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나트륨이차전지용 전환반응 음극 소재 기술 동향

Research Trend on Conversion Reaction Anodes for Sodium-ion Batteries

김유진|김수지|류원희
한국전기화학회 (The Korean Electrochemical Society)|2019.02|전기화학회지 (Journal of the Korean Electrochemical Society)|제22권 제1호|pp. 22-35|DOI 10.5229/JKES.2019.22.1.22

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키워드

Sodium-Ion BatteriesAnode MaterialsConversion Reaction
주제분류화학

초록

이차 전지의 개발이 전기자동차나 스마트그리드와 같은 중대형의 에너지저장장치로 응용범위가 확대됨에 따라 이차 전지의 경제성확보가 화두가 되고 있다. 나트륨이차전지는 리튬보다 훨씬 저렴한 나트륨원료를 사용하여 저가의 차세대 이차 전지로 크게 주목받고 있다. 이에 따라 이온반경이 큰 나트륨이온의 삽입과 탈리를 원활하게 해줄 수 있는 음극 소재의 개발이 최근 몇 년간 활발히 수행되어 왔다. 나트륨이차전지용 음극은 세 가지의 반응 메커니즘 (층간 삽입반응, 금속-합금반응, 전환반응)을 기반한 소재들이 보고되었으며, 본 총설에서는 전환반응으로 구동하는 다양한 음극 소재들을 소개하며 나트륨 전지 셀 내 반응 메커니즘을 소개하고자 한다.

Abstract

Development of low cost rechargeable batteries has been considered as a significant task for future large-scale energy storage units (i.e. electric vehicles, smart grids). Sodium-ion batteries (SIBs) have been recognized as a promising alternative to replace conventional lithium-ion batteries (LIBs) because of their abundancy and economic benign. Nevertheless, Na ions have larger ionic radius than that of Li ions, resulting in sluggish transport of Na ionsin electrodes for cell operation. There have been efforts to seek suitable anode materials for the past years operated based on three different kinds of reaction mechanism (intercalation, alloy reaction, and conversion reaction). In this review, we introduce a class of conversion reaction anode materials for Na-ion batteries, which have been reported.

참고문헌 (62)

  1. Chu, S., "The path towards sustainable energy", Nature Materials, 16, pp.16~22 (2017)
  2. Larcher, D., "Towards greener and more sustainable batteries for electrical energy storage", Nature Chemistry, 7, pp.19~29 (2014)
  3. Hwang, J. -Y., "Sodium-ion batteries: present and future", Chemical Society Reviews, 46, pp.3529~3614 (2017)
  4. Li, T., "In Situ Grown Fe2O3 Single Crystallites on Reduced Graphene Oxide Nanosheets as High Performance Conversion Anode for Sodium-Ion Batteries", ACS Appl Mater Inter, 9, pp.19900~19907 (2017)
  5. Hu, M., "Reversible Conversion-Alloying of Sb2O3 as a High-Capacity, High-Rate, and Durable Anode for Sodium Ion Batteries", ACS Appl Mater Inter, 6, pp.19449~19455 (2014)
  6. Zhang, Z., "Facile synthesis of Sb2S3", MoS2heterostructure as anode material for sodium-ion batteries, 2018, pp.29, 335401~
  7. Jiang, Y., "Transition metal oxides for high performance sodium ion battery anodes", Nano Energy, 5, pp.60~66 (2014)
  8. Slater, M. D., "Sodium-Ion Batteries", Adv Funct Mater, 23, pp.947~958 (2013)
  9. Wen, Y., "Expanded graphite as superior anode for sodium-ion batteries", Nat Commun, 5 (2014)
  10. Sun, R., "Vanadium Sulfide on Reduced Graphene Oxide Layer as a Promising Anode for Sodium Ion Battery", Acs Appl Mater Inter, 7, pp.20902~20908 (2015)
  11. Luo, W., "Na-Ion Battery Anodes: Materials and Electrochemistry", Accounts Chem Res, 49, pp.231~240 (2016)
  12. Zhao, Q., "Advanced Organic Electrode Materials for Rechargeable Sodium-Ion Batteries", Adv Energy Mater, 7, pp.1601792~ (2017)
  13. Wang, L., "Metal oxide", graphene composite anode materials for sodium-ion batteries, 2019, pp.16, 434~454
  14. Kubota, K., "Review—Practical Issues and Future Perspective for Na-Ion Batteries", Journal of The Electrochemical Society, 162, pp.A2538~A2550 (2015)
  15. Yoo, H. D., "On the challenge of developing advanced technologies for electrochemical energy storage and conversion", Mater Today, 17, pp.110~121 (2014)
  16. Hou, H., "Carbon Anode Materials for Advanced Sodium-Ion Batteries", Adv Energy Mater, 7, pp.1602898~ (2017)
  17. Yang, J., "SDoped N-Rich Carbon Nanosheets with Expanded Interlayer Distance as Anode Materials for Sodium-Ion Batteries", Advanced Materials, 29, pp.1604108~ (2017)
  18. Jian, Z., "Insights on the Mechanism of Na-Ion Storage in Soft Carbon Anode", Chemistry of Materials, 29, pp.2314~2320 (2017)
  19. Cao, Y., "Sodium Ion Insertion in Hollow Carbon Nanowires for Battery Applications", Nano Letters, 12, pp.3783~3787 (2012)
  20. Chen, C., "Na+ intercalation pseudocapacitance in graphene-coupled titanium oxide enabling ultra-fast sodium storage and long-term cycling", Nat Commun, 6 (2015)
  21. Xiong, H., "Amorphous TiO2 Nanotube Anode for Rechargeable Sodium Ion Batteries", The Journal of Physical Chemistry Letters, 2, pp.2560~2565 (2011)
  22. Wu, L., "Unfolding the Mechanism of Sodium Insertion in Anatase TiO2Nanoparticles", Adv Energy Mater, 5, pp.1401142~ (2015)
  23. Xu, H., "Boosting sodium storage properties of titanium dioxide by a multiscale design based on MOFderived strategy", Energy Storage Mater, 17, pp.126~135 (2019)
  24. Hwang, J.-Y., "Carbon-Free TiO2 Microspheres as Anode Materials for Sodium Ion Batteries", Acs Energy Lett, pp.494~501 (2019)
  25. Wahid, M., "Hard Carbons for Sodium-Ion Battery Anodes:Synthetic Strategies, Material Properties, and Storage Mechanisms", ChemSusChem, 11, pp.506~526 (2018)
  26. Irisarri, E., "Review—Hard Carbon Negative Electrode Materials for Sodium-Ion Batteries", J Electrochem Soc, 162, pp.A2476~A2482 (2015)
  27. Dou, X., "Hard carbons for sodium-ion batteries:Structure, analysis, sustainability, and electrochemistry", Mater Today, ~ (2019)
  28. Prabakar, S. J. R., "Nanoporous hard carbon anodes for improved electrochemical performance in sodium ion batteries", Electrochim Acta, 161, pp.23~31 (2015)
  29. Balogun, M. -S., "A review of carbon materials and their composites with alloy metals for sodium ion battery anodes", Carbon, 98, pp.162~178 (2016)
  30. Luo, W., "Low-Surface-Area Hard Carbon Anode for Na-Ion Batteries via Graphene Oxide as a Dehydration Agent", Acs Appl Mater Inter, 7, pp.2626~2631 (2015)
  31. Wang, L. P., "Recent developments in electrode materials for sodium-ion batteries", J Mater Chem A, 3, pp.9353~9378 (2015)
  32. Chevrier, V. L., "Challenges for Na-ion Negative Electrodes", J Electrochem Soc, 158, pp.A1011~ (2011)
  33. Kim, S. -W., "Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries", Adv Energy Mater, 2, pp.710~721 (2012)
  34. Rudola, A., "Na2Ti3O7: an intercalation based anode for sodium-ion battery applications", Journal of Materials Chemistry A, 1, pp.2653~ (2013)
  35. Li, Z., "Tin and Tin Compounds for Sodium Ion Battery Anodes: Phase Transformations and Performance", Accounts of Chemical Research, 48, pp.1657~1665 (2015)
  36. Kim, Y., "High-Capacity Anode Materials for Sodium-Ion Batteries", Chemistry - A European Journal, 20, pp.11980~11992 (2014)
  37. Xiao, L., "High capacity, reversible alloying reactions in SnSb", C nanocomposites for Na-ion battery applications, 2012, pp.48, 3321~
  38. Edison, E., "Beyond intercalation based sodium-ion batteries: the role of alloying anodes, efficient sodiation mechanisms and recent progress", Sustain Energ Fuels, 2, pp.2567~2582 (2018)
  39. Chen, L., "Readiness Level of Sodium-Ion Battery Technology: A Materials Review", Adv Sustain Syst, 2, pp.1700153~ (2018)
  40. Ryu, W. -H., "Vine-like MoS2anode materials self-assembled from 1-D nanofibers for high capacity sodium rechargeable batteries", Nanoscale, 6, pp.10975~10981 (2014)
  41. Wu, C., "The State and Challenges of Anode Materials Based on Conversion Reactions for Sodium Storage", Small, 14, pp.1703671~ (2018)
  42. Hasa, I., "Transition metal oxide-carbon composites as conversion anodes for sodium-ion battery", Electrochim Acta, 173, pp.613~618 (2015)
  43. Liu, X., "Fe2O3 -reduced graphene oxide composites synthesized via microwave-assisted method for sodium ion batteries", Electrochim Acta, 166, pp.12~16 (2015)
  44. Li, D., "Amorphous Fe2O3", Graphene Composite Nanosheets with Enhanced Electrochemical Performance for Sodium-Ion Battery, 2016, pp.8, 30899~30907
  45. Liu, Y., "Mesoporous Co 3 O 4 sheets", 3D graphene networks nanohybrids for high-performance sodium-ion battery anode, 2015, pp.273, 878~884
  46. Rahman, M. M., "Electrochemical investigation of sodium reactivity with nanostructured Co3O4 for sodium-ion batteries", Chem. Commun, 50, pp.5057~5060 (2014)
  47. Santangelo, S., "Electro-spun Co3O4 anode material for Na-ion rechargeable batteries", Solid State Ionics, 309, pp.41~47 (2017)
  48. Li, H.-H., "Shale-like Co3O4 for high performance lithium", sodium ion batteries, 2016, pp.4, 8242~8248
  49. Yuan, S., "Engraving Copper Foil to Give Large-Scale Binder-Free Porous CuO Arrays for a High-Performance Sodium-Ion Battery Anode", Adv Mater, 26, pp.2273~2279 (2014)
  50. Klein, F., "Kinetics and Degradation Processes of CuO as Conversion Electrode for Sodium-Ion Batteries: An Electrochemical Study Combined with Pressure Monitoring and DEMS", The Journal of Physical Chemistry C, 121, pp.8679~8691 (2017)
  51. Zhou, Q., "Co3S4@polyaniline nanotubes as highperformance anode materials for sodium ion batteries", J Mater Chem A, 4, pp.5505~5516 (2016)
  52. Wang, J., "An Advanced MoS2", Carbon Anode for High-Performance Sodium-Ion Batteries, 2015, pp.11, 473~481
  53. Su, D., "Ultrathin MoS2Nanosheets as Anode Materials for Sodium-Ion Batteries with Superior Performance", Adv Energy Mater, 5, pp.1401205~ (2015)
  54. Liu, Y., "WS2Nanowires as a High-Performance Anode for Sodium-Ion Batteries", Chemistry - A European Journal, 21, pp.11878~11884 (2015)
  55. Choi, S. H., "Sodium ion storage properties of WS2-decorated three-dimensional reduced graphene oxide microspheres", Nanoscale, 7, pp.3965~3970 (2015)
  56. Wang, X., "(002)-oriented WS2 with high crystalline with enhanced capacity as anode material for sodium ion batteries", Journal of Alloys and Compounds, 696, pp.22~27 (2017)
  57. Ryu, W.-H., "Heterogeneous WSx", WO3 Thorn-Bush Nanofiber Electrodes for Sodium-Ion Batteries, 2016, pp.10, 3257~3266
  58. Shadike, Z., "Improved electrochemical performance of CoS2–MWCNT nanocomposites for sodium-ion batteries", Chem Commun, 51, pp.10486~10489 (2015)
  59. Li, X., "Mo 2 C", N-doped carbon nanowires as anode materials for sodium-ion batteries, 2017, pp.194, 30~33
  60. 김주형, "Conversion-Alloying Anode Materials for Na-ion Batteries: Recent Progress, Challenges, and Perspective for the Future", 한국세라믹학회지, 55(4), pp.307~324 (2018), 한국세라믹학회
  61. Zheng, Y., "Boosted Charge Transfer in SnS", SnO2Heterostructures: Toward High Rate Capability for Sodium-Ion Batteries, 2016, pp.128, 3469~3474
  62. Hong, X., "Ultrafast charge transfer in atomically thin MoS2", WS2 heterostructures, 2014, pp.9, 682~686

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