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철부식생성물 저감을 위한 고온 pH(t) 상향 연구

Study on Increasing High Temperature pH(t) to Reduce Iron Corrosion Products

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주제분류금속공학

초록

The transportation and deposition of iron corrosion products are important elements that affect both the steam generator (SG) integrity and secondary system in pressurized water reactor (PWR) nuclear power plants. Most of iron corrosion products are generated on carbon steel materials due to flow accelerated corrosion (FAC). The several parameters like water chemistry, temperature, hydrodynamic, and steel composition affect FAC. It is well established that the at-temperature pH of the deaerated water system has a first order effect on the FAC rate of carbon steels through nuclear industry researches. In order to reduce transportation and deposition of iron corrosion products, increasing pH(t) tests were applied on secondary system of A, B units. Increasing pH(t) successfully reduced flow accelerated corrosion. The effect of increasing pH(t) to inhibit FAC was identified through the experiment and pH(t) evaluation in this paper.

Abstract

The transportation and deposition of iron corrosion products are important elements that affect both the steam generator (SG) integrity and secondary system in pressurized water reactor (PWR) nuclear power plants. Most of iron corrosion products are generated on carbon steel materials due to flow accelerated corrosion (FAC). The several parameters like water chemistry, temperature, hydrodynamic, and steel composition affect FAC. It is well established that the at-temperature pH of the deaerated water system has a first order effect on the FAC rate of carbon steels through nuclear industry researches. In order to reduce transportation and deposition of iron corrosion products, increasing pH(t) tests were applied on secondary system of A, B units. Increasing pH(t) successfully reduced flow accelerated corrosion. The effect of increasing pH(t) to inhibit FAC was identified through the experiment and pH(t) evaluation in this paper.

참고문헌 (6)

  1. V. G. Kritsky, "Water Chemistry and Corrosion of Nuclear Power Plant Structural Material", pp.53~ (1999), American Nuclear Society
  2. Development of High Temperature Chemistry Measurement System for Establishment of On-Line Water Chemistry Surveillance, "J. W. Yeon", Korea Atomic Energy Research Institute, 5~ (2010)
  3. S. M. Rohrer, "Plant Chemistry Simulator, Ver 4.0" (2001), Electric Power Research Institute
  4. M. Guillodo, , Proceeding of the int'l conference on Water Chemistry of Nuclear Reactor Systems, pp.336~ (2004), Electric Power Research Institute
  5. M. Yoshinori, , Proceeding of the Symposium on Water Chemistry and Corrosion of Nuclear Power Plants In Asia, pp.17~ (2007), Chung Hwa Nuclear Society
  6. K. Fruzzetti, "Pressurized Water Reactor Secondary Water Chemistry Guidelines, Rev 7", pp.2~ (2009), Electric Power Research Institute

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