, 4, pp.1623~ (2004)
  11. El-Sayed, M. A., , Heteroatom Chem, 10, pp.1~ (1999)
  12. Shakir, M., , Spectrochim. Acta, Part A, 65, pp.490~ (2006)
  13. Kumar, K. G., , React. Funct. Polym, 66, pp.1427~ (2006)
  14. Mohamed, G. G., , Spectrochim. Acta, Part A, 61, pp.1059~ (2005)
  15. Wang, X. B., , J. Inorg. Chim. Acta, 359, pp.3481~ (2006)
  16. Amirnasr, M., , Polyhedron, 25, pp.671~ (2006)
  17. Ismail, K. Z., , Polyhedron, 16, pp.2909~ (1997)
  18. Kannan, S., , Polyhedron, 25, pp.3095~ (2006)
  19. Pouralimardan, O., , Inorg. Chim. Acta, 360, pp.1599~ (2007)
  20. Leniec, G., , Solid State Sci, 9, pp.267~ (2007)
  21. Keskioglu, E., , Spectrochim. Acta, Part A, 70, pp.634~ (2008)
  22. Nakamoto, K., "Infrared and Raman Spectra of Inorganic and Coordination Compounds" (1986), Wiley Interscience
  23. Sen, S., , Dalton Trans, pp.1758~ (2006)
  24. Singh, G., , Proc. Natl. Acad. Sci. Ind, 72, pp.87~ (2002)
  25. Teotia, M., , Inorg. Nucl. Chem, 42, pp.821~ (1980)
  26. Boghaei, D. M., , Spectrochim. Acta, Part A, 67, pp.944~ (2007)
  27. El-Shazly, R. M., , Spectrochim. Acta, Part A, 61, pp.243~ (2005)
  28. Nakamoto, K., "Infrared Spectra of Inorganic and Coordination Compounds 2nd ed" (1970), John Wiley and Sons Inc
  29. Geary, W., , Coord. Chem. Rev, 7, pp.81~ (1971)
  30. Tas, E.;, , J. Chem. Res-(S), pp.242~ (2006)
  31. Mohamed, G. G., , Spectrochim. Acta, Part A, 62, pp.1140~ (2005)
  32. Mondal, N., , Polyhedron, 19, pp.2707~ (2000)
  33. Ketcham, K. A., , Polyhedron, 20, pp.3265~ (2001)
  34. Sanmartin, J., , Polyhedron, 25, pp.1714~ (2006)
  35. Mostafa, S. I., , Journal of Molecular Catalysis A: Chemical, 225, pp.181~ (2005)
  36. Abu El-Reash, G. M., , Trans. Met. Chem, 15, pp.148~ (1990)
  37. Figgis, B. N., "Introduction to ligand fields" (1966), Wiley
  38. Mostafa, M. M., , Synth. Reac. Inorg. Met-Org. Chem, 14, pp.39~ (1984)
  39. Kivelson, D., , J. Chem. Phys, 35, pp.149~ (1961)
  40. Chandra, S., , Spectrochim. Acta, Part A, 62, pp.1102~ (2005)
  41. Addison, A. W., "Copper Coordination Chemistry Biochemical and Inorganic Perspectives" (1983), Adenine Press
  42. Shauib, N. M., , Spectrochim. Acta, Part A, 63, pp.714~ (2006)
  43. El-Tabl, A. S., , Polish J. Chem, 71, pp.1213~ (1997)
  44. Fouda, M. F. R., , J. Coord. Chem, 61(12), pp.1983~ (2008)

관련 논문AI추천

Transition Metal Complexes Derived From 2-hydroxy-4-(p-tolyldiazenyl)benzylidene)-2-(p-tolylamino)acetohydrazide Synthesis, Structural Characterization, and Biological ActivitiesAdel M. E. Shakdofa, Ahmed N. Al-Hakimi, Ashwaq M. Abdu, Ibrahim A. Alhagri, Maged S. Al-Fakeh, Mohamad M. E. Shakdofa, S. El-Sayed Saeed대한화학회 · 대한화학회지2021 · 제65권 제2호Synthesis and Characterization of Transition Metal Complexes with Benzimidazolyl-2-hydrazones of o-anisaldehyde and FurfuralA. Mahapatra, D. C. Dash, R. K. Mohapatra, S. K. Mishra, U. K. Mishra대한화학회 · 대한화학회지2011 · 제55권 제6호Synthesis, Characterization and Antimicrobial Activities of Hydrazone Ligands Derived from 2-(phenylamino)acetohydrazide and Their Metal ComplexesA. N. Al-Hakimi, F. A. EL-Saied, M. M. E. Shakdofa대한화학회 · 대한화학회지2011 · 제55권 제3호Synthesis and Characterization of Some Transition Metal Complexes of Unsymmetrical Tetradentate Schiff Base LigandA. N. Jagdale, A. S. Munde, S. M. Jadhav, T. K. Chondhekar대한화학회 · 대한화학회지2009 · 제53권 제4호Synthesis, Physico-Chemical and Biological Properties of Complexes of Cobalt(II) Derived from Hydrazones of Isonicotinic Acid HydrazideRam K. Agarwal, Surendra Prasad대한화학회 · 대한화학회지2009 · 제53권 제1호Synthesis, Magneto-Spectral, Electrochemical, Thermal Characterization and Antimicrobial Investigations of Some Nickel(II) Complexes of Hydrazones of IsoniazidRam K. Agarwal, Surendra Prasad대한화학회 · 대한화학회지2009 · 제53권 제6호

이 간행물의 다른 논문 (19건)

The Effect of Exchange and Correlation on Properties of Carbon Nanotube Structure: A DFT studyK. Bakhshi, F. Mollaamin, M. Monajjemipp. 7-13Esterification of Methacrylic acid with Ethylene glycol over Heteropolyacid supported on ZSM-5Ch. Subrahmanyam, A. Prabhakarn, J. A. Fereiropp. 14-18Spectroscopic, Thermal and Biological Studies on Newly Synthesized Cu(II), Ni(II) and Co(II) Complexes with 3-N-2-hydroxyethylamine Benzanthrone and 3-N-2-aminoethylamine BenzanthroneSamir El-Ghol, Ivo Grabchev, Ibrahim M. El-Deen, Moamen S. Refat, Adel S. Megahedpp. 28-37X-ray and Spectroscopy Studies of Mercury (II) and Silver (I) Complexes of α-Ketostabilized Phosphorus YlidesK. Karami, H. Dalvand, O. Büyükgüngörpp. 38-45Extraction-Spectrophotometric Determination of Cimetidine in Pharmaceutical Samples as an Ion Pair with Bromothymol BlueB. Zargar, N. Pourreza, M. Shahrouzpp. 46-49
원문 보기