산화코발트 나노입자의 첨가에 따른 산화니켈 기반 반도체 산화물의 에탄올 가스 검출 특성 향상
Ethanol Gas Sensing Properties of NiO-based Composite Oxide Semiconductor with Co3O4 Nanoparticles
1
조회
0
다운로드
1
인용
0
참고문헌
키워드
초록
NiO nanoparticles were synthesized by hydrothermal method for the application to ethanol gas sensor. They were composited with Co3O4 nanoparticles to improve the sensitivity to ethanol gas. Scanning electron microscopy revealed that the synthesized NiO nanoparticles were plate-shaped with the approximate size and thickness of 60 - 120 nm and 20 nm, respectively. On the other hand, Co3O4 nanoparticles mixed with NiO was observed to be spherical with the size range of 30 - 50 nm. The sensitivities of NiO sensors composited with Co3O4 nanoparticles at an optimal ratio of 8 : 2 were enhanced to approximately 1.44 - 1.79 times as high as those of as-synthesized NiO sensors for the ethanol concentration of 10 - 200 ppm at 200oC. The mechanism of the improved ethanol gas sensing of the NiO sensors composited with Co3O4 nanoparticles was discussed.
Abstract
NiO nanoparticles were synthesized by hydrothermal method for the application to ethanol gas sensor. They were composited with Co3O4 nanoparticles to improve the sensitivity to ethanol gas. Scanning electron microscopy revealed that the synthesized NiO nanoparticles were plate-shaped with the approximate size and thickness of 60 - 120 nm and 20 nm, respectively. On the other hand, Co3O4 nanoparticles mixed with NiO was observed to be spherical with the size range of 30 - 50 nm. The sensitivities of NiO sensors composited with Co3O4 nanoparticles at an optimal ratio of 8 : 2 were enhanced to approximately 1.44 - 1.79 times as high as those of as-synthesized NiO sensors for the ethanol concentration of 10 - 200 ppm at 200oC. The mechanism of the improved ethanol gas sensing of the NiO sensors composited with Co3O4 nanoparticles was discussed.
참고문헌 (24)
- Miao Zhang, "Time-Resolved Observations of Water Oxidation Intermediates on a Cobalt Oxide Nanoparticle Catalyst", Nat. Chem, 6, pp.362~367 (2014)
- Ngai Yui Chan, "Highly Sensitive Gas Sensor by the LaAlO3", SrTiO3 Heterostruxcture with Pd Nanoparticle Surface Modulation, 2014, pp.26, 5962~5968
- Jin Wu, "In Situ Synthesis of Large-Area Single Sub-10 nm Nanoparticle Array by Polymer Pen Lithography", Nanoscale, 6, pp.749~752 (2014)
- Hiroaki Yoshida, "P2-Type Na2", 3Ni1, 3-xTixO2 as a New Positive Electrode for Higher Energy Na-Ion Batteries, pp.Chem. Commun, 2014[DOI]
- Peimei Da, "Surface Plasmon Resonance Elnhanced Real-Time Photoelectrochemical Protein Sensing by Gold Nanoparticle-Decorated TiO2 Nanowires", Anal. Chem, 86, pp.6633~6639 (2014)
- Wenjin Yang, "Psudobinary Solid-Solution : An Alternative Way for the Bandgap Engineering of Semiconductor Nanowires in the Case of GaPZnSe", Adv. Funct. Mater, 25, pp.2543~2551 (2015)
- Pengfei Qiang, "TiO2 Nanowires for Potential Facile Integration of Solar Cells and Electrochromic Devices", Nanotechnol, 24, pp.435403~435407 (2013)
- M. Fickenscher, "Optical, Structural, and Numerical Investigations of GaAs", AlGaAs Core-Multishell Nanowire Quantum Well Tubes, 2013, pp.13, 1016~1022
- Emily P. Thi, "Lipid Nanoparticle siRNA Treatment of Ebola-Virus-Makona-Infected Nonhuman Primates", Nature, 521, pp.362~365 (2015)
- Heng Chen, "Molecular Dynamics Study of a CNT-Buckyball-Enabled Energy Absorption System", Phys. Chem. Chem. Phys, 17, pp.17311~17321 (2015)
- Chunyan Zhang, "Hydrothermal Synthesis of Mn-Doped CdS Hollow Sphere Nanocomposites as Efficient Visible-Light Driven Photocatalysts", RSC Adv, 5, pp.15110~15117 (2015)
- Zhenxin Zhang, "Ultrathin Inorganic Molecular Nanowire Based on Polyoxometalates", Nat. Commun, 6, pp.7731~7740 (2015)
- Iskandar N. Kholmanov, "Optical, Electrical, and Electromechanical Properties of Hybrid Graphene", Carbon Nanotube Films, 2015, pp.27, 3053~3059
- Josephine Socratous, "Electronic Structure of Low-Temperature Solution-Processed Amorphous Metal Oxide Semiconductors for Thin-Film Transistor Applications", Adv. Funct. Mater, 25, pp.1873~1885 (2015)
- Songyue Chen, "Sensitivity and Detection Limit Analysis of Silicon Nanowire Bio (Chemical) Sensors", Sens. Actuators B, 209, pp.486~489 (2015)
- Xiaohong Sun, "Enhanced Gas-Sensing Performance of Fe-Doped Ordered Mesoporous NiO with Long-Range Periodicity", J. Phys. Chem. C, 119, pp.3228~3237 (2015)
- Jinwei Li, "Hydrothermal Synthesis of Self-Assembled Hierarchical Tungsten Oxides Hollow Spheres and Their Gas Sensing Properties", ACS Appl. Mater. Interfaces, 7, pp.10108~10114 (2015)
- Liqiang Zhang, "Synthesis of TiO2 Decorated Co3O4Acicular Nanowire Arrays and Their Application as an Ethanol Sensor", J. Mater. Chem. A, 3, pp.2794~2801 (2015)
- Chen Wang, "Ultrasensitive and Low Detection Limit of Acetone Gas Sensor Based on W-Doped NiO Hierarchical Nanostructure", Sens. Actuators B, 220, pp.59~67 (2015)
- Chengjun Dong, "Porous NiO Nanosheets Self-Grown on Alumina Tube Using a Novel Flash SYnthesis and Their Gas Sensing Properties", RSC Adv, 5, pp.4880~4885 (2015)
- Changhui Zhao, "Enhanced Ethanol Sensing Performance of Porous Ultrathin NiO Nanosheets with Neck-Connected Networks", RSC Adv, 3, pp.4018~4023 (2013)
- Cheng-Liang Hsu, "Fabrication of Gas Sensor Based on p-Type ZnO Nanoparticles and n-Type ZnO Nanowires", Sens. Actuators B : Chem, 182, pp.190~196 (2013)
- Sahar Hemmati, "Nanostructured SnO2-ZnO Sensors: Highly Sensitive and Selective to Ethanol", Sens. Actuators B : Chem, 160, pp.1298~1303 (2011)
- Davide Barreca, "Novel Synthesis and Gas Sensing Performances of CuO-TiO2 Nanocomposites Functionalized with Au Nanoparticles", J. Phys. Chem. C, 115, pp.10510~10517 (2011)
