본문 바로가기
KERD
논문

소나무 잎을 이용한 대기 중 다이옥신/퓨란 발생원 추정

Source Tracking of PCDD/Fs in Ambient Air Using Pine Needles

천만영|김정수|고도현
한국환경보건학회 (Korean Society of Environmental Health)|2015.02|한국환경보건학회지 (JOURNAL OF ENVIRONMENTAL HEALTH SCIENCES)|제41권 제1호|pp. 49-60|DOI http://dx.doi.org/10.5668/JEHS.2015.41.1.49

2

조회

0

다운로드

1

인용

0

참고문헌

키워드

PCAPine needlePCDD/FsSource contributionWaste incineratorPAS

초록

Objectives: Pine needles were used as a passive air sampler (PAS) of atmospheric persistent organic pollutants(POPs). This study was performed to investigate concentrations of polychlorinated dibenzo-p-dioxins anddibenzofurans (PCDD/Fs) deposited on pine needles near a waste incinerator and PCDD/Fs source contributionsusing principal component analysis (PCA). Methods: Two-year-old pine needles were sampled at 11 points with respect to distance and wind direction fromthe incinerator. PCDD/Fs deposited on pine needles were analyzed with HRGC/HRMS. The source contributionof PCA was calculated with SPSS. Results: The average concentration of PCDD/Fs deposited on pine needle was 0.79 (0.27-1.76) pg TEQ/g dry,PCDDs with 0.24 (0.01-0.95) pg TEQ/g dry and PCDFs with 0.56 (0.27-0.82) pg TEQ/g dry, respectively. Theaverage concentration fraction of PCDDs was 29.7%, that of PCDFs was 70.3%, and PCDFs were moreprevalent than PCDDs. The contributions of PCDD/Fs sources were estimated as incineration at 58.3% andautomobiles at 28.4%. However, a relation and regulation between PCDD/Fs concentrations deposited on pineneedles and distance from incinerator or wind direction was not shown. Conclusion: It was concluded that atmospheric PCDD/Fs concentrations near an industrial complex with awaste incinerator were affected by multiple sources. However, PCDD/Fs concentrations were lower than in otherinland cities with the exception of background area.

Abstract

Objectives: Pine needles were used as a passive air sampler (PAS) of atmospheric persistent organic pollutants(POPs). This study was performed to investigate concentrations of polychlorinated dibenzo-p-dioxins anddibenzofurans (PCDD/Fs) deposited on pine needles near a waste incinerator and PCDD/Fs source contributionsusing principal component analysis (PCA). Methods: Two-year-old pine needles were sampled at 11 points with respect to distance and wind direction fromthe incinerator. PCDD/Fs deposited on pine needles were analyzed with HRGC/HRMS. The source contributionof PCA was calculated with SPSS. Results: The average concentration of PCDD/Fs deposited on pine needle was 0.79 (0.27-1.76) pg TEQ/g dry,PCDDs with 0.24 (0.01-0.95) pg TEQ/g dry and PCDFs with 0.56 (0.27-0.82) pg TEQ/g dry, respectively. Theaverage concentration fraction of PCDDs was 29.7%, that of PCDFs was 70.3%, and PCDFs were moreprevalent than PCDDs. The contributions of PCDD/Fs sources were estimated as incineration at 58.3% andautomobiles at 28.4%. However, a relation and regulation between PCDD/Fs concentrations deposited on pineneedles and distance from incinerator or wind direction was not shown. Conclusion: It was concluded that atmospheric PCDD/Fs concentrations near an industrial complex with awaste incinerator were affected by multiple sources. However, PCDD/Fs concentrations were lower than in otherinland cities with the exception of background area.

참고문헌 (31)

  1. Eitzer BD, "Atmospheric transport and deposition of polychlorinated dibenzo-p-dioxins and dibenzofurans", Environ Sci Technol, 23(11), pp.1396~1401 (1989)
  2. Ministry of Environment., "Official method of polychlorinated dibenzo-p-dioxins", polychlorinated dibenzo-furans (PCDDs, HRMS, pp.Ministry of Environment Press, 2011[DOI]
  3. Shoeib M, "Characterization and comparison of three passive samplers for persistent organic pollutants", Environ Sci Technol, 36(19), pp.4142~4151 (2002)
  4. 천만영, "소나무잎에 침착된 PCDD", Fs 특성, 2005, pp.27(6), 599~605[DOI]
  5. 천만영, "소나무잎을 Passive Air Sampler(PAS)로 이용하여 대기 중 PCBs 농도 추정", 한국환경보건학회지, 38(4), pp.360~368 (2012), 한국환경보건학회[DOI]
  6. 천만영, "소나무잎과 토양에 침착된 PCDD", Fs 특성, 2005, pp.24(3), 280~288[DOI]
  7. Chun MY., "A study on the deposition of PCBs in air on coniferous needles", J Korean Soc of Environ Eng, 20(10), pp.1377~1383 (1998)
  8. 천만영, "PAS를 위한 대기 중 PAHs의 소나무잎 침착율 산정", 한국환경분석학회지, 14(2), pp.83~88 (2011), 한국환경분석학회
  9. 천만영, "시골과 도시지역의 소나무잎과 토양에 침착된 PAHs 특성", 한국환경분석학회지, 12(1), pp.6~12 (2009), 한국환경분석학회
  10. 천만영, "나이별 소나무 잎에 침착된 대기 중 폴리브롬화디페닐에테르 특성", 한국환경보건학회지, 40(4), pp.313~321 (2014), 한국환경보건학회[DOI]
  11. Juuti S, "Trichloroacetic acid in pine needles in the vicinity of a pulp mill", Chemosphere, 26(10), pp.1859~1868 (1993)
  12. Chun MY, "A study on the sampling error of PCBs deposited on pine needles", Korean J Environ Agric, 17(2), pp.17~121 (1998)
  13. 천만영, "대기 중 폴리브롬화디페닐에테르의 소나무 잎 침착 특성과 농도 보정법", 한국환경기술학회지, 15(4), pp.315~328 (2014), 한국환경기술학회
  14. Korea meteorogical administration., "Annual climatological report", pp.20~ (2013), Korea meteorogical administration Press
  15. HRMS, "Official method of persistent organic pollutants (POPs) in fish-HRGC", pp.2011, Ministry of Environment.
  16. "Tetra- Through Octa-Chlorinated Dioxins and Furans by Isotope Dilution HRGC/HRMS"[URL]
  17. Chang MB, "Dioxin emission factors for automobiles from tunnel air sampling in northern Taiwan", Sci Total Environ, 325(1-3), pp.129~138 (2004)
  18. Kim KS, "Emission characteristics of PCDD", Fs in diesel engine with variable load rate, 2003, pp.53(6), 601~607
  19. Park JS, "Monitoring of dioxin levels in stack gas of incinerator and environmental Samples", J Korean Soc Environ Analys, 5(2), pp.89~93 (2002)
  20. 김용진, "생활 및 영농 폐기물의 노천소각에 의한 다이옥신류의 배출", 한국폐기물자원순환학회지, 25(1), pp.66~72 (2008), 한국폐기물자원순환학회
  21. 김경수, "청주지역 대기 중 PCDD", Fs 오염특성 및 거동, 2009, pp.31(4), 294~299[DOI]
  22. 강병욱, "CMB모델 적용을 위한 대기 미세먼지(PM_2.5) 중 원소분석방법에 관한 비교 연구", 한국환경분석학회지, 14(4), pp.198~205 (2011), 한국환경분석학회
  23. Tian FL, "Source identification of PCDD", Fs and PCBs in pine (Cedrus deodara) needles: A case study in Dalian, China, 2008, pp.42(19), 4769~4777
  24. Badol C, "Using a sourcereceptor approach to characterise VOC behaviour in a French urban area influenced by industrial emissions Part II: source contribution assessment using the Chemical Mass Balance (CMB) model", Sci Total Environ, 389(2-3), pp.429~440 (2008)
  25. Li GL, "Source contributions of PAHs and toxicity in reed wetland soils of Liaohe estuary using a CMB-TEQ method", Sci Total Environ, 490, pp.199~204 (2014)
  26. Cho YS, "Sensitivity analysis of the CMB modeling results by considering photochemical degradation of polycyclic aromatic hydrocarbons (PAHs) in the Seoul atmosphere", Par Aerosol Res, 10(1), pp.9~17 (2014)
  27. 김종국, "이성체 정보를 이용한 토양 중 다이옥신 오염원 해석", 대한환경공학회지, 27(3), pp.316~322 (2005), 대한환경공학회
  28. Kim BH, "A case study of dioxin monitoring in and around an industrial waste incinerator in Korea", Chemosphere, 58(11), pp.1589~1599 (2005)
  29. 김용진, "보리 짚 소각재와 농지 중 다이옥신류 농도 분포", 한국도시환경학회지, 9(1), pp.81~87 (2009), 한국도시환경학회
  30. Ok G, "Monitoring of air pollution by polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans of pine needles in Korea", Chemospere, 46(9-10), pp.1351~1357 (2002)
  31. "Carcinogen-Reduction of national PCDD/Fs emission quantity in Korea" (2014)[URL]

관련 논문AI추천

소나무 잎을 PAS로 이용하여 대기 중 PCDD/Fs 농도 추정천만영한국환경보건학회 · 한국환경보건학회지2015 · 제41권 제2호소나무잎을 PAS로 이용하여 지역별 대기 중 PCBs 농도 추정천만영한국환경보건학회 · 한국환경보건학회지2013 · 제39권 제2호소나무잎을 Passive Air Sampler(PAS)로 이용하여 대기 중 PCBs 농도 추정천만영한국환경보건학회 · 한국환경보건학회지2012 · 제38권 제4호소나무잎을 Passive Air Sampler로 이용하여 지역별 대기 중 다환방향족 탄화수소의 농도 및 발생원 추정천만영한국환경보건학회 · 한국환경보건학회지2014 · 제40권 제1호대기 중 PCBs의 PAS에 이용되는 여러 매체의 PCBs 침착 특성천만영한국환경보건학회 · 한국환경보건학회지2013 · 제39권 제2호나이별 소나무 잎에 침착된 대기 중 폴리브롬화디페닐에테르 특성천만영한국환경보건학회 · 한국환경보건학회지2014 · 제40권 제4호

이 간행물의 다른 논문 (6건)

불산 누출사고에 따른 지역사회 구성원들의 노출평가이현수, 김순신, 우극현, 양원호, 유승도, 조용성, 김근배, 이석용, 윤성용, 임현술pp. 1-10금연정책 시행이 전국 PC방의 간접흡연에 미치는 영향양원호, 이기영, 김성렬, 김성천, 하권철, 곽수영pp. 11-16나노물질의 세포독성 평가법으로 Colony Forming Efficiency Assay에 대한 검증연구최경희, 이재우, 박선영, 김필제, 조은혜, 엄익춘pp. 17-23대학생들의 혈액 내 휘발성 유기화합물 노출에 영향을 미치는 요인신원호, 최정미, 김민수, 문찬석pp. 24-29국내 유통 한약재의 중금속 함량 모니터링 -서울과 대구지역 한약재 중심으로 -이아영, 장설, 이아름, 김호경, 최고야pp. 30-39
원문 보기