Quantitative Determination of Ascaridole, Carvacrol and p-Cymene in the Biopesticides Products Derived from Chenopodium ambrosioides L. Extracts by Gas Chromatography
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BACKGROUND: The commercial biopesticides containing Chenopodium ambrosioides L. extracts which have been registered as one of the ingredients of the commercial biopesticide by the organic agriculture materials, and have been widely used in Republic of Korea. However, the quantitative analysis method of the active substances for the commercial biopesticides containing C. ambrosioides L. extract has not been conducted. METHODS AND RESULTS: To analyze the quantitative analysis of ascaridole, carvacrol, and p-cymene as active substances of C. ambrosioides L. extract, hydrophilic lipophilic balance cartridge was used for solid phase extraction. The active substances were analyzed by the gas chromatography with flame ionization detector. The limit of quantitation values of ascaridole, carvacrol, and p-cymene were 10, 5, and 2 mg/L, and the recovery rates were 96.3, 84.0, and 82.5% in liquid products and 98.3, 99.1, and 97.3% in solid products, respectively. The total content of ascaridole, carvacrol, and p-cymene in the commercial biopesticides was ranged from 0.08 to 12.75%. CONCLUSION: From these results, this method was suitable for the quantitative analysis of the active substances of commercial biopesticides containing C. ambrosioides L. extract.
Abstract
BACKGROUND: The commercial biopesticides containing Chenopodium ambrosioides L. extracts which have been registered as one of the ingredients of the commercial biopesticide by the organic agriculture materials, and have been widely used in Republic of Korea. However, the quantitative analysis method of the active substances for the commercial biopesticides containing C. ambrosioides L. extract has not been conducted. METHODS AND RESULTS: To analyze the quantitative analysis of ascaridole, carvacrol, and p-cymene as active substances of C. ambrosioides L. extract, hydrophilic lipophilic balance cartridge was used for solid phase extraction. The active substances were analyzed by the gas chromatography with flame ionization detector. The limit of quantitation values of ascaridole, carvacrol, and p-cymene were 10, 5, and 2 mg/L, and the recovery rates were 96.3, 84.0, and 82.5% in liquid products and 98.3, 99.1, and 97.3% in solid products, respectively. The total content of ascaridole, carvacrol, and p-cymene in the commercial biopesticides was ranged from 0.08 to 12.75%. CONCLUSION: From these results, this method was suitable for the quantitative analysis of the active substances of commercial biopesticides containing C. ambrosioides L. extract.
참고문헌 (17)
- Cavalli, J. F., "Combined analysis of the essential oil of Chenopodium ambrosioides by GC, GC-MS and 13C-NMR spectroscopy: quantitative determination of ascaridole, a heat-sensitive compound", Phytochemical Analysis, 15(5), pp.275~279 (2004)
- Chiasson, H., "Acaricidal properties of a Chenopodium-based botanical", Journal of Economic Entomology, 97(4), pp.1373~1377 (2004)
- Chiasson, H., "Insecticidal properties of a Chenopodium-based botanical", Journal of Economic Entomology, 97(4), pp.1378~1383 (2004)
- Chu, S. S., "Composition of essential oil of Chinese Chenopodium ambrosioides and insecticidal activity against maize weevil, Sitophilus zeamais", Pest Management Science, 67(6), pp.714~718 (2011)
- Hmamouchi, M., "Molluscicidal activity of some Moroccan medicinal plants", Fitoterapia, 71(3), pp.308~314 (2000)
- Jardim, C. M., "Composition and antifungal activity of the essential oil of the Brazilian Chenopodium ambrosioides L", Journal of Chemical Ecology, 34(9), pp.1213~1218 (2008)
- Jiménez-Osornio, F. M. V. Z. J., "Allelopathic activity of Chenopodium ambrosioides L", Biochemical Systematics and Ecology, 24(3), pp.195~205 (1996)
- Lall, N., "In vitro inhibition of drugresistant and drug-sensitive strains of Mycobacterium tuberculosis by ethnobotanically selected South African plants", Journal of Ethnopharmacology, 66(3), pp.347~354 (1999)
- Lee, J. W., "Investigation on the insecticidal limonoid content of commercial biopesticides and neem extract using solid phase extraction", Journal of Agricultural Chemistry and Environment, 2(4), pp.81~85 (2013)
- 임성진, "Quantitative Analysis of Cinnamaldehyde, Cinnamylalcohol and Salicylaldehyde in Commercial Biopesticides Containing Cinnamon Extract Using Gas Chromatography - Flame Ionization Detector", 한국환경농학회지, 33(3), pp.213~219 (2014), 한국환경농학회[DOI]
- Malik, M. M., "Screening of some indigenous plants as repellants or antifeedants for stored grain insects", Journal of Stored Products Research, 20(1), pp.41~44 (1984)
- Monzote, L., "Essential oil from Chenopodium ambrosioides and main components:activity against Leishmania, their mitochondria and other microorganisms", Experimental Parasitology, 136(1), pp.20~26 (2014)
- Noumi, E., "Medicinal plants used for intestinal diseases in Mbalmayo Region, Central Province, Cameroon", Fitoterapia, 72(3), pp.246~254 (2001)
- Olajide, O. A., "Pharmacological screening of the methanolic extract of Chenopodium ambrosioides", Fitoterapia, 68(6), pp.529~532 (1997)
- Pandey, A. K., "Repellent activity of some essential oils against two stored products beetles Callosobruchus chinensis L. and C. maculatus F. (Coleoptera: Bruchidae) with reference to Chenopodium ambrosioides L. oil for the safety of pigeon pea seeds", Journal of Food Science and Technology, 51(12), pp.4066~4071 (2014)
- Pino, J. A., "Essential oil of Chenopodium ambrosioides L. from Cuba", Journal of Essential Oil Research, 15(3), pp.213~214 (2003)
- Yang, J. Y., "Acaricidal activities of the active component of Lycopus lucidus oil and its derivatives against house dust and stored food mites (Arachnida: Acari).", Pest Management Science, 68(4), pp.564~572 (2012)