Sol-Gel 법에 의한 압전 PZT 후막의 제조
Fabrication of Piezoelectric PZT Thick Film by Sol-gel Process
1
조회
0
다운로드
1
인용
0
참고문헌
키워드
초록
Lead zirconate titanate (PZT) thick films with thicknesses of 20–100 ㎛ were fabricated on silicon substrates using an aerosoldeposition method. A PZT powder solution was prepared using a sol-gel process. The average diameters (d50) obtained were 1.67, 1.98, and 2.40μm when the pyrolysis temperatures were 300°C, 350°C, and 450°C respectively. The as-deposited film had a uniform microstructure without anycracks or pores. The as-deposited films on silicon were annealed at a temperature of 700°C. The 20-㎛-thick PZT film showed good adherencebetween the PZT film and substrate, with no tearing observed in the conventional solid phase process. This was probably because the presence ofpores produced from organic residue during annealing relieved the residual stresses in the deposited film.
Abstract
Lead zirconate titanate (PZT) thick films with thicknesses of 20–100 ㎛ were fabricated on silicon substrates using an aerosoldeposition method. A PZT powder solution was prepared using a sol-gel process. The average diameters (d50) obtained were 1.67, 1.98, and 2.40μm when the pyrolysis temperatures were 300°C, 350°C, and 450°C respectively. The as-deposited film had a uniform microstructure without anycracks or pores. The as-deposited films on silicon were annealed at a temperature of 700°C. The 20-㎛-thick PZT film showed good adherencebetween the PZT film and substrate, with no tearing observed in the conventional solid phase process. This was probably because the presence ofpores produced from organic residue during annealing relieved the residual stresses in the deposited film.
참고문헌 (13)
- Akedo, J., "Microstructure and Electrical Properties of Lead Zirconate Titanate Thick Films Deposited by Aerosol Deposition Method", Japanese Journal of Applied Physics, 38, pp.5397~5401 (1999)
- Choi, J. J., "Preparation of Highly Dense PZN-PZT Thick Films by the Aerosol Deposition Method using Excess PbO Powder", Journal of American Ceramic Society, 90(11), pp.3389~3394 (2007)
- Evans, A. G., "The Thermomechanical Integrity of Thin Films and Multilayers", Acta Metallurgica et Materialla, 43(7), pp.2507~2530 (1995)
- Haertling, G. H., "Ferroeletric Ceramics : History and Technology", Journal of American Ceramic Society, 84(3), pp.797~818 (1999)
- 홍동수, "무선 임피던스 센서노드를 이용한 강-볼트 접합부의 임피던스기반 손상모니터링에 미치는 온도 영향", 한국해양공학회지, 26(1), pp.27~33 (2012), 한국해양공학회
- Khilkin, A. L., "PZT-based Piezoelectric Composites via Modified Sol-Gel Route", Journal of European Ceramic Society, 21(10), pp.1535~1538 (2001)
- Kim, C. J., "Investigation of the Drying Temperature Dependence of the Orientation in Sol-Gel Processed PZT Thin Films", Journal of Materials Science, 32, pp.1213~1219 (1997)
- 김기훈, "에어로졸 증착법에 의한 압전 PZT 후막의 제조", 한국해양공학회지, 27(6), pp.95~99 (2013), 한국해양공학회
- Malic, B., "Crystallization Study of the Alkoxide-Based Pb(Zr0. 30Ti0. 70)O3Thin-Film Precursor", Acta Chimica Slovenica, 52, pp.259~263 (2005)
- 박재형, "Development of Acceleration-PZT Impedance Hybrid Sensor Nodes Embedding Damage Identification Algorithm for PSC Girders", 한국해양공학회지, 24(3), pp.1~10 (2010), 한국해양공학회
- Park, Y., "Delamination Behavior of Pt in a SiO2", Pb(ZrxTi1-x)O3, Journal of Applied Physics, pp.2001, 89(3)[DOI]
- Schwartz, R. W., "Chemical Solution Deposition of Perovskite Thin Films", Chemistry of Materials, 9, pp.2325~2340 (1997)
- Zhilun, G., "Low-Temperature Sintering of Lead-Based Piezoelectric Ceramics", Journal of American Ceramic Society, 72(3), pp.486~491 (1989)
