Carbon Nanotube Film을 이용한 액체 전기화학 센서
Liquid electrochemical sensors using carbon nanotube film
1
조회
0
다운로드
0
인용
0
참고문헌
키워드
초록
We studied electrochemical sensors using printed carbon nanotube (CNT) film on a polyethylene terephthalate (PET) substrate. Multiwalled CNT films were printed on a PET substrate to study its feasibility as hazardous and noxious substances (HNS) detection sensor. The printed CNT film (PCF) with a 50 µm thickness exhibited a specific resistance of 230 ohm. To determine the optimum sensor structure, a resistance-type PCF sensor (R-type PCF sensor) and a conductive-type PCF sensor (C-type PCF sensor) were fabricated and compared using diluted NH3 droplets with various concentrations. The response magnitude, response time, sensitivity, linearity, and limit of detection (LOD) were compared, and it was concluded that the C-type PCF sensor exhibited superior performance. By applying a C-Type PCF sensor, we confirmed the detection performance of 12 types of floating HNS and the response of the sensor with selectivity according to the degree of polarity.
Abstract
We studied electrochemical sensors using printed carbon nanotube (CNT) film on a polyethylene terephthalate (PET) substrate. Multiwalled CNT films were printed on a PET substrate to study its feasibility as hazardous and noxious substances (HNS) detection sensor. The printed CNT film (PCF) with a 50 µm thickness exhibited a specific resistance of 230 ohm. To determine the optimum sensor structure, a resistance-type PCF sensor (R-type PCF sensor) and a conductive-type PCF sensor (C-type PCF sensor) were fabricated and compared using diluted NH3 droplets with various concentrations. The response magnitude, response time, sensitivity, linearity, and limit of detection (LOD) were compared, and it was concluded that the C-type PCF sensor exhibited superior performance. By applying a C-Type PCF sensor, we confirmed the detection performance of 12 types of floating HNS and the response of the sensor with selectivity according to the degree of polarity.
참고문헌 (27)
- S. Hong, "Improved CO gas detection of Si MOSFET gas sensor with catalytic Pt decoration and pre-bias effect", Sens. Actuator B-Chem, 300, pp.127040~ (2019)
- W. Chen, "Flexible room temperature ammonia gas sensor based on in suit polymerized PANI", PVDF porous composite film, 2020, pp.31, 11870~11877
- M. Tonezzer, "Selective gas sensor based on one single SnO2 nanowire", Sens. Actuators B Chem, 288, pp.53~59 (2019)
- J. Y. Zhou, "Gas sensing enhancing mechanism via doping-induced oxygen vacancies for gas sensors based on indium tin oxide nanotubes", Sens. Actuators B-Chem., 265, pp.273~284 (2018)
- J. Kong, "Nanotube Molecular Wires as Chemical Sensors", Science., 287(5453), pp.622~625 (2000)
- V. Schroeder, "Carbon Nanotube Chemical Sensors", Chem. Rev., 119(1), pp.599~663 (2018)
- A. D. Rushi, "Selective Discrimination among Benzene, Toluene, and Xylene : Probing Metalloporphyrin-Functionalized Single-Walled Carbon Nanotube-Based Field Effect Transistors", J. Phys. Chem. C., 118(41), pp.24034~24041 (2014)
- P. Li, "Dielectrophoresis Aligned Single-Walled Carbon Nanotubes as pH Sensors", Biosensors, 1(1), pp.23~35 (2011)
- M. B. Gumpu, "A review on detection of heavy metal ions in water – An electrochemical approach", Sens. Actuator BChem., 213, pp.515~533 (2015)
- 김영윤, "해상 위험·유해물질(HNS) 관리 우선순위 선정에 관한 연구", 해양환경안전학회지, 21(6), pp.672~678 (2015), 해양환경안전학회[DOI]
- M. I. Bodnarchuk, "Large-Area Ordered Superlattices from Magnetic Wüstite", Cobalt Ferrite Core, ACS Nano, pp.2010, 4(1)[DOI]
- P. P. Prosini, "Electrochemical performance of Li-ion batteries assembled with water-processable electrodes", Solid State Ion., 274, pp.34~39 (2015)
- Sang Won Lee, "ADHESION TEST OF CARBON NANOTUBE FILM COATED ONTO TRANSPARENT CONDUCTING SUBSTRATES", NANO, 5(3), pp.133~138 (2010), 성균나노과학기술원
- Y. R. Kim, "Initial environmental risk assessment of hazardous and noxious substances(HNS)spill accidents to mitigate its damages", Mar., 139, pp.205~213 (2019)
- A. P. P. Alves, "Poly(3-hexylthiophene)-multi-walled carbon nanotube(1 : 1)hybrids : Structure and electrochemical properties", Electrochim. Acta, 111(209), pp.111~120 (2016)
- M. A. Riheen, "Inkjet Printing on PET Substrate", J. Electrochem. Soc, 166(9), pp.B3036~B3039 (2019)
- N. aran, "Fabrication and Characterization of Thin Films of Single-Walled Carbon Nanotube Bundles on Flexible Plastic Substrates", J. Am. Chem. Soc., 126(14), pp.4462~4463 (2004)
- P. R. Chalker, "A review of the methods for the evaluation of coating-substrate adhesion", Mater. Sci. Eng. A, (140), pp.583~592 (1991)
- S. Petit, "Al", PET adhesion : role of an excimer laser pretreatment of PET prior to aluminum thermal evaporation, 2003, pp.17(3), 353~368
- Y. Zhang, "Two-component spincoated Ag", CNT composite films based on a silver heterogeneous nucleation mechanism adhesion-enhanced by mechanical interlocking and chemical grafting, 2017, pp.28(10), 105607~
- N. A. Bohari, "Optimization and Analytical Behavior of Electrochemical Sensors Based on the Modification of Indium Tin Oxide(ITO)Using PANI", MWCNTs, Sensors, pp.2020, 20(22)[DOI]
- N. H. Quang, "Effect of NH3 gas on the electrical properties of singlewalled carbon nanotube bundles", Sens. Actuator B-Chem., 113(1), pp.341~346 (2006)
- K. A. Mirica, "Mechanical Drawing of Gas Sensors on Paper", Angew. Chem., 124(43), pp.10898~10903 (2012)
- S. G. Wang, "Multi-walled carbon nanotube-based gas sensors for NH3 detection", Diam. Relat. Mater, 13(4-8), pp.1327~1332 (2004)
- T. Zhang, "Recent progress in carbon nanotube-based gas sensors", Nanotechnology, 19(33), pp.33200~ (2008)
- A. Yamada, "Computer-assisted measurement of ion-diffusion coefficients by use of the cottrell equation", Anal. Chim. Acta., 112(1), pp.55~63 (1979)
- 김영윤, "해상 유해액체물질(NLS) 유출사고대비 물질군 선정에 관한 연구", 해양환경안전학회지, 22(7), pp.846~853 (2016), 해양환경안전학회[DOI]
