Spectrophotometric Determination of Maximum Loading Capacity of a Dendrimer
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초록
A series of hydrophobic dodecyl-terminated 6th-generation poly(amidoamine) dendrimer (H)-encapsulated cadmium sulfide ((CdS)n@H) nanoparticles in a co-solvent (toluene: methanol = 6.8: 3.2 v/v) are synthesized. The diameters of CdS nanoparticles within the dendrimer were estimated by analyzing the positions of the first excitonic absorption peaks of CdS in UV-vis spectra. The size of the CdS nanoparticle within the dendrimer shows a saturation value as the CdS/H ratio (n) increases, which is believed to be due to the limited physical size of the void cavity within the dendrimer. This simple and convenient method of estimating the saturation of the size of CdS in dendrimers may be useful in determining the maximum void space within other dendrimers under various solvent conditions.
Abstract
A series of hydrophobic dodecyl-terminated 6th-generation poly(amidoamine) dendrimer (H)-encapsulated cadmium sulfide ((CdS)n@H) nanoparticles in a co-solvent (toluene: methanol = 6.8: 3.2 v/v) are synthesized. The diameters of CdS nanoparticles within the dendrimer were estimated by analyzing the positions of the first excitonic absorption peaks of CdS in UV-vis spectra. The size of the CdS nanoparticle within the dendrimer shows a saturation value as the CdS/H ratio (n) increases, which is believed to be due to the limited physical size of the void cavity within the dendrimer. This simple and convenient method of estimating the saturation of the size of CdS in dendrimers may be useful in determining the maximum void space within other dendrimers under various solvent conditions.
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