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Preconcentration and Determination of Copper(II) Using Octadecyl Silica Membrane Disks Modified by 2-Propylpiperidine-1-carbodithioate and Flame Atomic Absorption Spectrometry

Ali Moghimi|Haydar Mossalayi
대한화학회|2008.04|대한화학회지 (Journal of the Korean Chemical Society)|제52권 제2호|pp. 148-154

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참고문헌

키워드

AASSPECopper(II)구리(II)Octadecyl 실리카 디스크2-Propylpiperidine-1-carbodithioate (PPCD) IOctadecyl Slica Disks
주제분류화학

초록

2-Propylpiperidine-1-carbodithioate(PPCD)I 로 수식화한 octadecyl로 결합된 실리카 막 디스크로 구리(II) 이온의 잔유양의 추출과 간단하고 빠르게 원자흡수분광법(AAS)으로의 정량법을 소개한다. 추출효율과 흐름속도, pH, 형태, 벗김 산의 가장 적은 양에 대해 연구되었다. Anthraquinone 유도체의 2 mg로 수식한 막디스크의 최대 용량은 425 킽 Cu2+ 이었다. 제안한 방법의 검출한계는 7 ng/ml이다. 이 방법은 다른 시료와 온천수 시료로부터 Cu2+의 회수에 적용하였다.

Abstract

A simple and fast method for extraction and determination of trace amounts of copper(II) ions using octadecyl-bonded silica membrane disks modified with 2-propylpiperidine-1-carbodithioate (PPCD)I and atomic absorption spectrometry (AAS) is introduced. Extraction efficiency and the influence of flow rates, pH, and type and smallest amount of stripping acid were investigated. Maximum capacity of the membrane disks modified with 2 mg of the anthraquinone derivative used was found to be 425µg Cu2+. The limit of detection of the proposed method is 7 ng/ml. The method is applied to the recovery of Cu2+ from different synthetic samples and a spring water sample.

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