본문 바로가기
KERD
논문KCI 등재

부산 도심하천 하구의 Nonylphenol 거동 특성

Behavior Characteristics of Nonylphenol in the Downstream of River in Busan, Korea

2

조회

0

다운로드

3

인용

0

참고문헌

키워드

주제분류수산학

초록

Nonylphenol is an endocrine-disrupting chemical that is the degradation product of the nonionic surfactants nonylphenol ethoxylates. To understand the contamination and behavioral characteristics of nonylphenol, we measured the nonylphenol concentrations in surface water in the lower reaches of the Suyeong River, Korea. The results were used to estimate the material balance. The target area was divided into three regions to estimate the material balance of nonylphenol. In region 1, in flux of the dissolved nonylphenol was 282.3 g/day and the nonylphenol influx in particulate suspended solids was 1,582.8 g/day. The dissolved nonylphenol outflow discharged toward region 2 was 192.5 g/day, while the adsorption to particulate suspended solids was 89.8 g/day. Within the particulate suspended solids, the outflow to region 2 was 1,250.0 g/day, while the estimated amount settling in the sediments was 422.7 g/day. The adsorption of dissolved nonylphenol to the particulate suspended solids in regions 1 and 2 was 31.8% and 54.9%, respectively. In region 3, the desorption rate was 8.8%.

Abstract

Nonylphenol is an endocrine-disrupting chemical that is the degradation product of the nonionic surfactants nonylphenol ethoxylates. To understand the contamination and behavioral characteristics of nonylphenol, we measured the nonylphenol concentrations in surface water in the lower reaches of the Suyeong River, Korea. The results were used to estimate the material balance. The target area was divided into three regions to estimate the material balance of nonylphenol. In region 1, in flux of the dissolved nonylphenol was 282.3 g/day and the nonylphenol influx in particulate suspended solids was 1,582.8 g/day. The dissolved nonylphenol outflow discharged toward region 2 was 192.5 g/day, while the adsorption to particulate suspended solids was 89.8 g/day. Within the particulate suspended solids, the outflow to region 2 was 1,250.0 g/day, while the estimated amount settling in the sediments was 422.7 g/day. The adsorption of dissolved nonylphenol to the particulate suspended solids in regions 1 and 2 was 31.8% and 54.9%, respectively. In region 3, the desorption rate was 8.8%.

참고문헌 (24)

  1. Fundamental Planning Report for River Improvement Works, "Busan Metropolitan City", Busan Metropolitan City, 17~19, pp.Busan Metropolitan City 265 (2003)
  2. Characteristics of Aquatic Environment in Close-to-Nature Oncheon Stream, "Busan Metropolitan City Institute of Health & Environment", BIHE, 63~75, pp.The annual report of BIHE 17 (2007)
  3. Colborn T, "Developmental Effects of Endocrine-Disrupting Chemicals in Wildlife and Humans", Environ Health Perspect, 101, pp.378~384 (1993)
  4. Ferrara F, "Alkylphenolic compounds in edible molluscs of the Adriatic sea(Italy)", Environ Sci Technol, 35, pp.3109~3112 (2001)
  5. Fries E, "Occurrence and behaviour of 4-nonylphenol in river water of Germany", J Environ Monit, 5, pp.598~603 (2003)
  6. Giger P, "4-Nonylphenol in sewage sludge : accumulation of toxic metabolites from nonionic surfactants", Science, 225, pp.623~625 (1984)
  7. 함영국, "상수도 계통에서 비스페놀 A와 노닐페놀의 실태조사", 분석과학, 17(5), pp.423~433 (2004), 한국분석과학회
  8. Isobe T, "Distribution and behavior of nonylphenol, octylphenol, and nonylphenol monoethoxylate in Tokyo metropolitan area : their association with aquatic particles and sedimentary distribution", Environ Sci Technol, 35, pp.1041~1049 (2001)
  9. Isobe T, "Determination of degradation products of alkylphenol polyethoxylates in municipal waste waters and rivers in Tokyo, Japan", Environ Tox and Chem, 23(3), pp.599~605 (2004)
  10. Jonkers N, "Aerobic biodegradation studies of nonylphenol ethoxylates in river water using liquid chromatographyelectrospray tandemmass spectrometry", Environ Sci Technol, 35, pp.335~340 (2001)
  11. Kavlock RJ, "Research Needs for the Risk Assessment of Health and Environmental Effects of Endocrine Disruptors : A Report of the U. S. EPA-sponsored Workshop", Environ Health Perspect, 104, pp.715~740 (1996)
  12. Report of research projects of endocrine disrupting chemicals, "MEV (Ministry of Environment)", MEV and NIER, 897~ (2000)
  13. Environmental monitoring of endocrine disrupting chemicals, "NIER(National Institute of Environmental Research)", 33~83, pp.MEV 104 (2006)
  14. 8th report of research projects of endocrine disrupting chemicals, "NIER(National Institute of Environmental Research)", 24~25, pp.MEV 31 (2007)
  15. Effect of endocrine disrupting compounds on coastal ecosystem, "KORDI (Korea Ocean Research and Development Institute)", 35~36, pp.MEST 183 (2004)
  16. 이세한, "낙동강 중류 수계에 있어서 Alkylphenol Polyethoxylate의 오염원과 잔류특성(051012-051215)", 대한환경공학회지, 27(12), pp.1277~1284 (2005), 대한환경공학회
  17. Li DH, "Seasonal flux of nonylphenol in Han River, Korea", Chemosphere, 56, pp.1~6 (2004)
  18. 이동호, "광양만 및 주변 하천에서의 노닐페놀 화합물 분포", 환경생물, 22, pp.71~77 (2004), 한국환경생물학회
  19. Park MS, "A study on the water quality characteristics of the Suyeong river", Master, pp.1997
  20. Renner R, "European bans on surfactant trigger transatlantic debate", Environ Sci Technol, 31, pp.316A~320A (1997)[DOI]
  21. Rice CP, "Alkylphenol and alkylphenol-ethoxylates in carp, water, and sediment from the Cuyahoga River, Ohio", Environ Sci Technol, 37, pp.3747~3754 (2003)
  22. Shang DY, "Persistence of nonylphenol ethoxylate surfactants and their primary degradation products in sediments from near a municipal outfall in the strait of Georgia, British Columbia, Canada", Environ Sci Technol, 33, pp.1366~1372 (1999)
  23. Soto AM, "PNonylphenol : an estrogenic xenobiotic released from"modified"polystyrene", Environ Health Perspect, 92, pp.167~173 (1991)
  24. Wu ZB, "Nonylphenol and octylphenol in urban eutrophic lakes of the subtropical China", Fresenius Environ Bull, 16, pp.227~234 (2007)

관련 논문AI추천

이 간행물의 다른 논문 (12건)