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원전 2차계통의 수화학 변화가 배관감육에 미치는 영향 분석

Analysis of Pipe Wall-thinning Caused by Water Chemistry Change in Secondary System of Nuclear Power Plant

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주제분류금속공학

초록

Pipe wall-thinning by flow-accelerated corrosion (FAC) is a significant and costly damage of secondary system piping in nuclear power plants (NPPs). All NPPs have their management programs to ensure pipe integrity from wall-thinning. This study analyzed the pipe wall-thinning caused by changing the amine, which is used for adjusting the water chemistry in the secondary system of NPPs. The pH change was analyzed according to the addition of amine. Then, the wear rate calculated in two different amines was compared at the steam cycle in NPPs. As a result, increasing the pH at operating temperature (Hot pH) can reduce the rate of FAC damage significantly. Wall-thinning is affected by amine characteristics depending on temperature and quality of water.

Abstract

Pipe wall-thinning by flow-accelerated corrosion (FAC) is a significant and costly damage of secondary system piping in nuclear power plants (NPPs). All NPPs have their management programs to ensure pipe integrity from wall-thinning. This study analyzed the pipe wall-thinning caused by changing the amine, which is used for adjusting the water chemistry in the secondary system of NPPs. The pH change was analyzed according to the addition of amine. Then, the wear rate calculated in two different amines was compared at the steam cycle in NPPs. As a result, increasing the pH at operating temperature (Hot pH) can reduce the rate of FAC damage significantly. Wall-thinning is affected by amine characteristics depending on temperature and quality of water.

참고문헌 (9)

  1. Flow-Accelerated Corrosion in Power Plant, "EPRI", ~, pp.TR-106611-R1 (1998)
  2. Recommendations for Controlling Cavitation, Flashing, Liquid Droplet Impingement, and Solid Particle Erosion in Nuclear Power Plant Piping Systems, "EPRI", ~, pp.TR-1011231 (2004)
  3. Mentoring Guide for Flow-Accelerated Corrosion Engineers, "EPRI", ~, pp.TR-1022295 (2010)
  4. Recommendations for an Effective Flow-Accelerated Corrosion Program (NSAC- 202L-R4), "EPRI", ~, pp.Technical Report 2001000563 (2013)
  5. 이은희, "유동가속부식에 영향을 미치는 수화학 인자 : pH, 용존산소, 하이드라진", CORROSION SCIENCE AND TECHNOLOGY, 12(6), pp.280~287 (2013), 한국부식방식학회[DOI]
  6. PWR Advanced Amine Application Guidelines, "EPRI", ~, pp.TR-102952-R2 (1997)
  7. Danienl C. Harris, "Quantitative Chemical Analysis" (2012)
  8. CHECWORKS Steam Feedwater Application (SFA) Version 3.0 User Guide, "EPRI", ~, pp.TR-1018102 (2008)
  9. Guidelines for Plant Modeling and Evaluation of Component Inspection Data, "EPRI", ~, pp.TR-1009599 (2004)

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