3D 프린팅 가동 조건 별 발생 입자크기 분포와 흡입 노출량 추정
Size Distributions of Particulate Matter Emitted during 3D Printing and Estimates of Inhalation Exposure
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참고문헌
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초록
Objective: This study aimed to identify the size distributions of particulate matter emitted during 3D printing according to operational conditions and estimate particle inhalation exposure doses at each respiratory region. Methods: Four types of printing filaments were selected: acrylonitrile-butadiene-styrene (ABS), polylactic acid (PLA), Laywood, and nylon. A fused deposition modeling (FDM) 3D printer was used for printing. Airborne particles between 10 nm and 10 µm were measured before, during, and after printing using real-time monitors under extruder temperatures from 215 to 290 o C. Inhalation exposures, including inhaled and deposited doses at the respiratory regions, were estimated using a mathematical model. Results: Nanoparticles dominated among the particles emitted during printing, and more particles were emitted with higher temperatures for all materials. Under all temperature conditions, the Laywood emitted the highest particle concentration, followed by ABS, PLA, and nylon. The particle concentration peaked for the initial 10 to 20 minutes after starting operations and gradually decreased with elapsed time. Nanoparticles accounted for a large proportion of the total inhaled particles in terms of number, and about a half of the inhaled nanoparticles were estimated to be deposited in the alveolar region. In the case of the mass of inhaled and deposited dose, particles between 0.1 and 1.0 µm made up a large proportion. Conclusion: The number of consumers using 3D printers is expected to expand, but hazardous emissions such as thermal byproducts from 3D printing are still unclear. Further studies should be conducted and appropriate control strategies considered in order to minimize human exposure.
Abstract
Objective: This study aimed to identify the size distributions of particulate matter emitted during 3D printing according to operational conditions and estimate particle inhalation exposure doses at each respiratory region. Methods: Four types of printing filaments were selected: acrylonitrile-butadiene-styrene (ABS), polylactic acid (PLA), Laywood, and nylon. A fused deposition modeling (FDM) 3D printer was used for printing. Airborne particles between 10 nm and 10 µm were measured before, during, and after printing using real-time monitors under extruder temperatures from 215 to 290 o C. Inhalation exposures, including inhaled and deposited doses at the respiratory regions, were estimated using a mathematical model. Results: Nanoparticles dominated among the particles emitted during printing, and more particles were emitted with higher temperatures for all materials. Under all temperature conditions, the Laywood emitted the highest particle concentration, followed by ABS, PLA, and nylon. The particle concentration peaked for the initial 10 to 20 minutes after starting operations and gradually decreased with elapsed time. Nanoparticles accounted for a large proportion of the total inhaled particles in terms of number, and about a half of the inhaled nanoparticles were estimated to be deposited in the alveolar region. In the case of the mass of inhaled and deposited dose, particles between 0.1 and 1.0 µm made up a large proportion. Conclusion: The number of consumers using 3D printers is expected to expand, but hazardous emissions such as thermal byproducts from 3D printing are still unclear. Further studies should be conducted and appropriate control strategies considered in order to minimize human exposure.
참고문헌 (28)
- Noorani R., "Rapid prototyping: principles and applications" (2006), John Wiley and Sons Inc
- Vance ME, "Aerosol emissions from fuse-deposition modeling 3D printers in a chamber and in real indoor environments", Environ Sci Technol, 51(17), pp.9516~9523 (2017)
- Wong KV, "A review of additive manufacturing", ISRN Mecha Eng, pp.1~10 (2012)
- A pilot study to evaluate VOCs outgassed in polymer filaments used in 3D printing, "Cheves S.", 1~26 (2014)
- Cimino D, "3d printing technologies: are their materials safe for conservation treatments?", IOP Conference Series: Materials Science and Engineering (2018), IOP Publishing
- Lithner D, "Environmental and health hazard ranking and assessment of plastic polymers based on chemical composition", Sci Total Environ, 409(18), pp.3309~3324 (2011)
- Stabile L, "Airborne particle emission of a commercial 3D printer: The effect of filament material and printing temperature", Indoor Air, 27(2), pp.398~408 (2017)
- Azimi P, "Emissions of ultrafine particles and volatile organic compounds from commercially available desktop three-dimensional printers with multiple filaments", Environ Sci Technol, 50(3), pp.1260~1268 (2016)
- Kim Y, "Emissions of nanoparticles and gaseous material from 3D printer operation", Environ Sci Technol, 49(20), pp.12044~12053 (2015)
- Kwon O, "Characterization and control of nanoparticle emission during 3D printing", Environ Sci Technol, 51(18), pp.10357~10368 (2017)
- Human Respiratory Tract Model for Radiological Protection, "International Commission on Radiological Protection", ICRP Publication, 24~21, pp.ICRP Publication 66 (1994)
- Wojtyła S, "Is 3D printing safe? Analysis of the thermal treatment of thermoplastics:ABS, PLA, PET, and nylon", J Occup Env Hyg, 14(6), pp.D80~D85 (2017)
- Choi C., "Characteristics of particle emissions according to parameter setting", pp.2016
- Stefaniak AB, "Characterization of chemical contaminants generated by a desktop fused deposition modeling 3-dimensional Printer", J Occup Env Hyg, 14(7), pp.540~550 (2017)
- Steinle P., "Characterization of emissions from a desktop 3D printer and indoor air measurements in office settings", J Occup Env Hyg, 13(2), pp.121~132 (2016)
- Yi J, "Emission of particulate matter from a desktop three-dimensional (3D)printer", J Toxic Env Health Part A, 79(11), pp.453~465 (2016)
- Afshar-Mohajer N, "Characterization of particulate matters and total VOC emissions from a binder jetting 3D printer", Build Environ, 93, pp.293~301 (2015)
- Du Preez S, "Exposures during industrial 3-D printing and post-processing tasks", Rapid Prototyping J, pp.1~8 (2018)
- Ryan T, "3-D printing hazards: Literature review & preliminary hazard assessment", Prof Saf, 61(6), pp.56~62 (2016)
- Stephens B, "Ultrafine particle emissions from desktop 3D printers", Atmos Environ, 79, pp.334~339 (2013)
- Yang Y, "Total volatile organic compound emission evaluation and control for stereolithography additive manufacturing process", J Clean Prod, 170, pp.1268~1278 (2018)
- Deng Y, "The impact of manufacturing parameters on submicron particle emissions from a desktop 3D printer in the perspective of emission reduction", Build Environ, 104, pp.311~319 (2016)
- Zhou Y, "Investigation of ultrafine particle emissions of desktop 3D printers in the clean room", Procedia Engineer, 121, pp.506~512 (2015)
- Mansour OY, "Thermal degradation of some thermoplastic polymers in presence of lignin", Polym-Plast Technol, 31(9-10), pp.747~758 (1992)
- Rutkowski JV, "Acrylonitrile–butadiene–styrene copolymers(ABS): Pyrolysis and combustion products and their toxicity-a review of the literature", Fire Mater, 10(3-4), pp.93~105 (1986)
- Park J, "Spatial-Temporal Dispersion of Aerosolized Nanoparticles During the Use of Consumer Spray Products and Estimates of Inhalation Exposure", Environ Sci Technol, 51(13), pp.7624~7638 (2017)
- Nazarenko Y, "Quantitative assessment of inhalation exposure and deposited dose of aerosol from nanotechnology-based consumer sprays", Environ Sci Nano, 1, pp.161~171 (2014)
- Azimi P, "Predicting concentrations of ultrafine particles and volatile organic compounds resulting from desktop 3D printer operation and the impact of potential control strategies", J Ind Ecol, 21(S1), pp.S107~S119 (2017)
