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A Systematic Study on Knoevenagel Reaction and Nazarov Cyclization of Less Reactive Carbonyl Compounds Using Rare Earth Triflates and Its Applications

A. Ilangovan|S. Muralidharan|S. Maruthamuthu
대한화학회|2011.12|대한화학회지 (Journal of the Korean Chemical Society)|제55권 제6호|pp. 1000-1006

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참고문헌

키워드

13-diketonesKnoevenagel ReactionNazarov cyclizationYetterbium triflateEthyl acetoacetate
주제분류화학

초록

A systematic study of Knoevenagel reaction and Nazarov cyclization was made on variety of less reactive carbonyl compounds such as β-ketoesters, 1,3-diketones and cyclic active methylene compounds using Yb(OTf)_3 as the catalyst. Recycling study confirms reusability of the catalyst without much loss of activity.

Abstract

A systematic study of Knoevenagel reaction and Nazarov cyclization was made on variety of less reactive carbonyl compounds such as β-ketoesters, 1,3-diketones and cyclic active methylene compounds using Yb(OTf)_3 as the catalyst. Recycling study confirms reusability of the catalyst without much loss of activity.

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