황화수소 가스 감지를 위한 고성능 변색성 섬유형 센서의 제작 및 개발
Fabrication of High-Performance Colorimetric Fiber-Type Sensors for Hydrogen Sulfide Detection
0
조회
0
다운로드
0
인용
0
참고문헌
키워드
초록
Hydrogen sulfide(H2S) gas is a high-risk gas that can cause suffocation or death in severe cases, depending on the concentration of exposure. Various studies to detect this gas are still in progress. In this study, we demonstrate a colorimetric sensor that can detect H2S gas using its direct color change. The proposed nanofiber sensor containing a dye material named Lead(II) acetate, which changes its color according to H2S gas reaction, is fabricated by electrospinning. The performance of this sensor is evaluated by measuring RGB changes, ΔE value, and gas selectivity. It has a ΔE value of 5.75×10-3ΔE/s·ppm, showing improved sensitivity up to 1.4 times that of the existing H2S color change detection sensor, which is a result of the large surface area of the nanofibers. The selectivity for H2S gas is confirmed to be an excellent value of almost 70 %.
Abstract
Hydrogen sulfide(H2S) gas is a high-risk gas that can cause suffocation or death in severe cases, depending on the concentration of exposure. Various studies to detect this gas are still in progress. In this study, we demonstrate a colorimetric sensor that can detect H2S gas using its direct color change. The proposed nanofiber sensor containing a dye material named Lead(II) acetate, which changes its color according to H2S gas reaction, is fabricated by electrospinning. The performance of this sensor is evaluated by measuring RGB changes, ΔE value, and gas selectivity. It has a ΔE value of 5.75×10-3ΔE/s·ppm, showing improved sensitivity up to 1.4 times that of the existing H2S color change detection sensor, which is a result of the large surface area of the nanofibers. The selectivity for H2S gas is confirmed to be an excellent value of almost 70 %.
참고문헌 (20)
- D. A. Mattorano, "Respiratory protection on offshore drilling rigs", Appl. Occup. Environ. Hyg, 14(3), pp.141~148 (1999)
- T. L. Guidotti, "Hydrogen sulphide", Occup. Med, 45(5), pp.367~371 (1996)
- R. Sokolovskij, "Hydrogen sulfide detection properties of Pt-gated AlGaN", GaN HEMT-sensor, 2018, pp.274, 636~644
- D. Li, "Preparation and gas-sensing performances of ZnO", CuO rough nanotubular arrays for low-working temperature H2S detection, 2018, pp.254, 834~841
- Z. Li, "Ultra-sensitive UV and H2S dual functional sensors based on porous In2O3 nanoparticles operated at room temperature", J. Alloy. Compd, 770, pp.721~731 (2019)
- H. Huang, "Sulfuration-desulfuration reaction sensing-effect of intrinsic ZnO nanowires for high-performance H2S detection", J. Mater, Chem. A, 3(12), pp.6330~6339 (2015)
- N. S. A. Eom, "Room-temperature H2S gas sensing by selectively synthesized Cux(x=1, 2)O : SnO2 thin film nanocomposites with oblique & vertically assembled SnO2ceramic nanorods", Sens. Actuators B, 273, pp.1054~1061 (2018)
- P. L. Quang, "Simple post-synthesis of mesoporous p-type Co3O4 nanochains for enhanced H2S gas sensing performance", Sens. Actuators B, 270, pp.158~166 (2018)
- A. Stanoiu, "Sensors based on mesoporous SnO2-CuWO4 with high selective sensitivity to H2S at low operating temperature", J. Hazard. Mater, 331, pp.150~160 (2017)
- M. A. H. Khan, "Recent advances in electrochemical sensors for detecting toxic gases : NO2, SO2and H2S", Sensors, 19(4), pp.905(1)~905(39) (2019)
- D. Haydt, "H2S DETECTION AND DETERMINATION, Tech. Rep", pp.1~34 (2000), Galvanic Applied Sciences
- F. I. M. Ali, "Hydrogen Sulfide(H2S)Gas Sensor : A Review", IEEE J. Sens, 19(7), pp.2394~2407 (2019)
- M. A. Mohamed, "Non-isothermal kinetic and thermodynamic study of the decomposition of lead acetate trihydrate", Ther. Act, 236, pp.249~262 (1994)
- 이준엽, "황화수소(H2S) 감지를 위한 아세트산 납이 침염된 폴리에스터(PET) 섬유 기반의 변색성 센서", 센서학회지, 29(5), pp.360~364 (2020), 한국센서학회
- R. A. Chapman, "Application of nonwovens in technical textiles", pp.1~203 (2010), Elsevier
- J. W. Lee, "Nanofibers : Preparations and Applications", KIC NEWS, 13(1), pp.32~50 (2010)
- S. G. Kumbar, "Electrospun nanofiber scaffolds : engineering soft tissues", Biomed. Mater, 3(3), pp.034002~ (2008)
- Kylie Koenig, "A new prototype melt-electrospinning device for the production of biobased thermoplastic sub-microfibers and nanofibers", 생체재료학회지, 23(2), pp.111~122 (2019), 한국생체재료학회[DOI]
- W. S. Mokrzycki, "Color difference Delta E-A survey", Mach. Graph. Vis, 20(4), pp.383~411 (2011)
- B. N. Choi, "Effect of morphological change of copper-oxide fillers on the performance of solid polymer electrolytes for lithium-metal polymer batteries", RSC Adv, 9(38), pp.21760~21770 (2019)