Quantitative Analysis of Cinnamaldehyde, Cinnamylalcohol and Salicylaldehyde in Commercial Biopesticides Containing Cinnamon Extract Using Gas Chromatography - Flame Ionization Detector
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참고문헌
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초록
BACKGROUND: In an environment-friendly agriculture,plant extracts have been perceived as alternatives ofsynthetic pesticides. The Environment-friendly AgriculturePromotion Act of Korea has approved cinnamon extract asa matter for the production of commercial biopesticides. Thirteen commercial biopesticides containing cinnamonextract have been marketed locally. However, the analyticalmethod for the quality control of these biopesticidescontaining cinnamon extract has not been studied. METHODS AND RESULTS: Cartridge clean-up methodfor the determination of cinnamaldehyde, cinnamylalcoholand salicylaldehyde in biopesticides containing cinnamonextract was developed and validated by gas chromatography(GC). The clean-up method was optimized with HLB SPEcartridges for the bioactive substance in biopesticidescontaining cinnamon extract, and the eluate was analyzedby GC. The developed method was validated, and the LOQand recovery rates of cinnamaldehyde, cinnamylalcoholand salicylaldehyde were 0.139, 0.067 and 0.062 mg L-1 and84.2, 86.5 and 82.1%, respectively. The contents ofcinnamaldehyde, cinnamylalcohol and salicylaldehydewere analyzed using the developed method in the 13commercial biopesticides. Results showed 0.06-17.37%,<LOQ-0.01% and <LOQ, respectively. CONCLUSION: This method would contribute tomanufacturers producing biopesticides and the qualitycontrol of biopesticides containing cinnamon extract.
Abstract
BACKGROUND: In an environment-friendly agriculture,plant extracts have been perceived as alternatives ofsynthetic pesticides. The Environment-friendly AgriculturePromotion Act of Korea has approved cinnamon extract asa matter for the production of commercial biopesticides. Thirteen commercial biopesticides containing cinnamonextract have been marketed locally. However, the analyticalmethod for the quality control of these biopesticidescontaining cinnamon extract has not been studied. METHODS AND RESULTS: Cartridge clean-up methodfor the determination of cinnamaldehyde, cinnamylalcoholand salicylaldehyde in biopesticides containing cinnamonextract was developed and validated by gas chromatography(GC). The clean-up method was optimized with HLB SPEcartridges for the bioactive substance in biopesticidescontaining cinnamon extract, and the eluate was analyzedby GC. The developed method was validated, and the LOQand recovery rates of cinnamaldehyde, cinnamylalcoholand salicylaldehyde were 0.139, 0.067 and 0.062 mg L-1 and84.2, 86.5 and 82.1%, respectively. The contents ofcinnamaldehyde, cinnamylalcohol and salicylaldehydewere analyzed using the developed method in the 13commercial biopesticides. Results showed 0.06-17.37%,<LOQ-0.01% and <LOQ, respectively. CONCLUSION: This method would contribute tomanufacturers producing biopesticides and the qualitycontrol of biopesticides containing cinnamon extract.
참고문헌 (36)
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