화염 분무 열분해법으로 합성된 Cr-Co3O4 나노입자 자일렌 가스센서
Xylene Sensor Using Cr-doped Co3O4 Nanoparticles Prepared by Flame Spray Pyrolysis
1
조회
0
다운로드
2
인용
0
참고문헌
키워드
초록
Xylene is a hazardous volatile organic compound that should be precisely measured to monitor indoor air quality. However, the selectiveand sensitive detection of ppm-level xylene using oxide–semiconductor gas sensors remains a challenge. In this study, pure and CrdopedCo3O4 nanoparticles (NPs) were prepared using flame spray pyrolysis, and their gas-sensing characteristics to 5-ppm xylene at250 °C were investigated. The 4 at% Cr-doped Co3O4 NPs exhibited a high gas response to 5-ppm xylene (resistance ratio to gas andair = 39.1) and negligible cross-responses to other representative and ubiquitous indoor pollutants such as ethanol, benzene, formaldehyde,carbon monoxide, and ammonia. In this paper, the enhancement of the gas response and selectivity of Co3O4 NPs to xyleneby Cr doping was discussed in relation to the catalytic promotion of the gas-sensing reaction. This sensor can be used to monitor indoorxylene.
Abstract
Xylene is a hazardous volatile organic compound that should be precisely measured to monitor indoor air quality. However, the selectiveand sensitive detection of ppm-level xylene using oxide–semiconductor gas sensors remains a challenge. In this study, pure and CrdopedCo3O4 nanoparticles (NPs) were prepared using flame spray pyrolysis, and their gas-sensing characteristics to 5-ppm xylene at250 °C were investigated. The 4 at% Cr-doped Co3O4 NPs exhibited a high gas response to 5-ppm xylene (resistance ratio to gas andair = 39.1) and negligible cross-responses to other representative and ubiquitous indoor pollutants such as ethanol, benzene, formaldehyde,carbon monoxide, and ammonia. In this paper, the enhancement of the gas response and selectivity of Co3O4 NPs to xyleneby Cr doping was discussed in relation to the catalytic promotion of the gas-sensing reaction. This sensor can be used to monitor indoorxylene.
참고문헌 (30)
- S. Bakand, "A novel in vitro exposure technique for toxicity testing of selected volatile organic compounds", J. Environ. Monit, 8(1), pp.100~105 (2006)
- J. J. Langenfeld, "Quantitative analysis of fuel-related hydrocarbons in surface water and wastewater samples by solid-phase microextraction", Anal. Chem, 68(1), pp.144~155 (1996)
- P. Karlitschek, "Detection of aromatic pollutants in the environment by using UV-laser-induced fluorescence", Appl. Phys. B, 67(4), pp.497~504 (1998)
- W. Lindinger, "Proton-transferreaction mass spectrometry(PTR–MS) : on-line monitoring of volatile organic compounds at pptv levels", Chem. Soc. Rev, 27(5), pp.347~375 (1998)
- D. Smith, "Selected ion flow tube mass spectrometry(SIFT?MS)for on?line trace gas analysis", Mass Spectrom. Rev, 24(5), pp.661~700 (2005)
- A. Kolmakov, "Detection of CO and O2 Using Tin Oxide Nanowire Sensors", Adv. Mater, 15(12), pp.997~1000 (2003)
- A. Sanger, "Morphology?Controlled Aluminum? Doped Zinc Oxide Nanofibers for Highly Sensitive NO2 Sensors with Full Recovery at Room Temperature", Adv. Sci., 5(9), pp.1800816(1)~1800816(8) (2018)
- J. Shin, "Thin?Wall Assembled SnO2Fibers Functionalized by Catalytic Pt Nanoparticles and their Superior Exhaled?Breath?Sensing Properties for the Diagnosis of Diabetes", Adv. Funct. Mater, 23(19), pp.2357~2367 (2013)
- Y. G. Song, "Heterojunction Based on Rh-Decorated WO3 Nanorods for Morphological Change and Gas Sensor Application Using the Transition Effect", Chem. Mater, 31(1), pp.207~215 (2019)
- S. Park, "Synthesis, Structure, and Ethanol Gas Sensing Properties of In2O3 Nanorods Decorated with Bi2O3 Nanoparticles", ACS Appl. Mater. Interfaces, 7(15), pp.8138~8146 (2015)
- J. -H. Lee, "Gas Sensors using Hierarchical and Hollow Oxide Nanostructures : Overview", Sens. Actuator B-Chem, 140(1), pp.319~336 (2009)
- A. Mirzaei, "Resistive-based gas sensors for detection of benzene, toluene and xylene(BTX)gases : a review", J. Mater. Chem. C, 6(16), pp.4342~4370 (2018)
- J. -W. Yoon, "Gas sensing characteristics of p-type Cr2O3 and Co3O4 nanofibers depending on inter-particle connectivity", Sens. Actuator B-Chem, 202, pp.263~271 (2014)
- Y. -M. Jo, "Metal–Organic Framework-Derived Hollow Hierarchical Co3O4 Nanocages with Tunable Size and Morphology : Ultrasensitive and Highly Selective Detection of Methylbenzenes", ACS Appl. Mater. Interfaces, 10(10), pp.8860~8868 (2018)
- H. -J. Kim, "Ultraselective and sensitive detection of xylene and toluene for monitoring indoor air pollution using Cr-doped NiO hierarchical nanostructures", Nanoscale, 5(15), pp.7066~7073 (2013)
- H. -J. Kim, "Highly sensitive and selective gas sensors using p-type oxide semiconductors : Overview", Sens. Actuator B-Chem, 192, pp.607~627 (2014)
- J. -W. Yoon, "Trimodally porous SnO2 nanospheres with three dimensional interconnectivity and size tunability : a one-pot synthetic route and potential application as an extremely sensitive ethanol detector", NPG Asia Mater, 8(3), pp.e244(1)~e244(8) (2016)
- Y. Liu, "Hierarchical SnO2 Nanostructures Made of Intermingled Ultrathin Nanosheets for Environmental Remediation, Smart Gas Sensor, and Supercapacitor Applications", ACS Appl. Mater. Interfaces, 6(3), pp.2174~2184 (2014)
- L. Wang, "ZnO nanorod gas sensor for ethanol detection", Sens. Actuator B-Chem, 162(1), pp.237~243 (2012)
- W. Zheng, "A highly sensitive and fast-responding sensor based on electrospun In2O3 nanofivers", Sens. Actuator B-Chem, 142(1), pp.61~65 (2009)
- C. Sun, "Synthesis of nearly monodisperse Co3O4 nanocubes via a microwaveassisted solvothermal process and their gas sensing characteristics", Sens. Actuator B-Chem, 157(2), pp.681~685 (2011)
- J. Muzart, "Chromium-catalyzed oxidations in organic synthesis", Chem. Rev, 92(1), pp.113~140 (1992)
- C. Subrahmanyam, "Catalytic oxidation of toluene with molecular oxygen over Cr-substituted mesoporous materials", Appl. Catal., A, 241(1-2), pp.205~215 (1992)
- Y. Wang, "Mesoporous single-crystal Cr2O3 : Synthesis, characterization, and its activity in toluene removal", Solid State Sci, 10(9), pp.1117~1123 (2008)
- Y. Xia, "Mesoporous Chromia with Ordered Three-Dimensional Structures for the Complete Oxidation of Toluene and Ethyl Acetate", Environ. Sci. Technol, 43(21), pp.8355~8360 (2009)
- K. H. Lee, "Extremely selective detection of ppb levels of indoor xylene using CoCr2O4 hollow spheres activated by Pt doping", Chem. Commun, 55(6), pp.751~754 (2019)
- S. -Y. Jeong, "Ultra-selective detection of sub-ppm-level benzene using Pd–SnO2 yolk–shell microreactors with a catalytic Co3O4 overlayer for monitoring air quality", J. Mater. Chem. A, 5(4), pp.1446~1454 (2017)
- M. L. Kantam, "An Improved Process for Selective Liquid-Phase Air Oxidation of Toluene", Catal. Lett, 81(3-4), pp.223~232 (2002)
