팽창성 흑연과 금속수산화물이 목재⋅플라스틱 복합재의 특성에 미치는 영향에 관한 연구
A Study on the Effect of Expandable Graphite and Metal Hydroxides on the Properties of Wood Plastic Composites (WPCs) Seungkyun
0
조회
0
다운로드
0
인용
0
참고문헌
키워드
초록
Wood-plastic composites (WPCs) composed of mainly wood flour and thermoplastics have attracted considerable attentions due to advantages of cost effectiveness, high durability, and microbial resistance. However, relatively poor fire resistance of WPCs from low thermal stability of wood and plastics prevents further uses. This study investigated the effect of expandable graphite (EG) and aluminium hydroxide (AH)/magnesium hydroxide (MH) on the properties of WPCs. The combined incorporation of both EG and metal hydroxide (i.e., AH or MH) into formulations leads to higher flexural modulus of filled composites compared to neat PP and WPC. In thermal properties, EG played an important role in improving thermal stability of filled composites by suppressing thermal decompositions of wood and PP. Moreover, EG showed better water absorption features. From this research, it can be said that EG and metal hydroxides have potentials as effective reinforcement, flame retardant, and moisture barrier.
Abstract
Wood-plastic composites (WPCs) composed of mainly wood flour and thermoplastics have attracted considerable attentions due to advantages of cost effectiveness, high durability, and microbial resistance. However, relatively poor fire resistance of WPCs from low thermal stability of wood and plastics prevents further uses. This study investigated the effect of expandable graphite (EG) and aluminium hydroxide (AH)/magnesium hydroxide (MH) on the properties of WPCs. The combined incorporation of both EG and metal hydroxide (i.e., AH or MH) into formulations leads to higher flexural modulus of filled composites compared to neat PP and WPC. In thermal properties, EG played an important role in improving thermal stability of filled composites by suppressing thermal decompositions of wood and PP. Moreover, EG showed better water absorption features. From this research, it can be said that EG and metal hydroxides have potentials as effective reinforcement, flame retardant, and moisture barrier.
참고문헌 (11)
- 김범준, "유리섬유가 충전된 공압출 목재⋅플라스틱 복합재의 굽힘 특성에 관한 연구", 한국가구학회지, 24(4), pp.379~388 (2013), 한국가구학회
- 남경구, "경질 폴리우레탄 폼의 충진거동 및 팽창성 흑연의 첨가에 따른 난연성 연구", 석사, 고분자공학, pp.2005
- 서현정, "탄소나노소재의 건축재료 활용을 위한 난연 성능 향상방안 고찰", 한국생활환경학회지, 20(4), pp.514~526 (2013), 한국생활환경학회
- 이단비, "친환경 난연제와 탈크를 첨가한 목재·플라스틱 복합재의 기계적, 열적, 형태학적 및 수분흡수 특성에 관한 연구", 한국가구학회지, 27(2), pp.137~144 (2016), 한국가구학회
- 장복남, "난연제 및 난연수지 연구 동향", 고분자과학과 기술, 20(1), pp.8~15 (2009)
- Du, L., "Hygrothermal effects on properties of highly conductive epoxy", graphite composites for applications as bipolar plates, 2008, pp.182(1), 223~229
- Dweiri, R., "Electrical properties of carbon-based polypropylene composites for bipolar plates in polymer electrolyte membrane fuel cell(PEMFC)", Journal of Power Sources, 171(2), pp.424~423 (2007)
- Kim, B. -J., "Performance of bamboo plastic composites with hybrid bamboo and precipitated calcium carbonate fillers", Polymer Composites, 33(1), pp.68~78 (2012)
- Gwon, J. G., "Thermal degradation behavior of polypropylene base wood plastic composites hybridized with metal (aluminum, magnesium) hydroxides", Journal of Applied Polymer Science, 131(7), pp.40120~ (2014)
- Sever, K., "Electrical and mechanical properties of expanded graphite", high density polyethylene nanocomposites, 2013, pp.53, 226~233
- Stark, N. M., "Evaluation of various fire retardants for use in wood flour-polyethylene composites", Polymer Degradation and Stability, 95(9), pp.1903~1910 (2010)
