Poly(vinyl alcohol)/poly(ethylene glycol) 하이드로겔에서의silver nanoparticles의 제조
Preparation of Silver Nanoparticles on the Poly(vinyl alcohol)/ poly(ethylene glycol) Hydrogel
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초록
Silver nano-particles (AgNPs) have attracted much attention for centuries due to theirunique optical properties, electrical conductivities, oxidative catalysis, and antibacterial effect. Inthis study, AgNPs have been prepared by using aqueous AgNO3 solution in the poly(vinyl alcohol)(PVA)/poly(ethylene glycol) (PEG) hydrogels. PVA and PEG powders were dissolved in deionizedwater, and then irradiated by a gamma-ray with a radiation dose of 50 kGy to make hydrogels. PVA/PEG hydrogels were dipped into 1.0×10-2 M AgNO3 solution for 1 hour. After that, theswollen hydrogels were irradiated by gamma-ray for the formation of AgNPs. FE-SEM is used toobserve the formation of AgNPs as a function of the content of PEG and the irradiation dose. Also, AgNPs in the PVA/PEG hydrogels were monitored by UV-Vis. It is observed that thecontent of PEG and gamma-ray irradiation in the hydrogel is crucial to the formation of AgNPs. Finally, antibacterial tests indiacted that the hydrogel containing silver nanoparticle has antibacterialactivity.
Abstract
Silver nano-particles (AgNPs) have attracted much attention for centuries due to theirunique optical properties, electrical conductivities, oxidative catalysis, and antibacterial effect. Inthis study, AgNPs have been prepared by using aqueous AgNO3 solution in the poly(vinyl alcohol)(PVA)/poly(ethylene glycol) (PEG) hydrogels. PVA and PEG powders were dissolved in deionizedwater, and then irradiated by a gamma-ray with a radiation dose of 50 kGy to make hydrogels. PVA/PEG hydrogels were dipped into 1.0×10-2 M AgNO3 solution for 1 hour. After that, theswollen hydrogels were irradiated by gamma-ray for the formation of AgNPs. FE-SEM is used toobserve the formation of AgNPs as a function of the content of PEG and the irradiation dose. Also, AgNPs in the PVA/PEG hydrogels were monitored by UV-Vis. It is observed that thecontent of PEG and gamma-ray irradiation in the hydrogel is crucial to the formation of AgNPs. Finally, antibacterial tests indiacted that the hydrogel containing silver nanoparticle has antibacterialactivity.
참고문헌 (15)
- 조경환, "초음파법으로 제조된 은 나노 입자의 항균특성 연구", 공업화학, 15(8), pp.952~955 (2004), 한국공업화학회
- Choi EK, "Preparation and characterization of PVA", PVP, Chitosan hydrogels by freezing, pp.thawing and radiation crosslinking, J. Korean. Ind. Eng. Chem[DOI]
- Coviello T, "Polysaccharide hydrogels for modified release formulations", J. Control Release, 119, pp.5~24 (2007)
- He B, "Synthesis of size controlled Ag nanoparticles", J. Mol. Catal. A-Cehm, 221, pp.121~126 (2004)
- Huang NM, "Sucrose ester micellar-mediated synthesis of Ag nanoparticles and the antibacterial properties", Colloid. Surface. A, 353, pp.69~76 (2010)
- 김수남, "은나노 입자의 입경 크기 및 형태에 따른 체내 동태 및 염증 반응", 환경독성보건학회지, 25(3), pp.215~222 (2010), 환경독성보건학회
- Kim YH, "The effect of zeta-potential on the stabilization of silver nanoparticle colloid prepared by alcohol reduction method wih PVP", J. Korean Ind. Eng. Chem, 14, pp.487~492 (2003)
- Naghavi K, "Influence of dose on particle size of colloidal silver nanoparticle synthesized by gamma radiation", Rad. Phys. Chem, 79, pp.1203~1208 (2010)
- 이철재, "Silver", PMMA 나노복합체의 합성과 특성에 관한 연구, 2008, pp.52(4), 345~349[DOI]
- Qi M, "PVA hydrogel sheet macroencapsulation for the bioartificial pancreas", Biomaterials, 25, pp.5885~5892 (2004)
- Sagle AC, "PEGbased hydrogel membrane coatings", Polymer, 50, pp.756~766 (2009)
- Sanborn TJ, "In situ crosslinking of a biomaterials peptide-PEG hydrogel via thermally triggered activation of factor XIII", Biomaterials, 23, pp.2703~2710 (2002)
- Sun X, "Preparation and size control of silver nanoparticles by a thermal method", Mater. Lett, 59, pp.3847~3850 (2005)
- Tolaymat TM, "An evidence-based environmental perspective of manufactured silver nanoparticle in syntheses and applications : A systematic review and critical appraisal of peer-reviewed scientific papers", Sci. Total Environ, 408, pp.999~1006 (2010)
- Zhang DK, "Research on the long time swelling properties of poly(vinyl alcohol)", hydorxylapatitie composite hydrogel, 2009, pp.6, 22~28
