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안면도에서 대기 중 가스상 PAHs의 계절적 변동

Seasonal Variation of Atmospheric Polycyclic Aromatic Hydrocarbons (PAHs) on Anmyeon Island

안준건|임운혁|심원준|김기범|김승규|이희일
한국해양과학기술원 (Korea Institute of Ocean Science & Technology)|2009.06|Ocean and Polar Research|제31권 제2호|pp. 189-198

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참고문헌

키워드

fluxYellow Seapassive air sampler; PAHsgas exchange
주제분류해양학

초록

Passive air samplers with polyurethane foam (PUF) disks were employed to determine seasonal gas phase variation of polycyclic aromatic hydrocarbons (PAHs) in ambient air on Anmyeon island from March 2007 to January 2008. Sum of 13 PAHs ranged between 3.5 ng/m3 and 27.6 ng/m3. Total PAHs during the heating season was 6.2 times higher than non-heating season. The dominant PAHs components during sampling periods were low and middle molecular weight PAHs including phenanthrene, fluoranthene, pyrene and chrysene. Gas exchange fluxes of PAHs across the air-water interface of the Yellow Sea were calculated using a modified two-film exchange model. PAHs fluxes ranged from 196 ng/m2/d net volatilization during summer to 3830 ng/m2/d net absorption during winter. Passive air sampler provides a convenient and cost-effective tool for measuring averaged gas phase PAHs, which was successfully used for calculation of gas exchange flux of PAHs in the Yellow Sea.

Abstract

Passive air samplers with polyurethane foam (PUF) disks were employed to determine seasonal gas phase variation of polycyclic aromatic hydrocarbons (PAHs) in ambient air on Anmyeon island from March 2007 to January 2008. Sum of 13 PAHs ranged between 3.5 ng/m3 and 27.6 ng/m3. Total PAHs during the heating season was 6.2 times higher than non-heating season. The dominant PAHs components during sampling periods were low and middle molecular weight PAHs including phenanthrene, fluoranthene, pyrene and chrysene. Gas exchange fluxes of PAHs across the air-water interface of the Yellow Sea were calculated using a modified two-film exchange model. PAHs fluxes ranged from 196 ng/m2/d net volatilization during summer to 3830 ng/m2/d net absorption during winter. Passive air sampler provides a convenient and cost-effective tool for measuring averaged gas phase PAHs, which was successfully used for calculation of gas exchange flux of PAHs in the Yellow Sea.

참고문헌 (53)

  1. 안준건, "안면도에서 대기 중 다환방향족탄화수소 농도 와 침적", 석사, pp.2009
  2. Anne MM, "Using passive air samplers to assess urban-rural trends for persistent organic pollutants and polycyclic aromatic hydrocarbons. 2. Seasonal trends for PAHs, PCB, and organochlorine pesticides", Environ Sci Technol, 39, pp.5763~5773 (2005)
  3. Bae SY, "Temporal and spatial variations of the particle size distribution of PAHs and their dry deposition fluxes in Korea", Atmos Environ, 36, pp.5491~5500 (2002)
  4. 백송이, "Passive Air Sampler (PAS)와 기체", 입자 분배모델을 이용한 대기 중 PCB 농도 산정, 2007, pp.23(6), 734~743[DOI]
  5. Baker JE, "Loadings of atmospheric trace elements and organic contaminants to the Chesapeake Bay. In: Atmospheric deposition of contaminants to the great lakes and coastal waters", pp.171~194 (1997), SETAC Press
  6. Baker JE, "Concentrations and fluxes of polycyclic aromatic hydrocarbons and polychlorinated biphenyls across the air-water interface of Lake Superior", Environ Sci Technol, 24, pp.342~352 (1990)
  7. Bamford HA, "Diffusive exchange of polycyclic aromatic hydrocarbons across the air-water interface of the Patapsco river, an urbanized subestuary of the Chesapeake bay", Environ Sci Technol, 33, pp.2138~2144 (1999)
  8. Bartkow ME, "Field-based evaluation of semipermeable membrane devices (SPMDs) as passive air samplers of polycyclic aromatic hydrocarbons (PAHs)", Atmos Environ, 38, pp.5983~5990 (2004)
  9. Bartkow ME, "Photodegradation of polyaromatic hydrocarbons in passive air samplers: Field testing different deployment chambers", Environ Pollut, 144, pp.371~376 (2006)
  10. Bidleman TF, "Atmospheric processes: wet and dry deposition of organic compounds are controlled by their vapor-particle partitioning", Environ Sci Technol, 22, pp.361~367 (1988)
  11. Bjorseth A, "Handbook of Polycyclic aromatic hydrocarbons, Vol. 2. Marcel Dekker, New York and Basel (Chapter 1)", ~ (1985)
  12. Choi SD, "Influence of a large steel complex on the spatial distribution PAHs determined by passive air sampling using membrane-enclosed copolymer (MECOP)", Atmos Environ, 41, pp.6255~6264 (2007)
  13. Chung YS, "precipitation and large-scale transport of air pollutants observed in Korea", Water Air Soil Poll, 130, pp.367~372 (2001)
  14. Fang GC, "Characteristic of polycyclic aromatic hydrocarbon concentrations and source identification for fine and coarse particulate at Taichung Harbor near Taiwan Strait during 2004–2005", Sci Total Environ, 366, pp.729~738 (2005)
  15. Franz T, "Dry deposition of particulate polychlornated biphenyls and polycyclic aromatic hydrocarbons to Lake Michigan", Environ Sci Technol, 32, pp.3681~3688 (1998)
  16. Gevao B, "Polychlorinated biphenyls and polycyclic aromatic hydrocarbon deposition to and exchange at the air-water interface of Esthwaite Water, a small lake in the Cumbria", Environ Poll, 102, pp.63~73 (1998)
  17. Golomb DS, "Atmospheric deposition of toxics onto Massachusetts Bay-II. Polycyclic aromatic hydrocarbons", Atmos Environ, 31, pp.1361~1368 (1997)
  18. Golomb DS, "Atmospheric deposition of PAHs at Massachusetts Bay measured with a novel dry", wet collector, 1997, 81~13
  19. June Goss KU, "The air", surface adsorption equilibrium of organic compounds under ambient conditions, 2004, pp.34, 339~389
  20. ustafson KE, "Gaseous exchange of polycyclic aromatic hydrocarbons across the air-water nterface of southern Cesapeake Bay", Environ Sci Technol, 31, pp.1623~1629 (1997)
  21. Harner T, "Octanol-air partition coefficient for describing particle", gas partitioning of aromatic compounds in urban air, 1998, pp.32, 1494~1502
  22. Harner T, "Using passive air samplers to assess urban-rural trends for persistent organic pollutants (POPs): 1. Polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs)", Environ Sci Technol, 38, pp.4474~4483 (2004)
  23. Hornbuckle KC, "Seasonal variations in air-water exchange of polychlorinated biphenyls in lake superior", Environ Sci Technol, 28, pp.1491~1501 (1994)
  24. Jaward F, "Passive air sampling of PCBs, PBDEs, and organochlorine pesticides across Europe", Environ Sci Technol, 38, pp.34~41 (2004)
  25. Jaward F, "Passive air sampling of polycyclic aromatic hydrocarbons and polychlorinated naphthalenes across Europe", Environ Toxicol Chem, 23, pp.1355~1364 (2004)
  26. Kaupp H, "Gas", particle partitioning of PCDD, Chemosphere, pp.1999, 38[DOI]
  27. Kautenburger R, "PAH monitoring as pollution indication of combustion processes, demonstrated by a case study in a village of Saarland, Germany", Forum Staedte-Hygiene, 47, pp.308~319 (1996)
  28. Kulkarni P, "Atmospheric polycyclic aromatic hydrocarbons in Mumbai", Atmos Environ, 34, pp.2785~2790 (2000)
  29. Lee WMG, "The partitioning model of polycyclic aromatic hydrocarbons between gaseous and particulate (PM10) phases in urban atmosphere with high humidity", Sci Total Environ, 145, pp.163~171 (1994)
  30. Liu Y, "Inhalation exposure of traffic police officers to polycyclic aromatic hydrocarbons (PAHs) during the winter in Beijing, China", Sci Total Environ, 383, pp.98~105 (2007)
  31. Nelson ED, "Diffusive exchange of gaseous polycyclic aromatic hydrocarbons and polychlorinated biphenyls across the air-water interface of the Chesapeake bay", Environ Sci Technol, 32, pp.912~919 (1998)
  32. in Chicago air, "Sci Total Environ", 1999, 57~67
  33. Park JS, "Atmospheric deposition of PAHs, PCBs, and organochlorine pesticides to Corpus Christi Bay, Texas", Atmos Environ, 36, pp.1707~1720 (2002)
  34. Park SS, "Atmospheric polycyclic aromatic hydrocarbons in Seoul, Korea", Atmos Environ, 36, pp.2917~2924 (2002)
  35. 박승식, "Atmospheric Concentrations of PAHs in the Vapor and Particulate Phases in Chongju", Journal of Korean Society for Atmospheric Environment, 22(E2), pp.57~68 (2006), 한국대기환경학회
  36. Pandit GG, "Exchange of polycyclic aromatic hydrocarbons across the air-water interface at the creek adjoining Mumbai harbour, India", Environ Int, 32, pp.259~264 (2006)
  37. Pozo K, "Passive-sampler derived air concentrations of persistent organic pollutants on a North-South transect in Chile", Environ Sci Technol, 38, pp.6529~6537 (2004)
  38. Santiago EC, "Polycyclic aromatic hydrocarbons in ambient air in the Philippines derived from passive sampler with polyurethane foam disk", Atmos Environ, 41, pp.4138~4147 (2007)
  39. Shen L, "Atmospheric distribution and long-range transport behavior of organochlorine pesticides in North America", Environ Sci Technol, 39, pp.409~420 (2005)
  40. Simkova I, "Concentration of polycyclic aromatic hydrocarbons in rain water in the Prachatice", Hygiena, 41, pp.139~146 (1996)
  41. Soderstrom H, "PAHs and nitrated PAHs in air of five European countries determined using SPMDs as passive samplers", Atmos Environ, 39, pp.1627~1640 (2005)
  42. Tao S, "Calibration of a passive sample for both gaseous and particulate phase polycyclic aromatic hydrocarbons", Environ Sci Technol, 41, pp.568~573 (2007)
  43. Tsai P, "Atmospheric concentrations and fluxes of organic compounds in the northern San Francisco estuary", Environ Sci Technol, 36, pp.4741~4747 (2002)
  44. Tuduri L, "Polyurethane foam (PUF) disks passive air sampler: Wind effect on sampling rates", Environ Pollut, 144, pp.377~383 (2006)
  45. "Regionally based assessment of persistent toxic substances, Central and North East Asia regionally report, Global Environment Facility"[URL]
  46. US EPA, "Quality Criteria for Water 1986. EPA 440", 5- 86-001, 1987
  47. Vardar N, "Seasonal concentrations and partitioning of PAHs in a suburban site of Bursa, Turkey", Environ Poll, 155, pp.298~307 (2008)
  48. Vardar N, "Particulate dry deposition and overall deposition velocities of polycyclic aromatic hydrocarbons", J Environ Eng, 128, pp.269~274 (2002)
  49. Vasilakos C, "Gas-particle concentration and characterization of sources of PAHs in the atmosphere of suburban area in Athens, Greece", J Hazard Mater, 140, pp.45~51 (2007)
  50. Wanninkhof R, "Relationship between gas exchange and wind speed over the ocean", J Geophys Res, 97, pp.7373~7382 (1992)
  51. Yang XY, "Longrange transport of polycyclic aromatic hydrocarbons from China to Japan", Atmos Environ, 41, pp.2710~2718 (2007)
  52. Kim HS, "On Surface O3 Associated with Long-Range Transport in the Yellow Sea Region", Water Air Soil Poll, 165, pp.95~112 (2005)
  53. KORDI, "The Yellow Sea pollution and surveillance spersistent organic pollutants", Ocean Research & Development Institute, 1971(3), pp.522~ (2008)

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