본문 바로가기
KERD
논문KCI 등재

2차원 결정성 탄소 소재의 최근 이차전지 소재 개발 동향: 그래핀(graphene)과 그라파인(graphyne)의 이차전지 개발 최근 동향

Progress in Recent Research of 2D and Crystalline Carbon Materials in Secondary-ion Battery Application

봉성율|이혁진
한국전기화학회 (The Korean Electrochemical Society)|2022.11|전기화학회지 (Journal of the Korean Electrochemical Society)|제25권 제4호|pp. 162-173

1

조회

0

다운로드

0

인용

0

참고문헌

키워드

GrapheneTwo-dimensional materialsRenewable energyGraphyneSecondary battery
주제분류화학

초록

우리의 삶에 있어 새로운 물질의 개발/발견은 전 세계의 환경 및 에너지 문제를 해결하는 데필수적인 열쇠이다. 이러한 관점에서 결정성 탄소계 2차원 재료는 벌집 또는 sp/sp2 하이브리드구조의 탄소 소재의 전기 전도도, 화학적 안정성, 표면 공학 등 다양한 관점에서 오랜 시간 동안 연구되어 왔다. 특히, 그래핀을 포함한 새로운 2차원 탄소 소재 개발은 신재생 에너지 분야에서 수십 년 동안 지속적으로 개발되고 있다. 구체, 입방체 등의 다양한 구조 형태의 금속나노입자와 함께 복합화하여 시너지 효과를 낼 수 있는 탄소 동소체가 연구되고 있으며, 이를 통하여 신재생 에너지 분야의 디바이스 성능이 획기적으로 향상되고 있다. 본 총설에서는 2D 탄소동소체 재료, 그래핀 및 그라파인의 연구 방향과 재생 에너지 분야의 성능을 향상시키기 위한응용 방법을 소개하고자 한다.

Abstract

The development of new materials is an essential key for unraveling the environmental and energy problems all over the world. Among the various application materials in this area, crystalline and two-dimensional carbon materials have been studied from points of view such as electrical conductivity, chemical stability, and surface engineering due to the assembly of honeycomb and sp/sp2 hybridization structure. Novel two-dimensional materials, including graphene and graphyne, have been continuously reported for several decades to develop in renewable energy fields. Also, various pristine/engineered two-dimensional carbon allotropes have been researched to combine metal nanoparticles in the form of a sphere, cubic, and so on. The renewable energy performance to apply for these materials is drastically increased. In this review, we introduce the research points of the 2D carbon allotrope materials, graphene and graphyne, and applications to improve the performance of renewable energy applications.

참고문헌 (66)

  1. X. Tang, "Recent development of ionic liquid-based electrolytes in lithiumion batteries", J. Power Sources, 542, pp.231792~ (2022)
  2. X. Jiang, "The impact of electrode with carbon materials on safety performance of lithium-ion batteries: A review", Carbon, 191, pp.448~470 (2022)
  3. C. Huang, "Progress in research into 2D graphdiyne-based materials", Chem. Rev, 118, pp.7744~7803 (2018)
  4. M. Inagaki, "Graphene derivatives: graphane, fluorographene, graphene oxide, graphyne and graphdiyne", J. Mater. Chem. A, 2, pp.13193~13206 (2014)
  5. A. Razaq, "Review on graphene-, graphene oxide-, reduced graphene oxide-based flexible composites: From fabrication to applications", Materials, 15, pp.1012~ (2022)
  6. M. S. A. Bhuyan, "Synthesis of graphene", Int. Nano Lett, 6, pp.65~83 (2016)
  7. L. Sathishkumar, "Compatibility of lithium ion phosphate battery in solar offgrid application", J. Electrochem. Sci. Technol, 13(4), pp.472~478 (2022)
  8. H. Kim, "Enhancing electrochemical performance of Co(OH)2 anode materials by introducing graphene for next-generation liion batteries", J. Electrochem. Sci. Technol, 13(3), pp.398~406 (2022)
  9. M. -S. Shin, "Spherical silicon", CNT, J. Electrochem. Sci. Technol, pp.2022, 13(1)[DOI]
  10. X. Lu, "Tailoring graphite with the goal of achieving single sheets", Nanotechnology, 10, pp.269~ (1999)
  11. Y. Zhang, "Fabrication and electric-field-dependent transport measurements of mesoscopic graphite devices", Appl. Phys. Lett, 86, pp.073104~ (2005)
  12. A. M. Affoune, "Experimental evidence of a single nano-graphene", Chem. Phys. Lett, 348, pp.17~20 (2001)
  13. S. Bong, "Graphene supported electrocatalysts for methanol oxidation, Electrochem.", Electrochem. Commun, 12, pp.129~131 (2010)
  14. L. Sun, "Chemical vapour deposition", Nat. Rev. Methods Primer, 1, pp.5~ (2021)
  15. M. M. Haley, "Carbon networks based on dehydrobenzoannulenes: Synthesis of graphdiyne substructures", Angew. Chem. Int. Ed, 36(8), pp.836~838 (1997)
  16. J. M. Kehoe, "Carbon networks based on dehydrobenzoannulenes. 3. Synthesis of graphyne substructures1", Org. Lett, 2(7), pp.969~972 (2000)
  17. W. B. Wan, "Carbon networks based on dehydrobenzoannulenes. 4. Synthesis of “Star” and “Trefoil” graphdiyne substructures via sixfold crosscoupling of hexaiodobenzene", J. Org. Chem, 66(11), pp.3893~3901 (2001)
  18. X. Li, "A review of graphynes:Properties, applications and synthesis", New Carbon Mater, 35, pp.619~629 (2020)
  19. X. Gao, "Graphdiyne:synthesis, properties, and applications", Chem. Soc. Rev, 48, pp.908~936 (2019)
  20. J. Zhou, "Exploring approaches for the synthesis of few-layered graphdiyne", Adv. Mater, 31, pp.1803758~ (2019)
  21. D. Malko, "Competition for graphene: Graphynes with directiondependent dirac cones", Phys. Rev. Lett, 108, pp.086804~ (2012)
  22. H. Wang, "Review on recent progress in nitrogen-doped graphene: Synthesis, characterization, and its potential applications", ACS Catal, 2, pp.781~794 (2012)
  23. X. Li, "Superior cycle stability of nitrogen-doped graphene nanosheets as anodes for lithium ion batteries", Electrochem. Commun, 13, pp.822~825 (2011)
  24. S. H. Yang, "Metal-organic frameworks derived FeSe2@C nanorods interconnected by N-doped graphene nanosheets as advanced anode materials for Na-ion batteries", Int. J. Energy Res, 45, pp.20909~20920 (2021)
  25. S. Yu, "Graphene-based lithium-ion battery anode materials manufactured by mechanochemical ball milling process:A review and perspective", Compos. Part B Eng, 246, pp.110232~ (2022)
  26. Z. Luo, "Pyridinic N doped graphene: synthesis, electronic structure, and electrocatalytic property", J. Mater. Chem, 21, pp.8038~8044 (2011)
  27. D. Wei, "Synthesis of N-doped graphene by chemical vapor deposition and its electrical properties", Nano Lett, 9, pp.1752~1758 (2009)
  28. A. L. M. Reddy, "Synthesis of nitrogen-doped graphene films for lithium battery application", ACS Nano, 4, pp.6337~6342 (2010)
  29. S. M. Shinde, "Grain structures of nitrogen-doped graphene synthesized by solid source-based chemical vapor deposition", Carbon, 96, pp.448~453 (2016)
  30. M. Son, "High-quality nitrogen-doped graphene films synthesized from pyridine via two-step chemical vapor deposition", Carbon, 159, pp.579~585 (2020)
  31. J. Xu, "Sulfur and nitrogen Co-doped, few-layered graphene oxide as a highly efficient electrocatalyst for the oxygen-reduction reaction", ChemSusChem, 6, pp.493~499 (2013)
  32. F. Hassani, "A simple synthesis of sulfur-doped graphene using sulfur powder by chemical vapor deposition", RSC Adv, 6, pp.27158~27163 (2016)
  33. J. Zhou, "Growth and properties of largearea sulfur-doped graphene films", J. Mater. Chem. C, 5, pp.7944~7949 (2017)
  34. L. Ci, "Atomic layers of hybridized boron nitride and graphene domains", Nat. Mater, 9, pp.430~435 (2010)
  35. T. Wu, "Nitrogen and boron doped monolayer graphene by chemical vapor deposition using polystyrene, urea and boric acid", New J. Chem, 36, pp.1385~1391 (2012)
  36. Z. Zhai, "Metal-free synthesis of boron-doped graphene glass by hot-filament chemical vapor deposition for wave energy harvesting", ACS Appl. Mater. Interfaces, 12(2), pp.2805~2815 (2020)
  37. H. Kim, "Doping efficiency of single and randomly stacked bilayer graphene by iodine adsorption", Appl. Phys. Lett, 105, pp.011605~ (2014)
  38. Z. -S. Wu, "Doped graphene sheets as anode materials with superhigh rate and large capacity for lithium ion batteries", ACS Nano, 5, pp.5463~5471 (2011)
  39. G. H. Jun, "Enhanced conduction and charge-selectivity by N-doped graphene flakes in the active layer of bulkheterojunction organic solar cells", Energy Environ. Sci, 6, pp.3000~3006 (2013)
  40. Z. -H. Sheng, "Catalyst-free synthesis of nitrogen-doped graphene via thermal annealing graphite oxide with melamine and its excellent electrocatalysis", ACS Nano, 5, pp.4350~4358 (2011)
  41. X. Wang, "N-doping of graphene through electrothermal reactions with ammonia", Science, 324, pp.768~771 (2009)
  42. S. Yang, "Efficient synthesis of heteroatom (N or S)-doped graphene based on ultrathin graphene oxide-porous silica sheets for oxygen reduction reactions", Adv. Funct. Mater, 22, pp.3634~3640 (2012)
  43. H. M. Jeong, "Nitrogendoped graphene for high-performance ultracapacitors and the importance of nitrogen-doped sites at basal planes", Nano Lett, 11, pp.2472~2477 (2011)
  44. Y. Shao, "Nitrogen-doped graphene and its electrochemical applications", J. Mater. Chem, 20, pp.7491~7496 (2010)
  45. Y. Wang, "Ndoping of plasma exfoliated graphene oxide via dielectric barrier discharge plasma treatment for the oxygen reduction reaction", J. Mater. Chem. A, 6, pp.2011~2017 (2018)
  46. S. Li, "Plasma-induced highly efficient synthesis of boron doped reduced graphene oxide for supercapacitors", Chem. Commun, 52, pp.10988~10991 (2016)
  47. V. K. Abdelkader-Fernández, "Expanding graphene properties by a simple S-doping methodology based on cold CS2 plasma", Carbon, 144, pp.269~279 (2019)
  48. J. Guo, "Room-temperature synthesis of waterdispersible sulfur-doped reduced graphene oxide without stabilizers", RSC Adv, 10, pp.26460~26466 (2020)
  49. D. W. Chang, "Wetchemical nitrogen-doping of graphene nanoplatelets as electrocatalysts for the oxygen reduction reaction", J. Mater. Chem. A, 3, pp.7659~7665 (2015)
  50. P. Wu, "Enhancing the electrochemical reduction of hydrogen peroxide based on nitrogen-doped graphene for measurement of its releasing process from living cells", Chem. Commun, 47, pp.11327~11329 (2011)
  51. L. Sun, "Nitrogen-doped graphene with high nitrogen level via a one-step hydrothermal reaction of graphene oxide with urea for superior capacitive energy storage", RSC Adv, 2, pp.4498~4506 (2012)
  52. Y. Su, "Low-temperature synthesis of nitrogen", sulfur co-doped three-dimensional graphene frameworks as efficient metal-free electrocatalyst for oxygen reduction reaction, 2013, pp.62, 296~301
  53. N. Li, "Large scale synthesis of N-doped multi-layered graphene sheets by simple arc-discharge method", Carbon, 48(1), pp.255~259 (2010)
  54. Y. Zhou, "Graphene nanoflakes with optimized nitrogen doping fabricated by arc discharge as highly efficient absorbers toward microwave absorption", Carbon, 148, pp.204~213 (2019)
  55. L. S. Panchakarla, "Synthesis, structure, and properties of boron- and nitrogen-doped graphene", Adv. Mater, 21(46), pp.4726~4730 (2009)
  56. T. V. Pham, "High areal capacitance of N-doped graphene synthesized by arc discharge", Adv. Funct. Mater, 29(48), pp.1905511~ (2019)
  57. C. Liu, "Nitrogen-doped graphene by all-solid-state ball-milling graphite with urea as a high-power lithium ion battery anode", J. Power Sources, 342, pp.157~164 (2017)
  58. I. -Y. Jeon, "Edgeselectively sulfurized graphene nanoplatelets as efficient metal-free electrocatalysts for oxygen reduction reaction: The electron spin effect", Adv. Mater, 25(42), pp.6138~6145 (2013)
  59. H. N. Tien, "Synthesis of highly durable sulfur doped graphite nanoplatelet electrocatalyst by a fast and simple wet ball milling process", Mater. Lett, 161, pp.399~403 (2015)
  60. J. Xu, "Sulfur–graphene nanostructured cathodes via ball-milling for high-performance lithium–sulfur batteries", ACS Nano, 8, pp.10920~10930 (2014)
  61. J. Xu, "Edge-selectively halogenated graphene nanoplatelets (XGnPs, X = Cl, Br, or I) prepared by ball-milling and used as anode materials for lithium-ion batteries", Adv. Mater, 26(43), pp.7317~7323 (2014)
  62. X. Meng, "Scrutinizing defects and defect density of selenium-doped graphene for high-efficiency triiodide reduction in dye-sensitized solar cells", Angew. Chem, 130, pp.4772~4776 (2018)
  63. J. Ma, "γ-Graphyne nanotubes as promising lithium-ion battery anodes", Appl. Surf. Sci, 531, pp.147343~ (2020)
  64. Q. Zhang, "Strainenhanced Li storage and diffusion on the graphyne as the anode material in the Li-ion battery", J. Phys. Chem. C, 122(40), pp.22838~22848 (2018)
  65. B. Wu, "Superflexible C68-graphyne as a promising anode material for lithium-ion batteries", J. Mater. Chem A, 7, pp.17357~17365 (2019)
  66. X. Liu, "Constructing two-dimensional holey graphyne with unusual annulative π-extension", Matter, 5(7), pp.2306~2318 (2022)

관련 논문AI추천

계면 제어를 통한 2차원 그래핀 성장의 최근 연구 동향이승구, 이은호한국접착및계면학회 · 접착 및 계면2021 · 제22권 제3호차세대 소듐 이온 배터리 안정성 및 용량 향상을 위한 전극 소재 연구 동향김석규, 방대석, 이은호, 정동영한국접착및계면학회 · 접착 및 계면2025 · 제26권 제3호전고체 이차전지용 음극 소재의 개발 동향한국재료부식학회 · CORROSION SCIENCE AND TECHNOLOGY2025 · 제24권 제4호나트륨이차전지용 전환반응 음극 소재 기술 동향김수지, 김유진, 류원희한국전기화학회 · 전기화학회지2019 · 제22권 제1호리튬이차전지용 음극 소재 기술 개발 동향김성수한국전기화학회 · 전기화학회지2008 · 제11권 제3호리튬 이온 배터리 음극의 고율속 성능 향상: MoSe2 나노 시트 코팅된 흑연 복합체의 최적 합성 조건에 대한 연구박승운, 신혜영, 윤하나, 이영아, 장규연한국전기화학회 · 전기화학회지2024 · 제27권 제4호

이 간행물의 다른 논문 (7건)

전기화학 기반의 전기 변색 센서 연구 동향서민지pp. 125-133증착 기법을 이용한 리튬이차전지용 초박막 세라믹 코팅 분리막 기술최승엽, 노영준, 김우철, 이용민, Cyril Bubu Dzakpasupp. 134-153고분자 전해질막 수전해의 산화 전극용 귀금속 촉매의 연구 동향조현석, 정원석, 부종찬, 임다빈, 심유진pp. 154-161고분자 전해질 연료전지 및 수전해용 촉매층의 이오노머 바인더박종혁, 박진수, 김범석, 정다혜, 이민영, 마하무다아크테르, 신지윤pp. 174-183고분자 전해질 연료전지 및 수전해용 촉매층의 이오노머 바인더이민영, 정다혜, 김범석, 박진수, 마하무다아크테르, 신지윤, 박종혁pp. 174-183
원문 보기