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HPLC Tandem/MS를 이용한 흑색 젤펜 잉크의 염료성분 분석 및 개체 특성에 관한 연구

Study on the Dye Components of Black Gel Pen Inks by HPLC-Tandem/MS

박성우|최미정|선일식|김창성
한국과학수사학회 (The Korean Academy of Scientific Criminal Investigation)|2011.06|과학수사학회지 (Journal of Science Criminal Investigation)|제5권 제2호|pp. 123-132|DOI 10.20297/jsci.2011.5.2.123

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참고문헌

키워드

discriminationclassificationdyeforensic scienceHPLCgelpeninkstandem massHPLC/MS

초록

젤펜잉크 중 함유되어 있는 염료 성분에 대한 동시 다성분 분석법을 확립하였고 스크리닝을 통하여 개체별 함유 염료의 특성자료를 확보하고자 3개국에서 생산된 16종의 흑색 젤펜잉크 카트리지를 시료로 분석하였다. 검출된 염료의 M+H 질량으로는 358(MVB, methyl violet B base), 372(CV, crystal violet), 395(Methyl violet), 453(Acid Orange 10), 458(Sudan Black B), 478(VPBBO, victoria pure blue BO), 545(PBVF, patent blue VF), 582(Acid red 52), 788(Aniline blue diammonium salt) 으로 총 8가지가 검출되었다. 그중 M+H 372(CV, crystal violet ), 453(Acid orange 10), 458(Sudan black B), 478(VPBBO, victoria pure blue BO) 4가지의 경우 16종 젤펜 모든 시료에서 검출되었으며 M+H 788(Aniline blue diammonium salt)은 4종류의 절펜에서 검출되었고, M+H 582(Acid red 52)는 2종류의 젤펜에서 그리고 M+H 358(MVB, methyl violet B base)와 545(PBVF, patent blue VF)는 각 각 1종류의 젤펜에서 검출되는 것으로 나타나 생산국에 따른 특성과 제조사별 특정성분의 함유분포를 알 수 있어서 잉크 염료 성분으로 개체특성을 확인하였다.

Abstract

In this study, dyes of black gel pen inks was screening to identify individual characteristic of gel pen inks. Detected dyes was total 8 species(M+H 358(MVB, methyl violet B base), 372(CV, crystal violet), 395(Methyl violet), 453(Acid orange 10), 458(Sudan black B), 478(VPBBO, victoria pure blue BO), 545(PBVF, patent blue VF), 582(Acid red 52), 788(Aniline blue diammonium salt)). M+H 372(CV, crystal violet), 453(Acid orange 10), 458(Sudan black B), 478(VPBBO, victoria pure blue BO) were contained in all Gelpen. M+H 788(Aniline blue diammonium salt) was detected in 4 kinds of Gelpen, M+H 582(Acid red 52) was detected in 2 kinds of Gelpen, M+H 358(MVB, methyl violet B base) was detected in 1 Gelpen and 545(PBVF, patent blue VF) was detected in 1 Gelpen. The results of this study indicated that distinct characteristic about manufacture and brand could make a discriminating tool of inks for identification of between gel pen inks.

참고문헌 (39)

  1. M.N. Gernandt, "An introduction to the GelPen", J. Forensic Sci, 41, pp.503~504 (1996)
  2. L. Richard, "In Advances in the forensic analysisand dating of writing ink", pp.13~46 (2003), Springfield
  3. Xu Yuanyuan, "Dating the writing age ofblack roller and gel inks by gas chromatography andUV-vis spectrophotometer", J. Forensic Sci Int, 164, pp.140~143 (2006)
  4. M.Claybournand, "Using Raman spectros copy to solve crime inks,questioned documents and fraud", Sci.Justice, 40, pp.261~271 (2000)
  5. N.Y.Kim, , Analytical science & technology, 17, pp.312~315 (2004)
  6. A.Kher, "Forensic classificationof ballpoint pen inks using high performance liquidchromatography and infrared spectroscopy withprincipal components analysis and linear discriminantanalysis", 40, pp.270~277 (2006)
  7. P.C.White, "Insitusurface-enhanced resonance Ramanscattering(SERRS)spectroscopy of biroinkslongtermstability of colloid treated samples", Sci.Justice, 43, pp.149~152 (2003)
  8. J.A.Zlotnick, "Chromatographic and electrophoreticapproaches in ink analysis", J.Chromatogr, 733, pp.265~272 (1999)
  9. C.D.Adam, "Classification and individualisationof black ballpointpen inks using principal componentanalysis of UVvis absorption spectra", J.ForensicSciInt, 174, pp.16~25 (2008)
  10. R. Loos, "Solid-phaseextraction of polar hydrophilic aromatic sulfonatesfollowed by capillary zone electrophoresisUV absorbancedetection and ion-pair liquid chromatographydiodearray UV detection and electrospray massspectrometry", J. Chromatogr, 890, pp.225~237 (2000)
  11. V.Stanek, "Effects of substitutedcyclodextrins on the separation of aromatic sulphonicacids by capillary zone electrophoresis", J.Chromatogr, 948, pp.235~247 (2002)
  12. M. Perez-Urquiza, "Determination of sulfonatedazo dyes in river water samples by capillary zone electrophoresis", J. Chromatogr, 883, pp.277~283 (2000)
  13. S. Angelino, "Ion-interaction high-performanceliquid chromatography and micellar electrokinetic capillarychromatography: two complementary techniquesfor the separation of aromatic sulfonated compounds", J.Chromatogr, 845, pp.257~271 (1999)
  14. M. Perez-Urquiza, "Determination of thedissociation constants of sulfonated azo dyes by capillaryzone electrophoresis and spectrophotometry methods", J. Chromatogr, 917, pp.331~336 (2001)
  15. J. Umemura, , Vib. Spectrosc, 38, pp.29~ (2005)
  16. D.M. Milojkovic-Opsenica, "Reversed-phase thin-layer chromatographyof some foodstuff dyes", JPC J. PlanarChromatogr, 16, pp.276~279 (2003)
  17. W.C. Shu, "Determination of fluorescentwhitening agents in laundry detergents and surfacewaters by solid-phase extraction and ion-pair high-performanceliquid chromatography", J. Chromatogr, 1088, pp.218~223 (2005)
  18. Y. Miura, "Stabilization ofsulfide and sulfite and ion-pair chromatography of mixturesof sulfide, sulfite, sulfate and thiosulfate", J. Chromatogr, 1085, pp.47~53 (2005)
  19. R. Palmans, "Ion-pair chromatography of bis(sodium-sulfopropyl) disulfide brightener in acidiccopper plating baths", J. Chromatogr, 1085, pp.147~154 (2005)
  20. S.P. Wang, "Comparison of ion-pair chromatographyand capillary zone electrophoresis for theassay of organic acids as markers of abnormal metabolism", J. Chromatogr, 1051, pp.213~219 (2004)
  21. M.R. Fuh, "Determination of free-form amphetaminein rat brain by ion-pair liquid chromatographyelectrospraymass spectrometry with in vivomicrodialysis", J. Chromatogr, 1031, pp.197~201 (2004)
  22. P.Jandera, "Separation of isomericnaphthalene sulphonic acids by micro highperformanceliquid chromatography with mobilephases containing cyclo dextrin", J.Chromatogr, 871, pp.139~152 (2000)
  23. A. Plum, "Strategies for continuous onlinehigh performance liquid chromatography coupledwith diode array detection and electrospray tandemmass spectrometry for process monitoring of sulphonatedazo dyes and their intermediates in anaerobicaerobicbioreactors", J. Chromatogr, 1084, pp.119~133 (2005)
  24. M. Huang, "Analysis of fiber dyes by liquid chromatographymass spectrometry (LC-MS) with electrosprayionization: discriminating between dyes withindistinguishable UV-visible absorption spectra", J.Forensic Sci, 50, pp.526~534 (2005)
  25. A.Krivohlavek, "The determination of sulfonamides in honey by high performance liquid chroma-tographymass spectrometry method(LC", MS), 2005, pp.28, 1434~1439
  26. J. A. Zlotnick, "Chromatographic and electrophoreticapproaches in ink analysis", J. Chromatogr, 733, pp.265~272 (1999)
  27. S. Garcia-Marco, "Gradient ion-pair chromatographicmethod for the determination of iron N,N-ethylenediamine-di-(2-hydroxy-5-sulfophenylacetate) byhigh performance liquid chromatographyatmosphericpressure ionization electrospray mass spectrometry", J.Chromatogr, 1064, pp.67~74 (2005)
  28. P. J. Lee, "Acquity UPLC separation oftriarylmethane ink dyes(PART1)", ~ (2005), ApplicationNote 720001262EN
  29. K. Hunger, "Industrial Dyes:Chemistry, Properties,Application", pp.495~508 (2003), Wiley-VCH
  30. C. Rafols, "Determination of mono-and disulphonatedazo dyes by liquid chromatography-atmosphericpressure ionization mass spectrometry", J. Chromatogr, 777, pp.177~192 (1997)
  31. M. Holcapek, "High performance liquid chromatography-massspectrometric analysis of sulphonateddyes and intermediates", J. Chromatogr, 926, pp.175~186 (2001)
  32. H.Zou, "NACE discrimination of black ballpointpen inks", J.Chromatographia, 67, pp.483~486 (2008)
  33. Y. Liu, "Studies on the degradation of blue gelpen dyes by ion-pairing high performance liquid chromatographyand electrospray tandem mass spectrometry", J. Chromatography, 1125, pp.95~103 (2006)
  34. M. Puchalska, "Identification of indigoid dyes innatural organic pigments used in historical art objectsby high-performance liquid chromatography coupled toelectrospray ionization mass spectrometry", J.MassSpectrom, 39, pp.1441~1449 (2004)
  35. M. Huang, "Forensic identificationof dyes extracted from textile fibers by liquidchromatography mass spectrometry (LC-MS)", J.Forensic Sci, 49, pp.238~249 (2004)
  36. C. Miller-Stein, "Determinationof chiral sulfoxides in plasma by normal-phase liquidchromatographyatmospheric pressure chemical ionizationmass spectrometry", J. Chromatogr, 964, pp.161~168 (2002)
  37. L. Zhang, "Simultaneous determination of thyreostatic residues in animal tissuesby matrix solid-phase dispersion and gas chroma to graphy mass spectrom etry", J. Chromatogr, 1074, pp.17~ (2005)
  38. M. Hol capek, "High performance liquid chromatographymassspectrometric analysis of sulphonateddyes and intermediates", J. Chromatogr, 926, pp.175~186 (2001)
  39. Jeffrey D. Wilson, "Differentiation of Black Gel Inks Using Optical and Chemical Techniques", J. Forensic Sci, 49, pp.364~370 (2004)

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