PAS를 위한 대기 중 PAHs의 소나무잎 침착율 산정
Sampling Rate Evaluation of Atmospheric PAHs to Pine Needles for Passive Air Sampler
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초록
This study was carried out to use pine needles as passive air sampler (PAS) of atmospheric polycyclic aromatic hydrocarbons (PAHs). PAHs concentrations in ambient air (C_a) and pine needles (C_p) were analyzedsimultaneously from June 1 to December 31 using low volume PUF active air sampler. Furthermore, sampling rates (m3/day-g dry) of PAHs in the air to pine needles were calculated using C_a and C_p. Average samplingrate was 0.16 (0.00068-0.91) m³/day-g dry, which was the greatest in PAHs (Pyr, BkF, BaA, Chry, BbF, and BkF) with molecular weight of 202.26-252.32 and octanol-air partitioning coefficient (logK_oa) of 8.61-11.37. These values were the lowest with respect to PUF disk, XAD-2 resin and semipermeable membrane devices (SPMDs) PAS, demonstrating that pine needles are suitable for long time PAS as a result of very low sampling rates
Abstract
This study was carried out to use pine needles as passive air sampler (PAS) of atmospheric polycyclic aromatic hydrocarbons (PAHs). PAHs concentrations in ambient air (C_a) and pine needles (C_p) were analyzedsimultaneously from June 1 to December 31 using low volume PUF active air sampler. Furthermore, sampling rates (m3/day-g dry) of PAHs in the air to pine needles were calculated using C_a and C_p. Average samplingrate was 0.16 (0.00068-0.91) m³/day-g dry, which was the greatest in PAHs (Pyr, BkF, BaA, Chry, BbF, and BkF) with molecular weight of 202.26-252.32 and octanol-air partitioning coefficient (logK_oa) of 8.61-11.37. These values were the lowest with respect to PUF disk, XAD-2 resin and semipermeable membrane devices (SPMDs) PAS, demonstrating that pine needles are suitable for long time PAS as a result of very low sampling rates
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