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KCN 에칭 및 CdS 후열처리가 Cu(In,Ga)(S,Se)₂ 광흡수층 성능에 미치는 영향

Effect of Pre/Post-Treatment on the Performance of Cu(In,Ga)(S,Se)₂ Absorber Layer Manufactured in a Two-Step Process

이경아|김아현|전찬욱
한국신·재생에너지학회 (The Korean Society for New and Renewable Energy)|2021.12|신재생에너지 (New & Renewable Energy)|제17권 제4호|pp. 36-45|DOI 10.7849/ksnre.2021.0030

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참고문헌

키워드

CdSBuffer layerChemical bath depositionKCN 에칭공기어닐링용액성장법버퍼층CIGSSeKCN etchingAir annealing

초록

To remove the Cu secondary phase remaining on the surface of a CIGSSe absorber layer manufactured by the two-step process, KCN etching was applied before depositing the CdS buffer layer. In addition, it was possible to increase the conversion efficiency by air annealing after forming the CdS buffer layer. In this study, various pre-treatment/post-treatment conditions wereapplied to the S-containing CIGSSe absorber layerbefore and after formation of the CdS buffer layer to experimentally confirm whether similareffects as those of Se-terminated CIGSe were exhibited. Contrary to expectations, it was noted that CdS air annealing had negative effects.

Abstract

To remove the Cu secondary phase remaining on the surface of a CIGSSe absorber layer manufactured by the two-step process, KCN etching was applied before depositing the CdS buffer layer. In addition, it was possible to increase the conversion efficiency by air annealing after forming the CdS buffer layer. In this study, various pre-treatment/post-treatment conditions wereapplied to the S-containing CIGSSe absorber layerbefore and after formation of the CdS buffer layer to experimentally confirm whether similareffects as those of Se-terminated CIGSe were exhibited. Contrary to expectations, it was noted that CdS air annealing had negative effects.

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관련 논문AI추천

CdS 박막의 증착 후처리 방법이 CIGS 태양전지특성에 미치는 영향권수민, 김상목, 전찬욱한국신·재생에너지학회 · 신재생에너지2016 · 제12권 제1호단일 복합 타겟으로 스퍼터 코팅된 CIGS 박막의 형성과 열처리에 따른 미세구조 변화김종렬, 송영식한국표면공학회 · 한국표면공학회지2013 · 제46권 제2호스퍼터링법으로 제작한 CIGS 박막의 후열처리에 따른 물성 평가송풍근, 정재헌, 조상현한국표면공학회 · 한국표면공학회지2013 · 제46권 제1호셀렌화 공정을 제외한 RF 마그네트론 스퍼터링으로 제작된 Cu(In,Ga)Se2 박막의 구조 및 전기적 특성손영국, 최정규, 황동현한국표면공학회 · 한국표면공학회지2013 · 제46권 제2호태양전지용 CuGaSe2 단결정 박막 성장과 열처리 효과유상하, 홍광준한국태양에너지학회 · 한국태양에너지학회 논문집2003 · 제23권 제2호하이드라진 용액법으로 형성된 CuInSe2 다층 박막 분석정중희한국표면공학회 · 한국표면공학회지2015 · 제48권 제4호

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