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Application of the Electrochemical Noise Method with Three Electrodes to Monitor Corrosionand Environmental Cracking in Chemical Plants

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주제분류금속공학

초록

Recently an electrochemical noise method (ENM) with three electrodes has gained attention as a corrosion monitoring system in chemical plants. So far a few studies have been carried out for localized corrosion and environmental cracking of chemical plant materials. In this paper the ENM system is briefly summarized. Then an application of ENM to general corrosion for chemical plant materials is described. The emphasis is focused upon the analysis of stress on the corrosion cracking process of austenitic stainless steel in 30% MgCl₂ aqueous solution and the corrosion fatigue crack initiation process of 12 Cr stainless steel in 3% NaCl aqueous solution by ENM. Finally future problems for ENM to monitor regarding corrosion and environmental cracking in chemical plants are discussed.

Abstract

Recently an electrochemical noise method (ENM) with three electrodes has gained attention as a corrosion monitoring system in chemical plants. So far a few studies have been carried out for localized corrosion and environmental cracking of chemical plant materials. In this paper the ENM system is briefly summarized. Then an application of ENM to general corrosion for chemical plant materials is described. The emphasis is focused upon the analysis of stress on the corrosion cracking process of austenitic stainless steel in 30% MgCl₂ aqueous solution and the corrosion fatigue crack initiation process of 12 Cr stainless steel in 3% NaCl aqueous solution by ENM. Finally future problems for ENM to monitor regarding corrosion and environmental cracking in chemical plants are discussed.

참고문헌 (8)

  1. S. Haruyama, , Boshoku-Gijutsu, 27, pp.449~ (1978)
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  3. D. A. Eden, "Uhlig Corrosion Handbook", pp.1227~ (2000), John Wiley&Sons
  4. M. Miyazawa, , Zairyo-to-Kankyo, 53 (2004)
  5. M. Miyazawa, , Strength Fracture and Complexity, 4, pp.129~ (2006)
  6. M. Kowaka, , Tetsu-to-Hagane, 62, pp.390~ (1976)
  7. S. Kim, , Journal of the Japanese Society for Strength and Fracture of Materials, 40, pp.35~ (2006)
  8. R. Ebara, "Materials Science & Engineering A" (2007)

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