유연한 탄화규소 섬유 로프 발열체의 제조와 저항 발열 특성
Fabrication and resistance heating properties of flexible SiC fiber rope as heating elements
0
조회
0
다운로드
0
인용
0
참고문헌
키워드
초록
고분자로부터 제조되는 탄화규소 섬유는 고온 내산화성, 인장강도, 그리고 경량성 때문에 세라믹 복합체의 강화재료로 주로 적용되고 있다. 본 연구에서 탄화규소 연속섬유는 유연한 로프 형태의 고온 발열체(> 650℃)로 제조하기 위해사용되었다. 특히, 탄화규소 섬유 발열체는 고효율의 저항 발열을 위해 단면적과 길이에 대한 저항 변화를 2-point probe 방법으로 측정하고, 비정질 탄화규소 섬유에 존재하는 산소 불순물과 결정립의 크기 제어를 통해 로프형 섬유 발열체의 저항값을 최적화하였다. 그 결과, 약 100~200Ω의 저항 범위를 가지는 탄화규소 섬유 발열체는 탄소 섬유 발열체보다 1.5배의우수한 소비전력 효율을 가졌다.
Abstract
Silicon carbide (SiC) fibers mainly fabricated from polycarbosilane, a ceramic precursor, are applied as reinforcingmaterials for ceramic matrix composites (CMCs) because of their high temperature oxidation resistance, tensile strength, andlight weight. In this study, continuous SiC fibers used to fabricate rope-type flexible heating elements capable of generatinghigh-temperature heat (> 650℃). For high-efficiency heating elements, the resistance of SiC fiber rope was measured by 2-point probe method according to the cross-sectional area and length. In addition, the fabrication conditions of rope-type SiCfiber heating elements were optimized by controlling the oxygen impurities and the size of crystal grains present in theamorphous SiC fiber. As a result, the SiC fiber heating element having a resistance range of about 100~200 Ω exhibited anexcellent power consumption efficiency of 1.5 times compared to that of the carbon fiber heating element.
참고문헌 (20)
- W.H. Gloor, "Inorganic fibers-formation and properties", Text Res. J, 1, pp.626~ (1966)
- T.F. Cooke, "Inorganic fibers—A literature review", J. Am. Ceram. Soc, 74, pp.2959~ (1991)
- A. Mortensen, "Metal matrix composites", Annu. Rev. Mater. Res, 40, pp.243~ (2010)
- W.B. Hilling, "Strength and toughness of ceramic matrix composites", Annu. Rev. Mater. Res, 17, pp.341~ (1987)
- R. Naslain, "Design, preparation and properties of nonoxide CMCs for application in engines and nuclear reactors : an overview", Compos. Sci. Technol, 64, pp.155~ (2004)
- M. Sharma, "Carbon fiber surfaces and composite interphases", Compos. Sci. Technol, 102, pp.35~ (2014)
- C. Soutis, "Carbon fiber reinforced plastics in aircraft construction", Mater. Sci. Eng. A, 412, pp.171~ (2005)
- F.K. Wang, "Thermal transport in carbon-based nanomaterials Vol. 7" (2017), Elsevier Inc
- R.S. Hay, "Hi-nicalonTM-S SiC fiber oxidation and scale crystallization kinetics", J. Am. Ceram. Soc, 94, pp.3983~ (2011)
- T. Ishikawa, "Recent development of the sic fiber nicalon and its composites, including properies of the sic fiber hi-nicalon for ultra-high temperature", Compos. Sci. Technol, 51, pp.135~ (1994)
- H. Ichikawa, "Polymer-derived ceramic fibers", Annu. Rev. Mater. Res, 46, pp.335~ (2016)
- Young Jun Joo, "Effect of pyrolysis temperature on heat-generating behavior and morphology of SiC fiber mats", Journal of Ceramic Processing Research, 20(5), pp.563~569 (2019), 청정에너지연구소[DOI]
- Khos-Erdene Khishigbayar, "Microwave-Assisted Heating of Electrospun SiC Fiber Mats", 한국세라믹학회지, 54(6), pp.499~505 (2017), 한국세라믹학회
- S. Cao, "Formation mechanism of large SiC grains on SiC fiber surfaces during heat treatment", CrystEngComm, 18, pp.3674~ (2016)
- Y. Sasaki, "Raman study of SiC fibres made from polycarbosilane", J. Mater. Sci, 22, pp.443~ (1987)
- K. Morishita, "Degradation mechanism of amorphous silicon carbide fiber due to air-exposure at high temperatures", Mater. Trans, 48, pp.111~ (2007)
- J. Hong, "In situ generation of graphene network in silicon carbide fibers: Role of iodine and carbon monoxide", Carbon, 158, pp.110~ (2020)
- C. Smith, "Determination of silicon carbide fiber electrical resistivity at elevated temperature", Int. J. Appl. Ceram. Technol, 14, pp.228~ (2017)
- Z. Yu, "Role of insitu formed free carbon on electromagnetic absorption properties of polymer-derived SiC ceramics", J. Adv. Ceram, 9, pp.617~ (2020)
- T. Kim, "Microwave heating of carbon-based solid materials", Carbon Lett, 15, pp.15~ (2014)
