Carboxylated Alginic Acid 및 이를 함유한 세정용 화장품의 납 흡착 효과
Lead Adsorption by Carboxylated Alginic Acid and Its Application in Cleansing Cosmetics
1
조회
0
다운로드
0
인용
0
참고문헌
키워드
초록
This study investigated lead adsorption by carboxylated alginic acid and its application in cleansing cosmetics. Carboxylated alginic acid showed the highest lead adsorptivity after oxidation in a 4–6 mM hydrogen peroxide solution at 20–30℃ for 30–40 min. Carboxylated alginic acid adsorbed 648.1±2.8–653.0±2.9 mg/g of lead dry mass at pH 4–6. Carboxylated alginic acid modified by hydrogen peroxide and potassium permanganate adsorbed 651.3±3.8 and 639.9±4.0 mg/g of lead dry mass, respectively. Carboxylated alginic acid showed higher lead adsorptivity after modification by hydrogen peroxide than by potassium permanganate, with an increase of ~30% compared with raw alginic acid. To access the potential application of carboxylated alginic acid in cleansing cosmetics, we investigated the lead adsorptivity, conditions of the cosmetics procedure, and cytotoxicity of various concentrations of cleansing cosmetics added to 5% carboxylated alginic acid. The ideal cosmetic concentrations combined with 5% carboxylated alginic acid were 70% for peeling gel, 20% for massage cream, 20% for foam cleansing and 40% for cleansing cream. There was no cytotoxicity in cleansing cosmetics combined with 5% carboxylated alginic acid.
Abstract
This study investigated lead adsorption by carboxylated alginic acid and its application in cleansing cosmetics. Carboxylated alginic acid showed the highest lead adsorptivity after oxidation in a 4–6 mM hydrogen peroxide solution at 20–30℃ for 30–40 min. Carboxylated alginic acid adsorbed 648.1±2.8–653.0±2.9 mg/g of lead dry mass at pH 4–6. Carboxylated alginic acid modified by hydrogen peroxide and potassium permanganate adsorbed 651.3±3.8 and 639.9±4.0 mg/g of lead dry mass, respectively. Carboxylated alginic acid showed higher lead adsorptivity after modification by hydrogen peroxide than by potassium permanganate, with an increase of ~30% compared with raw alginic acid. To access the potential application of carboxylated alginic acid in cleansing cosmetics, we investigated the lead adsorptivity, conditions of the cosmetics procedure, and cytotoxicity of various concentrations of cleansing cosmetics added to 5% carboxylated alginic acid. The ideal cosmetic concentrations combined with 5% carboxylated alginic acid were 70% for peeling gel, 20% for massage cream, 20% for foam cleansing and 40% for cleansing cream. There was no cytotoxicity in cleansing cosmetics combined with 5% carboxylated alginic acid.
참고문헌 (27)
- Becker EW, "Limitation of heavy metal removal from wastewater by means of algae", Water Res, 17, pp.459~466 (1983)
- Butter TJ, "The kinetics of metal uptake by microbial biomass: lmplications for the design of a biosorption reactor", Water Sci Technol, 38, pp.279~286 (1988)
- 조주식, "미역폐기물의 중금속 흡탈착 특성", 한국환경농학회지, 23(2), pp.92~98 (2004), 한국환경농학회
- 최익원, "해조류(Laminaria species, Ecklonia stolonifera, Gelidium amansii, Undaria pinnatifida)에 의한 중금속 생물흡착 특성", 한국환경농학회지, 24(4), pp.370~378 (2005), 한국환경농학회
- 최익원, "해조류(Laminaria species, Ecklonia stolonifera, Gelidium amansii, Undaria pinnatifida)에 의한 중금속 생물흡착 특성", 한국환경농학회지, 24(4), pp.370~378 (2005), 한국환경농학회
- Crist RH, "Interaction of metals and protons with algae. 3. Marine algae, with emphasis on lead and aluminum", Environ Sci Technol, 26, pp.496~502 (1992)
- Eouboulis AI, "Biosorption of metals from dilute aqueous solutions", Sep Purification Methods, 26, pp.255~295 (1997)
- 전 충, "알긴산을 이용한 중금속 제거에 관한 연구", 유기물자원화, 15(4), pp.107~114 (2007), 유기성자원학회
- Jeon C, "Characteristcs of metal removal using carboxylated alginic acid", Water Research, 36, pp.1814~1824 (2002)
- Jeon C, "Environmental effects and desorption characteristics on heavy metal removal using carboxylated alginic acid", Bioreso Technol, 96, pp.15~19 (2005)
- 정대영, "Biosorption of Metal Ions by Seaweed Alginate, Polyguluronate, and Polymannuronate", 생명과학회지, 19(5), pp.553~560 (2009), 한국생명과학회
- 김은지, "보라우무 메탄올추출물의 HT-29 대장암세포 증식 억제 효과", 한국식품영양과학회지, 36(4), pp.431~438 (2007), 한국식품영양과학회
- 김호현, "도심지역 성인의 혈중 중금속 농도 분포", 환경독성보건학회지, 19(4), pp.327~334 (2004), 환경독성보건학회
- 이미숙, "다섯 가지 해조류 에탄올 추출물의 항돌연변이 활성 및 암세포 성장억제 효과", 한국식품영양과학회지, 34(4), pp.451~459 (2005), 한국식품영양과학회
- Kim YH, "Characterization of lead adsorption by Undaria pinnatifida", Biotechnol Letters, 17, pp.345~350 (1995)
- Kim YS, "Heavy metals and cosmetics", Soci Cosmetic Sci of Kor, 28, pp.15~30 (2002)
- Koo JG, "Biosorption of lead and cadmium by fucoidan from Undaria finnatifia", J Korean Fish Soc, 34, pp.521~525 (2001)
- 김광국, "화학적으로 개질된 알긴산의 중금속 제거능", 한국물환경학회지, 21(6), pp.569~574 (2005), 한국물환경학회
- Park KL, "A study on the effect of sodium alginate in heavy metals poisoning of mouse", Korean J Environ Hlth Soc, 12, pp.147~154 (1986)
- Park WP, "Biosorption of heavy metal ions by waste brown seaweed and their derivatives", J Korean Environ Sci Soc, 10, pp.153~158 (2001)
- Park YH, "Seasonal variation in the chemical composition of brown algae with special reference to alginic acid", Bull Korean Fish Soc, 2, pp.71~82 (1969)
- STAT guide for personal computer. version 6th ed, "SAS", pp.1987, SAS
- Schweiger RG, "Actylation of alginic acid. Reaction of algin acetates with calcium and other divalent ions", J ORG Chem, 27, pp.1789~1791 (1962)
- Suh KH, "Sargassum confusum for Biosorption of Pb and Cr", J Korean Fish Soc, 34, pp.1~6 (2001)
- Suh KH, "Biosorption and development of biosorbent by using seaweed, Sargassum thunbergii", J Korean Fish Soc, 33, pp.60~65 (2000)
- Svein JH, "Ethanol production from seaweed extract", J ind Microbiol Biotechnol, 25, pp.249~254 (2000)
- Yasuhiro K, "Recovery of zinc, cadmium and lanthanum by biopolymer gel particles of alginic acid", Separation Sci and Technol, 28, pp.1691~1702 (1993)