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Rapid and Efficient Debromination of vic-Dibromides with VCl3/Indium System

박지연|유병우|신효종
대한화학회|2018.08|대한화학회지 (Journal of the Korean Chemical Society)|제62권 제4호|pp. 275-278|DOI https://doi.org/10.5012/jkcs.2018.62.4.275

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참고문헌

키워드

IndiumDebrominationvic-DibromideVanadium(III) chloride
주제분류화학

초록

The VCl3/In system was found to be a new protocol for debromination of a variety of vic-dibromides to the corresponding alkenes in high yields with short reaction times under mild conditions. This new methodology is highly chemoselective, tolerating several functional groups such as chloro, bromo, fluoro, keto, ester, carboxyl, and methoxy groups.

Abstract

The VCl3/In system was found to be a new protocol for debromination of a variety of vic-dibromides to the corresponding alkenes in high yields with short reaction times under mild conditions. This new methodology is highly chemoselective, tolerating several functional groups such as chloro, bromo, fluoro, keto, ester, carboxyl, and methoxy groups.

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