본문 바로가기
KERD
논문KCI 등재

Chemically Bonded Thermally Expandable Microsphere-silica Composite Aerogel with Thermal Insulation Property for Industrial Use

0

조회

0

다운로드

3

인용

0

참고문헌

키워드

주제분류재료공학

초록

Thermally expandable microsphere and aerogel composite was prepared by chemical compositization. Microsphere can produce synergies with aerogel, especially an enhancement of mechanical property. Through condensation between sulfonated microsphere and hydrolyzed silica sol, chemically-connected composite aerogel could be prepared. The presence of hydroxyl group on the sulfonated microsphere was observed, which was the prime functional group of reaction with hydrolyzed silica sol. Silica aerogel-coated microsphere was confirmed through microstructure analysis. The presence of silicon-carbon absorption band and peaks from composite aerogel was observed, which proved the chemical bonding between them. A relatively low thermal conductivity value of 0.063 W/m·K was obtained.

Abstract

Thermally expandable microsphere and aerogel composite was prepared by chemical compositization. Microsphere can produce synergies with aerogel, especially an enhancement of mechanical property. Through condensation between sulfonated microsphere and hydrolyzed silica sol, chemically-connected composite aerogel could be prepared. The presence of hydroxyl group on the sulfonated microsphere was observed, which was the prime functional group of reaction with hydrolyzed silica sol. Silica aerogel-coated microsphere was confirmed through microstructure analysis. The presence of silicon-carbon absorption band and peaks from composite aerogel was observed, which proved the chemical bonding between them. A relatively low thermal conductivity value of 0.063 W/m·K was obtained.

참고문헌 (34)

  1. Z. -L. Yu, "Fire-retardant and thermally insulating phenolic-silica aerogels", Angew. Chem. Int. Ed, 57(17), pp.4538~ (2018)
  2. Y. Lei, "Improvement of thermal insulation performance of silica aerogels by Al2O3powders doping", Ceram. Int, 43(14), pp.10799~ (2017)
  3. T. Feczkó, "Latent heat storage by silica-coated polymer beads containing organic phase change materials", Sol. Energy, 132, pp.405~ (2016)
  4. L. M. Sanz-Moral, "Synthesis and characterization Ru–C", SiO2 aerogel catalysts for sugar hydrogenation reactions, 2018, pp.148, 3514~
  5. G. Vamvounis, "Synthesis and properties of poly(3-n-dodecylthiophene) modified thermally expandable microspheres", Eur. Polym. J, 49, pp.1503~ (2013)
  6. S. Ries, "Foam injection molding of thermoplastic elastomers: Blowing agents, foaming process and characterization of structural foams", Proc. AIP Conf, 1593(1), pp.401~ (2014)
  7. S. -Y. Chen, "Preparation and characterization of conducting polymercoated thermally expandable microspheres", Chin. Chem. Lett, 28, pp.658~ (2017)
  8. M. Jonsson, "Surface modification of thermally expandable microspheres by grafting poly(glycidyl methacrylate)using ARGET ATRP", Eur. Polym. J, 45, pp.2374~ (2009)
  9. A. Schmid, "Synthesis and evaluation of polypyrrole-coated thermally-expandable microspheres: an improved approach to reversible adhesion", Soft Matter, 5(2), pp.407~ (2009)
  10. J. F. Illescas, "Producing surfactant-synthesized nanomaterials in situ on a building substrate, without volatile organic compounds", ACS Appl. Mater. Interfaces, 4(8), pp.4259~ (2012)
  11. C. Zhang, "Effects of hollow microspheres on the thermal insulation of polysiloxane foam", J. Appl. Polym. Sci, 134(18), pp.44778~ (2017)
  12. H. E. Cingil, "Conducting polymer-coated thermally expandable microspheres", Polym. Chem, 1(8), pp.1323~ (2010)
  13. S. Grama, "Monodisperse macroporous poly(glycidyl methacrylate)microspheres coated with silica: design, preparation and characterization", React. Funct. Polym, 77, pp.11~ (2014)
  14. H. Aglan, "Strength and toughness improvement of cement binders using expandable thermoplastic microspheres", Constr. Build. Mater, 23(8), pp.2856~ (2009)
  15. Y. Lu, "Surface modification of thermally expandable microspheres for enhanced performance of disbondable adhesive", Int. J. Adhes. Adhes, 66, pp.33~ (2016)
  16. M. Jonsson, "Thermally expandable microspheres with excellent expansion characteristics at high temperature", Journal of applied polymer science, 117(1), pp.384~ (2010)
  17. S. Mulik, "Cross-linking 3D assemblies of nanoparticles into mechanically strong aerogels by surface-initiated free-radical polymerization", Chem. Mater, 20, pp.5035~ (2008)
  18. X. Hu, "Characterization of silica-polymer aerogel composites by small-angle neutron scattering and transmission electron microscopy", J. Non-Cryst. Solids, 288, pp.184~ (2001)
  19. Z. Li, "Preparation of ambient pressure dried MTMS", TEOS co-precursor silica aerogel by adjusting NH4OH concentration, 2014, pp.129, 12~
  20. N. Hüsing, "Aerogels – airy materials:chemistry, structure, and properties", Int. Ed, 37, pp.22~ (1998)
  21. D. B. Mahadik, "Elastic and Superhydrophobic Monolithic Methyltrimethoxysilane-based Silica Aerogels by Two-step Sol-gel Process", 마이크로전자 및 패키징학회지, 23(1), pp.35~39 (2016), 한국마이크로전자및패키징학회
  22. 이규연, "Characterization of Mechanical Property Change in Polymer Aerogels Depending on the Ligand Structure of Acrylate Monomer", 마이크로전자 및 패키징학회지, 23(3), pp.15~20 (2016), 한국마이크로전자및패키징학회
  23. 나하윤, "산 촉매가 물유리 기반 실리카 에어로겔의 기공구조에 미치는 영향", 마이크로전자 및 패키징학회지, 24(3), pp.13~18 (2017), 한국마이크로전자및패키징학회
  24. 김영훈, "아세토니트릴 첨가가 물유리 기반 실리카 에어로겔의 기공구조에 미치는 영향", 마이크로전자 및 패키징학회지, 25(4), pp.143~148 (2018), 한국마이크로전자및패키징학회
  25. D. Ge, "Hydrophobic and thermal insulation properties of silica aerogel", epoxy composite, 2009, pp.355, 2610~
  26. N. Kuthirummal, "Photo-formation of gold nanoparticles : photoacoustic studies on solid monoliths of Au(III)–chitosan–silica aerogels", Spectrochimica Acta Part A : Molecular and Biomolecular Spectroscopy, 70(3), pp.700~ (2008)
  27. JaeTae Seo, "Large Optical Nonlinearity of Highly Porous Silica Nanoaerogels in the Nanosecond Time Domain", Journal of the Korean Physical Society, 48(6), pp.1395~1399 (2006), 한국물리학회
  28. H. M. Kim, "Silica aerogel", polyvinyl alcohol (PVA) insulation composites with preserved aerogel pores using interfaces between the superhydrophobic aerogel and hydrophilic PVA solution, 2015, pp.75, 39~
  29. A. Stojanovic, "Three routes to superinsulating silica aerogel powder", J. Sol-Gel Sci. Technol, 90(1), pp.57~ (2019)
  30. H. M. Kim, "Silica aerogel", epoxy composites with preserved aerogel pores and low thermal conductivity, 2015, pp.15(2), 111~
  31. P. Alves, "Surface modification and characterization of thermoplastic polyurethane", Eur. Polym. J, 45, pp.1412~ (2009)
  32. M. Ochoa, "Influence of structure-directing additives on the properties of poly(methylsilsesquioxane)aerogel-like materials", Gels, 5(1), pp.6~ (2019)
  33. H. Lee, "Super-insulating, flameretardant, and flexible poly(dimethylsiloxane) composites based on silica aerogel", Compos. Pt. A-Appl. Sci. Manuf, 123, pp.108~ (2019)
  34. K.-Y. Lee, "Methyltrimethoxysilane silica aerogel composite with carboxyl-functionalised multi-wall carbon nanotubes", Int. J. Nanotechnol., 15(6-7), pp.587~ (2018)

관련 논문AI추천

Ambient-pressure Drying Synthesis of High-performance Silica Aerogel Powders by Controlling Hydrolysis Reaction of Water GlassChang Kook Hong, Churl-Hee Cho, Jin-Suk Lee, Oh-Hoon Kwon, Sang-Eun Lee, Young-Soo Ahn청정에너지연구소 · Journal of Ceramic Processing Research2017 · 제18권 제11호Enhancement in the Textural Properties and Hydrophobicity of Tetraethoxysilane-based Silica Aerogels by Phenyl Surface Modification김용헌, 김태희, 박형호, 이규연, 최해령, 정해누리, Rushikesh P. Dhavale, Vinayak G. Parale한국마이크로전자및패키징학회 · 마이크로전자 및 패키징학회지2020 · 제27권 제2호Elastic and Superhydrophobic Monolithic Methyltrimethoxysilane-based Silica Aerogels by Two-step Sol-gel Process박형호, 이규연, 이윤광, 정해누리, D. B. Mahadik한국마이크로전자및패키징학회 · 마이크로전자 및 패키징학회지2016 · 제23권 제1호Effects of xonotlite additive and forming pressure on the properties of the SiO2-based nanoporous thermal insulation materialsBeiyue Ma, Jingkun Yu, Lu Han, Shiwei Liu청정에너지연구소 · Journal of Ceramic Processing Research2018 · 제19권 제3호실리카 에어로겔을 첨가한 폴리머 폼의 기계적 특성김정대, 김정현, 박강현, 박성균, 안재혁, 이제명한국해양공학회 · 한국해양공학회지2017 · 제31권 제6호Characterization of Mechanical Property Change in Polymer Aerogels Depending on the Ligand Structure of Acrylate Monomer박형호, 이규연, 정해누리, D. B. Mahadik한국마이크로전자및패키징학회 · 마이크로전자 및 패키징학회지2016 · 제23권 제3호

이 간행물의 다른 논문 (8건)