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Electrical properties and microstructure of zno varistor with high surge protective characteristics

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We fabricated ZnO-Bi2O3-Sb2O3-Al2O3-CoO-NiO varistor and investigated the effect of sintering temperature on itsmicrostructures and electrical properties. As the sintering temperature increases, crystalline grain growth and phase changeare observed owing to the volatilization of Bi2O3. The varistor voltage decreased from 280 V/mm to 195 V/mm with theincrease in sintering temperature, and the nonlinear coefficient (α) and leakage current of the varistor sintered at 1120 oC were42.3 and 2.8 μA, respectively. For the varistor sintered at 1120 oC, the surface temperature and current increased from 45.3 oCto 87.9 oC and from 2.8 kA to 7.44 kA, respectively, under the surge voltage (waveform of 1.2/50 ms) of 6 kV to 15 kV. According to a repeated surge test (waveform: 1.2/50 ms and 8/20 ms, surge voltage 6.6 kV/3 kA, interval: 60 s), the varistorexhibited excellent surge-withstanding capability with the variation rate of voltage 0.8% and the variation rate of leakagecurrent within 1.5%.

Abstract

We fabricated ZnO-Bi2O3-Sb2O3-Al2O3-CoO-NiO varistor and investigated the effect of sintering temperature on itsmicrostructures and electrical properties. As the sintering temperature increases, crystalline grain growth and phase changeare observed owing to the volatilization of Bi2O3. The varistor voltage decreased from 280 V/mm to 195 V/mm with theincrease in sintering temperature, and the nonlinear coefficient (α) and leakage current of the varistor sintered at 1120 oC were42.3 and 2.8 μA, respectively. For the varistor sintered at 1120 oC, the surface temperature and current increased from 45.3 oCto 87.9 oC and from 2.8 kA to 7.44 kA, respectively, under the surge voltage (waveform of 1.2/50 ms) of 6 kV to 15 kV. According to a repeated surge test (waveform: 1.2/50 ms and 8/20 ms, surge voltage 6.6 kV/3 kA, interval: 60 s), the varistorexhibited excellent surge-withstanding capability with the variation rate of voltage 0.8% and the variation rate of leakagecurrent within 1.5%.

참고문헌 (9)

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  4. 남춘우, "Sintering Effect on Clamping Characteristics and Pulse Aging Behavior of ESD-Sensitive V2O5", Mn3O4, Transactions on Electrical and Electronic Materials, pp.2015, 16(6)[DOI]
  5. "KS C IEC 61643-11; Low-voltage surge protective devices-Part 11:Surge protective devices connected to low-voltage power systems-Requirements and test methods", ~ (2012)
  6. 엄주홍, "Parameters Optimization of Impulse Generator Circuit for Generating First Short Stroke Lightning Current Waveform", Journal of Electrical Engineering & Technology, 9(1), pp.286~292 (2014), 대한전기학회
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