A New Simple Method for Photometric Determination of H2O2
0
조회
0
다운로드
0
인용
0
참고문헌
키워드
초록
Hydrogen peroxide (H O ) is widely used in bleaching treatments in the pulp and paper industry, in wastewater treatment, and as22a food additive. However, H O solutions are unstable and decompose slowly when subjected to external factors such as light, high22temperatures, or metal compounds. Therefore, a simple and reliable method to measure the concentration of H O is required for its22proper use in various applications. We determined the concentration of an H O22 solution by measurement at a single wavelength (249nm) without any reagents or complex analytical procedures. In the present work, the measurable concentration of H O was as low22as 0.015 wt% (4.41 mM) and as high as 0.300 wt% (88.2 mM), with high linearity (99.99% at 249 nm) between the concentrationof H O and the optical density (OD) values. In addition, the method could be used to measure the concentration of H O in a peracetic2222acid solution without interference from acetic acid and peracetate ion.
Abstract
Hydrogen peroxide (H O ) is widely used in bleaching treatments in the pulp and paper industry, in wastewater treatment, and as22a food additive. However, H O solutions are unstable and decompose slowly when subjected to external factors such as light, high22temperatures, or metal compounds. Therefore, a simple and reliable method to measure the concentration of H O is required for its22proper use in various applications. We determined the concentration of an H O22 solution by measurement at a single wavelength (249nm) without any reagents or complex analytical procedures. In the present work, the measurable concentration of H O was as low22as 0.015 wt% (4.41 mM) and as high as 0.300 wt% (88.2 mM), with high linearity (99.99% at 249 nm) between the concentrationof H O and the optical density (OD) values. In addition, the method could be used to measure the concentration of H O in a peracetic2222acid solution without interference from acetic acid and peracetate ion.
참고문헌 (21)
- Baga AN, "A simple spectrophotometric determination of hydrogen peroxide at low concentrations in aqueous solution", Anal. Chim. Acta, 204, pp.349~353 (1988)
- Belhateche D, "Using Cobalt–Ultraviolet Spectrophotometry to measure Hydrogen Peroxide concentration in organically Laden Groundwaters", J. Am. Water Works Assn, 83(8), pp.70~73 (1991)
- Castle L, "Chemical migration from polypropylene and polyethylene aseptic food packaging as affected by hydrogen peroxide sterilization", J. Food Prot, 58(2), pp.170~174 (1995)
- Chen JH, "Decomposition rate of hydrogen peroxide bleaching agents under various chemical and physical conditions", J. Prosthet. Dent, 69(1), pp.46~48 (1993)
- Chhetri RK, "Colorimetric quantification methods for peracetic acid together with hydrogen peroxide for water disinfection process control", Int. J. Environ. Res. Public Health, 17(13), pp.4656~ (2020)
- Clapp PA, "Spectrophotometric determination of hydrogen peroxide after extraction with ethyl acetate", Anal. Chim. Acta, 218, pp.331~334 (1989)
- Eisenberg G, "Colorimetric determination of hydrogen peroxide", Ind. Eng. Chem., Anal. Ed, 15(5), pp.327~328 (1943)
- Frew JE, "Spectrophotometric determination of hydrogen peroxide and organic hydropheroxides at low concentrations in aqueous solution", Anal. Chim. Acta, 155, pp.139~150 (1983)
- Higashi N, "Direct determination of peracetic acid, hydrogen peroxide, and acetic acid in disinfectant solutions by far-ultraviolet absorption spectroscopy", Anal. Chem, 77(7), pp.2272~2277 (2005)
- Holm TR, "Fluorometric determination of hydrogen peroxide in groundwater", Anal. Chem, 59(4), pp.582~586 (1987)
- Kim J, "Advanced oxidation process with peracetic acid and Fe(II)for contaminant degradation", Environ. Sci. Technol, 53(22), pp.13312~13322 (2019)
- Kitis M, "Disinfection of wastewater with peracetic acid : A review", Environment International, 30(1), pp.47~55 (2004)
- Klassen NV, "H2O2determination by the I3-method and by KMnO4 titration", Anal. Chem, 66(18), pp.2921~2925 (1994)
- Linley E, "Use of hydrogen peroxide as a biocide : new consideration of its mechanisms of biocidal action", J. Antimicrob. Chemother, 67(7), pp.1589~1596 (2012)
- Okninski A, "Development of green storable hybrid rocket propulsion technology using 98% hydrogen peroxide as oxidizer", Aerosp, 8(9), pp.234~ (2021)
- Pędziwiatr P, "Decomposition of hydrogen peroxide-kinetics and review of chosen catalysts", Acta Innovations, (26), pp.45~52 (2018)
- Pinkernell U, "Simultaneous HPLC determination of peroxyacetic acid and hydrogen peroxide", Anal. Chem, 69(17), pp.3623~3627 (1997)
- Pinkernell U, "Methods for the photometric determination of reactive bromine and chlorine species with ABTS", Water Res, 34(18), pp.4343~4350 (2000)
- Špička N, "Low-temperature bleaching of knit fabric from regenerated bamboo fibers with different peracetic acid bleaching processes", Textile Research J, 85(14), pp.1497~1505 (2015)
- Tamaoku K, "New water-soluble hydrogen donors for the enzymatic spectrophotometric determination of hydrogen peroxide", Anal. Chim. Acta, 136, pp.121~127 (1982)
- Tredwin C, "Hydrogen peroxide tooth-whitening(bleaching)products : review of adverse effects and safety issues", Br. Dent. J, 200(7), pp.371~376 (2006)
