Solid Phase Extraction of Copper(II) from Aqueous Solutions by Adsorption of its 2-propylpiperidine-1-carbodithioate Complex on Alumina Column
2
조회
0
다운로드
0
인용
0
참고문헌
키워드
초록
A novel approach has been developed for the solid phase extraction of copper(II) based on the adsorption of its 2-propylpiperidine-1-carbodithioate complex on alumina column. The effect of various parameters such as acidity, sample volume, interfering ions, etc., were studied in detail. The adsorbed complex could be easily eluted using polyethylene glycol-sulfuric acid mixture and the concentration of copper has been determined using visible spectrophotometry. The calibration graph was linear in the range 0-1 μgmL−1 copper(II) with a detection limit of 5 μgL−1. A highest preconcentration factor of 25 could be obtained for 250 mL sample volume using glass wool as support for the alumina bed adsorbent. Copper(II) could be effectively separated from other ions such as nickel, cobalt, zinc, chloride, sulfate, nitrate, etc., and the method has been successfully applied to study the recovery of copper in electroplating waste water and spiked water samples.
Abstract
A novel approach has been developed for the solid phase extraction of copper(II) based on the adsorption of its 2-propylpiperidine-1-carbodithioate complex on alumina column. The effect of various parameters such as acidity, sample volume, interfering ions, etc., were studied in detail. The adsorbed complex could be easily eluted using polyethylene glycol-sulfuric acid mixture and the concentration of copper has been determined using visible spectrophotometry. The calibration graph was linear in the range 0-1 μgmL−1 copper(II) with a detection limit of 5 μgL−1. A highest preconcentration factor of 25 could be obtained for 250 mL sample volume using glass wool as support for the alumina bed adsorbent. Copper(II) could be effectively separated from other ions such as nickel, cobalt, zinc, chloride, sulfate, nitrate, etc., and the method has been successfully applied to study the recovery of copper in electroplating waste water and spiked water samples.
참고문헌 (53)
- Bowen, H. J. M, "Enviromental Chemistery of the Elements", pp.132~135 (1979), Academic Press
- Brand, L. E, , J. Exp. Mar. Biol. Ecol, 96, pp.225~ (1986)
- Taylor, H. H, , Anstiss, J. M. Mar. Freshwat. Res, 50, pp.907~ (1999)
- Morel, F. M. M, "Price, N. M. Lim-nol", Oceanogr, 36, pp.1742~ (1991)
- Gordan, A.S, , Mar. Chem, 38, pp.1~ (1992)
- Moffett, J. W, "Barbeau, K. A. Limnol", Oceanoger, 42, pp.789~ (1997)
- Croot, P. L, "Limnol", Oceanogr, 45, pp.619~ (2000)
- Wood, M, , Environ. Sci. Technol, 17, pp.582~ (1983)
- Greemwood, N. N, "Chemistery of Elements" (1984), Pergamon Press
- Burtis, C. A, "Tiets Textbook of Clinical Chemistery" (1999), Macmillan
- Wetz, B, "Atomic Absorption Spectroscopy", VCH, ~ (1985)
- Eaton, A. D, "Standard Methods for the examination of water and waste water, 19th ed", American Public Health Association, ~ (1995)
- Welcher, F. J, "Organic Reagents for Copper" (1979), Krieger Huntington
- Marczenko, Z, "Separation and Spectrophotometric Determination of Elements" (1986)
- Bharagava, O. P, , Talanta, 16, pp.743~ (1969)
- Schilt, A. A, , Anal. Chem, 41, pp.344~ (1964)
- Borchart, L. G, , Anal. Chem, 29, pp.414~ (1957)
- Chaisuksant, R, , Talanta, 53, pp.579~ (2000)
- Kara, D, , Microchem. J, 71, pp.29~ (2002)
- Saito, K, , Anal. Chim. Acta, 294, pp.329~ (1994)
- Ikeda, K, , Anl. Chim. Acta, 363, pp.165~ (1998)
- Igarashi, S, , Anal. Chim. Acta, 424, pp.263~ (2000)
- Liu, J, , Talanta, 53, pp.1149~ (2001)
- Anthemidis, A. N, , Talanta, 54, pp.935~ (2001)
- Zenedelovska, D, , Talanta, 54, pp.139~ (2001)
- Endo, M, , Anal. Chim. Acta, 364, pp.13~ (1998)
- Campderros, M. E, , Talanta, 47, pp.19~ (1998)
- Narin, I, , Talanta, 52, pp.1041~ (2000)
- Akama, Y, , Talanta, 52, pp.645~ (2000)
- Ohta, K, , Talanta, 53, pp.715~ (2001)
- Cuculic, V, , Anal. Chim. Acta, 339, pp.181~ (1997)
- Moghimi, A, , Material Science Research India, 3(1), pp.27~ (2006)
- Tehrani, M. S, , Material Science Research India, 3(2), pp.135~ (2005)
- Thurman, E. M, "Solid-Phase Extraction, Principles and Practice" (1998), Wiley
- Pawliszyn, J, "Solid-Phase Microextraction, Theory and Practice" (1997), Wiley-VCH
- Izatt, R. M, , Pure Appl. Chem, 68, pp.1237~ (1996)
- Moghimi, A, , Oriental Journal of Chemistry, 22(3), pp.527~ (2006)
- Moghimi, A, , Chinese Journal of Chemistry, 25, pp.640~ (2007)
- Taylor, K. Z, "E. J. Anal. Chem. 1995", J. Anal. Chem, 67, pp.1186~ (1995)
- Moghimi, A, , Environmental chemistry an Indian journal, 2(3) (2007)
- Shamsipur, M, "Y. Anal. Chem. 1999", Anal. Chem, 71, pp.4892~ (1999)
- Shamsipur, M, , Int. J. Environ. Anal. Chem, 82, pp.23~ (2001)
- Brunner, J, , J. Am. Chem. Soc, 125, pp.12410~ (2003)
- Zelder, F. H, , Chem. Commun, pp.902~ (2004)
- Boll, I, "A. J. Am. Chem. Soc. 2005", J. Am. Chem. Soc, 27, pp.7849~ (2005)
- Moghimi, A, "A. Chinese Journal of Chemistry 2007", Chinese Journal of Chemistry, 25(10), pp.1536~ (2007)
- Nayebi, P, , Oriental Journal of Chemistry, 22(3), pp.507~ (2006)
- Yun-SeonChoi, "Sensitized Spectrophotometric Determination of Trace Cu(II)in Cationic Surfactant Media", Bulletin of the Korean Chemical Society, 24(2), pp.222~224 (2003), 대한화학회
- Matoso, E, "S. Talanta 2003", Talanta, 60, pp.1105~ (2003)
- Purachat, B, , Anal. Sci, 17, pp.443~ (2001)
- Ensafi, A. A, "Mohammad pour Baltork, I", Anal. Sci, 17, pp.609~ (2001)
- Saber Tehrani, M, "Z. ; Chinese Journal of Chemistry 2005", Chinese Journal of Chemistry, 23, pp.1437~ (2005)
- Moghimi, A, , Material Science Research India impress, 22(3) (2006)