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고분산성 Cr2O3 및 Co3O4 전이금속 나노입자 촉매가 기능화된 다공성 WO3 나노섬유를 이용한 구취진단용 화학센서

Bio-inspired Cr2O3 and Co3O4 Nanoparticles Loaded Electrospun WO3 Nanofiber Chemical Sensor for Early Diagnosis of Halitosis

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초록

In this work, we prepared porous WO3 nanofibers (NFs) functionalized by bio-inspired catalytic Cr2O3 and Co3O4 nanoparticles as highly sensitive and selective H2S gas sensing layers. Highly porous 3-dimensional (3D) NFs networks decorated by well-dispersed catalyst NPs exhibited superior H2S gas response (Rair/Rgas = 46 at 5 ppm) in high humidity environment (95 %RH). In particular, the sensors showed outstanding H2S selectivity against other interfering analytes (such as acetone, toluene, CO, H2, ethanol). Exhaled breath sensors using Cr2O3 and Co3O4 catalysts-loaded WO3 NFs are highly promising for the accurate detection of halitosis.

Abstract

In this work, we prepared porous WO3 nanofibers (NFs) functionalized by bio-inspired catalytic Cr2O3 and Co3O4 nanoparticles as highly sensitive and selective H2S gas sensing layers. Highly porous 3-dimensional (3D) NFs networks decorated by well-dispersed catalyst NPs exhibited superior H2S gas response (Rair/Rgas = 46 at 5 ppm) in high humidity environment (95 %RH). In particular, the sensors showed outstanding H2S selectivity against other interfering analytes (such as acetone, toluene, CO, H2, ethanol). Exhaled breath sensors using Cr2O3 and Co3O4 catalysts-loaded WO3 NFs are highly promising for the accurate detection of halitosis.

참고문헌 (10)

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  7. Koo, W. -T., "Catalyst-decorated hollow WO 3 nanotubes using layerby-layer self-assembly on polymeric nanofiber templates and their application in exhaled breath sensor", Sensors and Actuators B : Chemical, 223, pp.301~310 (2016)
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