分光學적 方法에 의한 重油灰 溶出液 中의 Ni 定量에 關한 基礎 硏究
Determination of Ni in Fly Ash Leach Liquor by Spectrophotometric Method
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초록
중유회로부터 증류수로 용출시킨 중유회 용출액에서 금속 중 Ni^2+이온의 정량을 분광광도법으로 측정하고자 하였다. 또 중유회용출액 중 다량 존재하는 V^3+이온이 Ni^2+이온의 분광광도법적 정량에 미치는 영향을 알아보기 위하여 Ni^2+이온 ppm 대비 V^3+이온의 함량을 달리한 시료의 흡광도를 조사한 결과 V^3+이온의 함량이 Ni^2+ 함량의 50% 이하인 조건에서는 시료 중 Ni^2+이온의 정량이 분광광도법으로 가능함을 확인하였다.
Abstract
We tried to measure the fixed quantity of Ni^2+ion among the metals which were eluted by distilled water from the Fly Ash Leach Liquor(FALL) with a spectrophotometric method. In addition, we researched absorbance values which had different contained quantity of V^3+ion in contrast with Ni^2+ion ppm to find out the influence of the V^3+ion existed in the FALL on the spectrophotometric fixed quantity of Ni2+ion. As a result, when V^3+ ion has below 50% of amount of Ni^2+ion, the fixed quantity of Ni^2+ion among the FALL was able to be confirmed by spectrophotometry.
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