초고속 원심방사에 의한 아세트산프로피온산 셀룰로오스/폴리부틸렌 숙시네이트 다공성 마이크론 섬유 제조
Fabrication of Porous Cellulose Acetate Propionate/Polybutylene Succinate Microfibers by High Speed Centrifugal Spinning
0
조회
0
다운로드
0
인용
0
참고문헌
키워드
초록
Cellulose is an abundant biodegradable material in nature with excellent properties, but due to its poor processability, it has been widely studied for processing through modification. Cellulose acetate propionate (CAP) is a cellulose derivative in which the hydroxyl group of cellulose is replaced by acetyl and propionyl groups. CAP has several advantages, such as excellent solubility, structural stability, light and weather resistance, and good transparency. Porous nanofibers with excellent specific surface area, which can be applied in various fields, can be easily formed by the phase separation method using highly volatile solvents. High speed centrifugal spinning is a nano/micro fiber preparation method with advantages such as fast spinning and easy alignment control. In this study, a CAP/polybutylene succinate (PBS) spinning solution with chloroform as solvent was prepared to prepare porous microfibers and the fiber morphology was examined as a function of the disk rotation speed in an High speed centrifugal spinning device.
Abstract
Cellulose is an abundant biodegradable material in nature with excellent properties, but due to its poor processability, it has been widely studied for processing through modification. Cellulose acetate propionate (CAP) is a cellulose derivative in which the hydroxyl group of cellulose is replaced by acetyl and propionyl groups. CAP has several advantages, such as excellent solubility, structural stability, light and weather resistance, and good transparency. Porous nanofibers with excellent specific surface area, which can be applied in various fields, can be easily formed by the phase separation method using highly volatile solvents. High speed centrifugal spinning is a nano/micro fiber preparation method with advantages such as fast spinning and easy alignment control. In this study, a CAP/polybutylene succinate (PBS) spinning solution with chloroform as solvent was prepared to prepare porous microfibers and the fiber morphology was examined as a function of the disk rotation speed in an High speed centrifugal spinning device.
참고문헌 (17)
- T. Heinze, "Novel Bulky Esters of Cellulose", Macromolecular Bioscience, 7(11), pp.1225~ (2007)
- R. Zhou, "Detection of Organic Solvents with Reliable Chemical Sensors Based on Cellulose Derivatives", Sensors and Actuators B : Chemical, 25(1-3), pp.443~ (1995)
- R. Liu, "Progress of Fabrication and Applications of Electrospun Hierarchically Porous Nanofibers", Advanced Fiber Materials, 4(4), pp.604~ (2022)
- J. Wu, "Porous Polymers as Multifunctional Material Platforms toward Task-specific Applications", Advanced Materials, 31(4), pp.1802922~ (2019)
- X. Y. Yang, "Hierarchically porous materials : synthesis strategies and structure design", Chemical Society Reviews, 46(2), pp.481~ (2017)
- C. Huang, "Fabrication of Porous Fibers via Electrospinning : Strategies and Applications", Polymer Reviews, 60(4), pp.595~ (2020)
- J. Liu, "Hierarchical Macro-meso-microporous ZSM-5 Zeolite Hollow Fibers with Highly Efficient Catalytic Cracking Capability", Scientific Reports, 4(1), pp.7276~ (2014)
- Y. Zhao, "Bio-mimic Multichannel Microtubes by a Facile Method", Journal of the American Chemical Society, 129(4), pp.764~ (2007)
- J. Xie, "Putting Electrospun Nanofibers to Work for Biomedical Research", Macromolecular Rapid Communications, 29(22), pp.1775~ (2008)
- M. R. Badrossamay, "Nanofiber Assembly by Rotary Jet-spinning", Nano Letters, 10(6), pp.2257~ (2010)
- Y. Y. Then, "Effect of 3-Amino propyltrimethoxysilane on Chemically Modified Oil Palm Mesocarp Fiber", poly(butylene succinate), 2015, pp.10(2), 3577~
- E. Rynkowska, "Physicochemical Properties and Pervaporation Performance of Dense Membranes Based on Cellulose Acetate Propionate(CAP)and Containing Polymerizable Ionic Liquid(PIL)", Journal of Membrane Science, 544, pp.243~ (2017)
- X. Hu, "Difference in Solid-state Properties and Enzymatic Degradation of Three Kinds of Poly(butylene succinate)", cellulose Blends, 2017, pp.7(56), 35496~
- X. Hu, "Blending Modification of PBS", PLA and its Enzymatic Degradation, 2018, pp.75, 533~
- M. D. S. R. Bastos, "Physical and Mechanical Testing of Essential Oil-embedded Cellulose Ester Films", Polymer Testing, 49, pp.156~ (2016)
- S. B. Yang, "Morphological Comparison of Aligned Poly (vinyl alcohol) Nanofibers Fabricated by Modified Electrospinning and Centrifugal Jet Spinning Techniques", Journal of Nanoscience and Nanotechnology, 17(12), pp.9056~ (2017)
- Q. G. Zhang, "Sub-10 nm Wide Cellulose Nanofibers for Ultrathin Nanoporous Membranes with High Organic Permeation", Advanced Functional Materials, 26(5), pp.792~ (2016)